===================== Product Identification =====================
MSDS NAME:139 7215, PT A, KODAK INDUSTREX DEVELOPER REPLENISHER
NIIN:01-353-4889
Status Code:A
Kit Part:Y
MSDS Number: CKZNG
=== Responsible Party ===
Company:EASTMAN KODAK CO.
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:60.
Maxumum % Wt:65.
Other REC Limits:NOT PROVIDED
Name:POTASSIUM SULFITE
CAS:10117-38-1
RTECS #:WT3530000
Minumum % Wt:20.
Maxumum % Wt:25.
Other REC Limits:NOT PROVIDED
Name:HYDROQUINONE
CAS:123-31-9
RTECS #:MX3500000
= Wt:9.
Other REC Limits:NOT PROVIDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:SODIUM BROMIDE
CAS:7647-15-6
RTECS #:VZ3150000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DI OXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: MAY CAUSE ALLERGIC SKIN REACTION BASE D ON HUMAN
EXPERIENCE. PROLONGED OR REPEATED CONTACT WITH AQUEOUS SOLUTIONS
MAY CAUSE IRRITATION. MAY CAUSE SKIN DEPIGMENTATION. INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTE STINAL
TRACT.
Explanation of Carcinogenicity:(COMPONENTS PRESENT AT 0.1% OR MORE): -
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN
CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE -
NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND
HEALTH ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUAL S MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: MAY CAUSE ALLERGIC SKIN REACTION
BASED ON HUMAN EXPERIENCE. PROLONGED OR REPEATED CONTACT WITH
AQUEOUS SOLUTIONS MAY CAUSE IRRITATI ON. MAY CAUSE SKIN
DEPIGMENTATION. INGESTION: MAY CAUSE IRRITATION OF THE
GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION IF S YMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND
SHOES. IF SKIN IRRITATION/ ALLERGIC SKIN REACTION DEVELOPS, GET
MEDICAL ATTENTION. W ASH CONTAMINATED CLOTHING BEFORE REUSE. CLEAN
CONTAMINATED SHOES. INGESTION: ONLY INDUCE VOMITING AT INSTRUCTION
OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS
PERSON. CALL PHYSICIA N OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF MIST. AVOID
CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A
NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF
WORKING SURFACES, GLOVES, ETC. WILL HELP MINIMIZE POSSIBILIT Y OF
SKIN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A FACE
SHIELD.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE
LIMITS. ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE .
N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
================== Physical/Chemical Properties ==================
HCC:F6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:24 MBAR 18 MMHG @ 68F
Vapor Density:0.6
Spec Gravity:1.310
pH:12.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, OFF-WHITE, ODORLESS.
Percent Volatiles by Volume:60-65 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:STABLE
Hazardous Decomposition Products:SULFUR DIOXIDE, CARBON DIOXIDE, CARBON
MONOXIDE.
=================== Toxicological Information ===================
Toxicological Information:INGESTION OF BROMIDE SALTS CAN CAUSE NAUSEA,
VOMITING, HEADACHE, IRRITABILITY, DELIRIUM, MEMORY LOSS,
DECREASED APPETITE, JOINT PAIN, HALLUCINATIONS, STUPOR, COMA,
AND ACNELIKE RASH ON FACE, LEGS, AND TRUNK. IN F-344 RATS,
CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN
THE FORMATION OF BENIGN KIDNEY TUMORS THOUGHT TO BE SECONDARY
TO NEPHROPATHY.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10.
DAPHNID EC50 MG/L: <1. ALGAL IC50 MG/L: 1-10. ORGANICS READILY
DEGRADAB LE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE G/L): 189. BOD5 (APPROXIMATE G/L): 119.
POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L):
>100.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: HYDROQUINONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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