===================== Product Identification =====================
MSDS NAME:MIL-P-24441 F-153 TP IV GRAY F/S 26008 A, MILPB20051
Status Code:A
MSDS Number: CKZMN
=== Responsible Party ===
Company:AMERON INTERNATIONAL PROTECTIVE COATINGS GROUP
Address:201 NORTH BERRY ST.
City:BREA
State:CA
ZIP:92821
Country:US
Info Phone Num:714-529-1951
Emergency Phone Num:800-424-9300
Preparer's Name:H. KLINE
Chemtrec Ind/Phone:(800)424-9300
CAGE:55849
=== Contractor Identification ===
Company:AMERON INTERNATIONAL PROTECTIVE COATINGS GROUP
Address:201 NORTH BERRY ST.
Box:City:BREA
State:CA
ZIP:92821
Country:US
Phone:714-529-1951
CAGE:55849
============= Composition/Information on Ingredients =============
Name:BUTYL ALCOHOL (VAPOR PRESSURE: 4.3 MMHG @ 68F)
CAS:71-36-3
RTECS #:EO1400000
< Wt:23.9
OSHA PEL:150 MG/M3;50 PPM
ACGIH TLV:150 MG/M3; 50PPM
ACGIH STEL:C152 MG/M3;C50 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:POLYAMINE ADDUCT. (CONTAINS BENZYL ALCOHOL) (MFR CAS #:
DATA NOT AVAILABLE)
< Wt:20.
OSHA PEL:DNA
ACGIH TLV:DNA
Name:BENZYL ALCOHOL (IMPURITIES MAY BE BENZALDEHYDE 0.3%,
DIBENZYL ETHER 0.1%, HYDROQUINONE METHYL ETHER 0.025%)
CAS:100-51-6
RTECS #:DN3150000
< Wt:15.
OSHA PEL:DNA
ACGIH TLV:DNA
Name:TITANIUM DIOXIDE (AS TI, POSSIBLE IMPURITIES, AMORPHOUS
SILICA <10%, ALUMINUM HYDROXIDE <6%)
CAS:13463-67-7
RTECS #:XR2275000
< Wt:10.
OSHA PEL:5 MG/M3; PPM=DNA
ACGIH TLV:5 MG/M3; PPM=DNA
Name:MAGNESIUM SILICATE. (RESPIRABLE QUARTZ <0.1%)
CAS:14807-96-6
RTECS #:WW2710000
< Wt:35.
OSHA PEL:2 MG/M3; PPM=DNA
ACGIH TLV:2 MG/M3; PPM=DNA
Name:AMIDO AMINE RESIN. (TEPA @ <5%)
CAS:68443-08-3
< Wt:5.
OSHA PEL:DNA
ACGIH TLV:DNA
===================== Hazards Identification =====================
LD50 LC50 Mixture:AMIDO AMINE RESIN: DERM LD50 1.7 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE ARE LISTED AS A ROUTE OF EXPOSURE
. EXPOSURE EFFECTS: VAPOR OR SPRAY MIST OR SPATTERED MATERIAL CAN
BE HARMFUL. IRRITATING TO EYES, SKIN, AND IF INHALED, TO NOSE AND
THROAT. EXCESSIVE OR PRO LONGED INHALATION CAN CAUSE HEADACHE,
NAUSEA OR DIZZINESS. PROLONGED AND REPEATED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS IS ASSOCIATED WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL ABUSE, MISUSE OR OTHER MASSIVE
EXPOSURE TO SOLVENTS MAY CAUSE MULTIPLE ORGAN DAMAGE AND/OR DEATH.
OVER-EXPOSURE (PROLONGED/REPEATED USE): CAN AGGRAVATE OR ACCENTUATE
ANY OF THESE EFFECTS. (OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT'D):
SKIN: SEVERE IRRITANT. SEVERE BURNS. SENSITIZATION OR ALLERGIC
REACTION, SUCH AS RASH OR HIVES. CAN BE ABSORBED THRU SKIN.
