===================== Product Identification =====================
MSDS NAME:139 7215,WKG SOL,KODAK INDUSTREX DEVELOPER REPLENISHER
NIIN:01-353-4889
Status Code:A
MSDS Number: CKZNK
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:85.
Maxumum % Wt:90.
Other REC Limits:NOT PROVIDED
Name:POTASSIUM SULFITE
CAS:10117-38-1
RTECS #:WT3530000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:HYDROQUINONE
CAS:123-31-9
RTECS #:MX3500000
= Wt:2.
Other REC Limits:NOT PROVIDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:POTASSIUM ACETATE
CAS:127-08-2
RTECS #:AJ3325000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:GLUTARALDEHYDE BIS (POTASSIUM BISULFITE)
CAS:68310-08-7
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING
TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: MAY CAUSE ALLERGIC SKIN REACTION B ASED ON HUMAN
EXPERIENCE. PROLONGED OR REPEATED CONTACT WITH AQUEOUS SOLUTIONS
MAY CAUSE IRRITATION. MAY CAUSE SKIN DEPIGMENTATION. INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROI NTESTINAL
TRACT.
Explanation of Carcinogenicity:(COMPONENTS PRESENT AT 0.1% OR MORE):
- INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE -
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH):
NONE - NATIONAL TOXICOLOG Y PROGRAM (NTP): NONE -
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUAL S MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: PROLONGED OR REPEATED CONTACT WITH
AQUEOUS SOLUTIONS MAY CAUSE IRRITATION. MAY CAUSE SKIN
DEPIGMENTATION. INGESTION: MAY CAUSE IRRI TATION OF THE
GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. IF SKIN IRRITATION/ AN ALLERGIC SKIN REACTION
DEVELOPS, GE T MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE
REUSE. INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF
MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL PHYSI CIAN/POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUA L CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION.
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF MIST. AVOID
CONTACT WITH EYES, SKIN, AND CLOTHING. WASH THOROUGHLY AFTER
HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
CLEANER AND REGULAR CL EANING OF WORKING SURFACES, GLOVES, ETC.
WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES APPROPRIATE FOR THE RISK OF
EXPOSURE.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:WEAR PROTECTIVE CLOTHING APPROPRIATE FOR THE
RISK OF EXPOSURE. EYE WASH STATION, SAFETY SHOWER, AND WASHING
FACILITIES.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE
LIMITS. ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE .
N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:18 @ 68F
Vapor Density:0.6
Spec Gravity:1.082
pH:10.4
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW-ORANGE LIQUID, SLIGHT ODOR.
Percent Volatiles by Volume:85-90 BY WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL
MAY REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:SULFUR DIOXIDE, CARBON DIOXIDE, CARBON
MONOXIDE
=================== Toxicological Information ===================
Toxicological Information:IN F-344 RATS, CHRONIC ORAL ADMINISTRATION OF
HYDROQUINONE HAS RESULTED IN THE FORMATION OF BENIGN KIDNEY
TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY.
HYDROQUINONE-INDUCED NEPHROPATHY FOLL OWING ORAL
ADMINISTRATION HAS BEEN NOTED IN THE MALE F-344 RAT, BUT NOT IN
OTHER SPECIES OR RAT STRAINS TESTED. ALTHOUGH AN INCREASE IN
MONONUCLEAR CELL LEUKEMIA IN F-344 FEMALE RATS HA S BEEN
REPORTED FOLLOWING CHRONIC ORAL ADMINISTRATION OF
HYDROQUINONE, THIS FINDING WAS NOT REPRODUCED IN A SUBSEQUENT
STUDY.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10.
DAPHNID EC50 MG/L: 1-10. ALGAL IC50 MG/L: 10-100. ORGANICS
READILY DEGR ADABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 117. BOD5
(APPROXIMATE G/L): 73. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: HYDROQUINONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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