===================== Product Identification =====================
MSDS NAME:METHYLENE BLUE TRIHYDRATE, M235-100
NIIN:00N092914
Status Code:A
MSDS Number: CJVWM
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Resp. Party Other MSDS Num.:ACC 00037
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:METHYLENE BLUE TRIHYDRATE EINECS/ELINCS: UNLISTED.
CAS:7220-79-3
RTECS #:SP5740000
> Wt:98.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT AVAILABLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES BURNS. SKIN: MAY
CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION
WITH NAUSEA, VOMITING AND DIARRHEA. MAY BE HARMFUL IF SWALLOWED.
INHALATION: DUST IS IRRITATING T O THE RESPIRATORY TRACT. MAY CAUSE
METHEMOGLOBINEMIA, CYANOSIS, CONVULSIONS, TACHYCARDIA, DYSPNEA, AND
DEATH. CHRONIC: NO INFORMATION FOUND. TARGET ORGANS: NONE.
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR
OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
Eyes: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID
IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: GET
MEDICAL AID. FLUS H WITH PLENTY OF SOAP & WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGESTION: IF
VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
AID IMMEDIATELY. INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR
IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
GET MED AID. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Flash Point Method:CALC
Flash Point:NOT AVAILABLE
Autoignition Temp:Autoignition Temp Text:N/AV
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DUSTS AT SUFFICIENT CONCENTRATIONS CAN
FORM EXPLOSIVE MIXTURES WITH AIR. DURING A FIRE, IRRITATING AND
HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION. FLASH POINT METHOD: ( ESTIMATED). HEALTH - 3;
FLAMMABILITY - 0; REACTIVITY - 0.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. CLEAN
UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE
EQUIPMENT SECTION. SWEEP U P OR ABSORB MATERIAL, THEN PLACE INTO A
SUITABLE CLEAN, DRY, CLOSED CONTAINER FOR DISPOSAL. AVOID
GENERATING DUSTY CONDITIONS. PROVIDE VENTILATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY,
WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions:CORROSIVE. USE WITH ADEQUATE VENTILATION. MINIMIZE
DUST GENERATION AND ACCUMULATION. DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. AVOID INGESTION AND
INHALATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPROVED RESPIRATORY PROGRAM THAT MEETS
OSHA'S 29 CFR '1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN
STANDARD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S US E.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL PROPERTIES: DENSITY: NOT AVAILABLE. MOLECULAR
FORMULA: C16H18CIN3S.3H2O. MOLECULAR WEIGHT: N/P.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Decomp Temp:=190.C, 374.F
Vapor Pres:NEGLIGIBLE
Vapor Density:13
Spec Gravity:NOT AVAILABLE
pH:3.4
Viscosity:NOT AVAILABLE
Solubility in Water:SOLUBLE
Appearance and Odor:DARK GREEN SOLID; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS, ALKALIS, DICHROMATES,
ALKALI IODIDES.
Stability Condition to Avoid:STABLE. HOWEVER, MAY DECOMPOSE IF HEATED.
AVOID INCOMPATIBLE MATERIALS, DUST GENERATION, STRONG OXIDANTS.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
CARBON DIOXIDE, SULFUR OXIDES (SO*X), INCLUDING SULFUR OXIDE AND
SULFUR DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:CAS #7220-79-3: RTECS # SP5745000:
EPIDEMIOLOGY: NO DATA AVAILABLE. TERATOGENICITY: NO DATA AVAILABLE.
REPRODUCTIVE EFFECTS: AN INCREASE IN POST INPLANTATION MORTALITY
WAS OBSERVED IN RATS 1-22 DAYS A FTER CONCEPTION. TDLO=2500 MG/KG.
NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: MUTATION STUDIES
HAVE BEEN CONDUCTED IN MICROORGANISMS, ASCITIES TUMOR CELLS FROM
MICE, AND IN MAMMALIAN LYMPHOCYTE CE LLS ACCORDING TO RTEC'S. OTHER
STUDIES: NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION
OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS;
F-SERIES; P-SERIES; & U-SER IES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION
AVAILABLE. IATA: SHIPPING NAME: NO INFORMATION AVAILABLE. RID/ADR:
SHIPPING NAME: NO INFORMATION AVAILABLE. IMO: SHIPPING NAME: NO
INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME: NO INFORMATION
AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS ARE
REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:TSCA:CAS # 7220-79-3 IS LISTED ON TSCA
INVENTORY. IT IS FOR RESEARCH & DEVEL USE ONLY. HLTH & SFTY
REPORTING LIST:NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST.
CHEM TEST RULES:NONE OF CHEMS IN THIS PROD ARE UNDER CHEM TEST
RULE. SECTION 12B:NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B.
TSCA SIGNIFICANT NEW USE RULE:NONE OF CHEMS IN THIS MATL HAVE SNUR
UNDER TSCA. CLEAN AIR ACT:THIS MATL DOES NOT CONTAIN ANY HAZ AIR
POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS.
THIS MA TL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN
WATER ACT:NONE OF CHEMS IN THIS PROD ARE LISTED AS HAZ (STATE
REGULATORY INFO)
State Regulatory Information:CAS #7220-79-3 IS NOT PRESENT ON STATE
LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT
RISK LEVEL:NONE OF CHEMS IN THIS PROD ARE LISTED. -- FED
REGULATORY:SUBSTANCES UNDER CWA. NONE OF CHEMS IN THIS PROD ARE
LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN THIS PROD
ARE LISTED AS TOX POLLUTANTS UNDER CWA. OSHA:NONE OF CHEMS IN THIS
PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. E UROPEAN/INTERNATIONAL
REGS:EUROPEAN LABELING I/A/W EC DIRECTIVES:HAZ SYMBOLS: NOT AVAIL.
RISK PHRASE S:N/P. SFTY PHRASES:N/P. WGK (WATER DANGER/PROT):CAS
#7220-79-3:NO INFO AVAIL. (OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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