INHALATION: SEVERE IRRITANT. LUN G INJURY. RESPIRATORY
SENSITIZATION AND ALLERGIC REACTION SUCH AS ASTHMA. CENTRAL NERVOUS
SYSTEM DAMAGE. EYES: SEVERE IRRITANT. CORNEAL INJURY. IRREVERSIBLE
BURNS AND DAMAGE. DO NOT WEAR CONTACT LENS ES WHEN USING THIS
MATERIAL. INGESTION: HARMFUL IF SWALLOWED. TARGET ORGANS: KIDNEYS,
LIVER, BLOOD, LUNGS, SKIN, EYES, STOMACH, CENTRAL NERVOUS SYSTEM.
Medical Cond Aggravated by Exposure:KIDNEYS, LIVER, SKIN, EYES,
RESPIRATORY, ALLERGIES.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE NORMAL BREATHING.
TREAT SYMPTOMATICALLY. SEE PHYSICIAN. SKIN: WASH THOROUGHLY WITH
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT PHYSICIAN IF
IRRITATI ON PERSISTS. EYES: FLUSH IMMEDIATELY WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. INGESTION:
DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY
MOUTH TO UNCON SCIOUS PERSON. DO NOT INDUCE VOMITING (UNLESS
METHANOL). CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=35.6C, 96.F
Lower Limits:1.4%
Upper Limits:11.2%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL. FLAMMABILITY: OSHA:
FLAMMABLE - CLASS IC. LOWEST FLASHING SOLVENT: 71-36-3.
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT, NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE USED TO COOL
CONTAINERS TO PREVENT PRESSURE BUILD-UP OR EXPLOSION WHEN EXPOSED
TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT AND PRESSURE BUILDUP. MAY PRODUCE A
FLOATING FIRE HAZARD. ISOLATE FROM ELECTRICAL EQUIPMENT, SPARKS,
HEAT AND OPEN FLAME. VAPORS MAY SPREAD L ONG DISTANCE, CAUSE FLASH
FIRE OR IGNITE EXPLOSIVELY.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS. VENTILATE AREA. USE ABSORBENT, INERT CLEANUP
MATERIALS (DO NOT USE SAWDUST). REMOVE ABSORBENT MATERIALS WITH
NON-SPARKING TOOLS. PLACE IN SEPARA TE CONTAINER. KEEP OUT OF
SEWERS AND WATERWAYS. IF ENTRY IS THREATENED OR OCCURS, NOTIFY
LOCAL AUTHORITIES.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN
NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID
PROLONGED STORAGE TEMPERATURES ABOVE 100F. USE CAUTION WHEN
POURING. AVOID BREATHING SANDING DUST. DO NO T WELD OR FLAME CUT ON
EMPTY CONTAINER.
Other Precautions:PREVENT SKIN CONTACT. PROTECT EYES FROM SPLASH,
SPATTER AND/OR SPRAY MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH-CERTIFIED RESPIRATOR DESIGNED TO
REMOVE COMBINATION OF PARTICULATES (DUST/SPRAY MIST) & VAPOR. WHEN
BRUSHING, ROLLING, OR SPREADING; SELECT APPROPRIATE RESPIRATORY
PROTECTION FOR CONDITIONS . FOR SPECIFIC CONDITIONS, REFER TO
CURRENT "NIOSH POCKET GUIDE TO CHEMICAL HAZARDS". IN CONFINED OR
RESTRICTED VENTILATION AREAS USE AIR- LINE (OTHER INFO)
Ventilation:IMPLEMENT ADMINISTRATIVE & ENGINEERING CONTROLS TO REDUCE
EXPOSURE. PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO
KEEP AIR CONTAMINANT (SUPPL SAFETY)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:SOLVENT-RESISTANT GLASSES WITH SPLASH GUARDS OR FACE
SHIELDS. (SUPP SAFETY)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . RESISTANT COVERALLS, GLOVES, SHOE COVERINGS. USE
EXPLOSION AND SPARK-PROOF EQUIPMENT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING,
SMOKING, USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES WHICH CANNOT BE
DECONTAMINATED.
