===================== Product Identification =====================
MSDS NAME:139 7215,PT B, KODAK INDUSTREX DEVELOPER REPLENISHER
NIIN:01-353-4889
Status Code:A
Kit Part:Y
MSDS Number: CKZNH
=== Responsible Party ===
Company:EASTMAN KODAK CO.
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:ACETIC ACID
CAS:64-19-7
RTECS #:AF1225000
Minumum % Wt:85.
Maxumum % Wt:90.
Other REC Limits:NOT PROVIDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:1-PHENYL-3-PYRAZOLIDIONE
CAS:92-43-3
RTECS #:UQ8750000
Minumum % Wt:5.
Maxumum % Wt:10.
Other REC Limits:0.2 MG/M3 TWA, MFR
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:NONIONIC SURFACTANT
CAS:68072-38-8
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:5-NITROINDAZOLE
CAS:5401-94-5
RTECS #:NK7962000
< Wt:1.
Other REC Limits:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR EXTREMELY
IRRITATING. MAY CAUSE DELAYED LUNG INJURY. EYES: CAUSES SEVERE
BURNS. VAPOR EXTREMELY IRRITATING. SKIN: CAUSES SEVERE BURNS. MAY
CAUSE ALLERGIC SKIN REACTION. INGESTION: HA RMFUL IF SWALLOWED. MAY
CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
Explanation of Carcinogenicity:(COMPONENTS PRESENT AT 0.1% OR MORE):
- INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE -
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH):
NONE - NATIONAL TOXICOLOG Y PROGRAM (NTP): NONE -
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: VAPOR EXTREMELY IRRITATING. EYES:
CAUSES SEVERE BURNS. VAPOR EXTREMELY IRRITATING. SKIN: CAUSES
SEVERE BURNS. INGESTION: MAY CAUSE BURNS OF THE GASTROINTESTINAL
TRACT IF SWALLOWED.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET
MEDICAL ATTENTION IMMEDIATELY. EYES: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FO R AT LEAST 15 MINUTES. GET MEDICAL ATTENTION
IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IM MEDIATELY. WASH CONTAMINATED CLOTHING
BEFORE REUSE. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A
GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
===================== Fire Fighting Measures =====================
Flash Point:38-40C, 100-140F
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:CLASSIFIED AS COMBUSTIBLE. MATERIAL
CONTAINS A COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN THE CONTAINER
HEADSPACE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MAY REQUIRE
NEUTRALIZATION IF PH < 2.0 OR > 12.5. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR
OTHER INERT MATERIAL, THEN PL ACE IN A CONTAINER FOR CHEMICAL
WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM HEAT AND FLAME. USE WITH
ADEQUATE VENTILATION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:DO NOT BREATHE VAPOR AT CONCENTRATIONS GREATER THAN
THE EXPOSURE LIMITS. USE ONLY WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, ON
CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE ORGANIC VAPOR
CARTRIDGE. IF RESPIRATO RS ARE USED, A PROGRAM SHOULD BE INSTITUTED
TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES APPROPRIATE FOR THE RISK OF
EXPOSURE.
Eye Protection:VAPOR TIGHT CHEMICAL GOGGLES, SAFETY GLASSES WITH
FACE/SIDE SHIELDS OR GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, WASHING
FACILITIES. WEAR PROTECTIVE CLOTHING APPROPIATE FOR THE RISK OF
EXPOSURE.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE
LIMITS. ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABL E.
N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
================== Physical/Chemical Properties ==================
HCC:F6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:NOT AVAILABLE
Vapor Density:N/AV
Spec Gravity:1.070
pH:2.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, AMBER COLOR, VINEGAR ODOR.
Percent Volatiles by Volume:85-90 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, BASES, METALS, AMINES
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN.
=================== Toxicological Information ===================
Toxicological Information:BASED ON REPEATED-DOSE INGESTION STUDIES IN
ANIMALS, 1-PHENYL-3-PYRAZOLIDINONE, A COMPONENT OF THIS PRODUCT MAY
CAUSE BLOOD, TESTICULAR, AND ADVERSE REPRODUCTIVE EFFECTS. ACUTE
OVEREXPOSURE TO EXTREME LY HIGH AIRBORNE CONCENTRATIONS OF
RESPIRATORY IRRITANTS HAS BEEN ASSOCIATED WITH DEVELOPMENT OF AN
ASTHMA-LIKE REACTIVE AIRWAYS SYNDROME (RADS) IN SUSCEPTIBLE
INDIVIDUALS. DATA FOR 1-PHENYL-3-PYRAZ OLIDINONE: ACUTE TOXICITY
DATA: ORAL LD-50 (MALE RAT): 476 MG/KG. ORAL LD-50 (FEMALE RAT):
336 MG/KG. DERMAL LD-50: > 1000 MG/KG, ESTIMATED
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 10-100.
DAPHNID EC50 MG/L: 10-100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEG RADABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 1170. BOD5
(APPROXIMATE G/L): 712. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >10 0.
==================== Disposal Considerations ====================
Waste Disposal Methods:MAY REQUIRE NEUTRALIZATION IF PH<2 OR >12.5.
DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE,
OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE
EMPTIED CONTAINERS RETA IN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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