Supplemental Safety and Health
(VENT)-CONCENTRATIONS BELOW TLV LIMITS. REMOVE WELDING/FLAME-CUTTING
DECOMPOSITON PRODUCTS; FOLLOW CURRENT ANSI Z49.1 "SAFETY IN WELDING
AND CUTTING." REFER TO 29 CFR PARTS 1910/1915 FOR COATING OPERA
TIONS; PART 1910.146, CONFINED SPACES. EYE PROTECTION: CONSULT 29
CFR 1910.132, 133, 136, 138; ANSI Z87.1, Z41.
================== Physical/Chemical Properties ==================
Boiling Pt:=117.8C, 244.F
B.P. Text:244-244F
Vapor Density:HEAV AIR
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:NO
Appearance and Odor:LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume:39.56
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS AND ALKALIES.
Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. EPOXIES
UNDER UNCONTROLLED CONDITIONS. THIS PRODUCT IS STABLE UNDER NORMAL
STORAGE CONDITIONS.
Hazardous Decomposition Products:(BY FIRE, BURING OR WELDING): CO, CO2.
NOX. ALDEHYDES. TOXIC GASES OR FUMES. METHYL MERCAPTAN.
Conditions to Avoid Polymerization:WILL NOT OCCUR UNDER NORMAL STORAGE
CONDITONS.
=================== Toxicological Information ===================
Toxicological Information:LD50 (G/KG): MAGNESIUM SILICATE: DATA NOT
AVAILABLE; BUTYL ALCOHOL: 4.200; POLYAMINE ADDUCT: 2.000; BENZYL
ALCOHOL: 2.000; TITANIUM DIOXIDE: 10.000; AMIDO AMINE RESIN: 1.700.
LC50 (PPM): MAGNESIUM S ILICATE: DATA NOT AVAILABLE; BUTYL
ALCOHOL: 8000.000; POLYAMINE ADDUCT: DATA NOT AVAILABLE; BENZYL
ALCOHOL: 1000.000; +TITANIUM DIOXIDE: 6820.000; AMIDO AMINE RESIN:
DATA NOT AVAILABLE. LD50=DERMAL, RABBIT; LC50=INHALATION, RAT.
===================== Ecological Information =====================
Ecological:NO INFORMATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA WASTE NO.: D001. PLACE IN SEPARATE,
APPROPRIATE CLOSED CONTAINER IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN
TESTED BY TOXICITY CHARACTERISTI C LEACHING PROCEDURE (TCLP).
=================== MSDS Transport Information ===================
Transport Information:D.O.T. PROPER SHIPPING NAME: PAINT. D.O.T. HAZARD
CLASS: 3. HAZARD SUBCLASS: NA. , PACKING GROUP: III. , IMO: NA.
D.O.T. UN/NA NUMBER: 1263. D.O.T.: FLAMMABLE.
===================== Regulatory Information =====================
SARA Title III Information:TOXIC CHEMICALS MARKED (SARA, CERCLA, HAPS)
ARE SUBJECT TO REPORTING REQUIREMENTS OF SARA (40CFR 355/372),
CERCLA (40CFR 302) OR HAPS (40CFR 63): BUTYL ALCOHOL
Federal Regulatory Information:ALL INGREDIENTS ARE ON TSCA INVENTORY OR
ARE EXEMPT. TITANIUM DIOXIDE: PIGMENT CONTENT IS DEPENDENT ON
COLOR. OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200). INTERN ATIONAL REGULATIONS: CANADIAN
WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED
PRODUCT REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS. CANADIAN
WHMIS CLASS: NO INFORMATION AVAILABLE. C ERCLA: BUTYL ALCOHOL.
State Regulatory Information:CALIFORNIA TITLE 26: 22-12000 (PROP 65).
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO STATE OF CA TO
CAUSE CANCER:MAGNESIUM SILICATE ( RESPIRABLE QUARTZ). NEW JERSEY
RIGHT-TO-KNOW: FOLLOWING MAT ERIALS ARE NON-HAZARDOUS, BUT ARE
AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: NO NON-HAZARDOUS
MATERIALS ARE AMONG THE TOP FIVE INGREDIENTS. PENNSYLVANIA
RIGHT-TO-KNOW: FOLLOWING NON-HAZARDOUS INGR EDIENTS PRESENT IN
PRODUCT AT GREATER THAN 3%: NO NON-HAZARDOUS INGREDIENTS PRESENT AT
GREATER THAN 3%.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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