===================== Product Identification =====================
MSDS NAME:ETHYL ALCOHOL 200 PROOF SDA 3A, COMPONENT OF HT25-1
Status Code:A
MSDS Number: CKZKM
=== Responsible Party ===
Company:SIGMA-ALDRICH CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
= Wt:5.
OSHA PEL:260 MG/M3;200 PPM
OSHA STEL:310 MG/M3; 250 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHYL ALCOHOL. (MF: C2H6O). (EC NO: 200-578-6)
CAS:64-17-5
RTECS #:KQ6300000
Other REC Limits:1000 PPM NIOSH TWA
OSHA PEL:1000 PPM, 1900 MG/M3
ACGIH TLV:1000 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORL-RAT LD50: 7060 MG/KG (ETHYL ALCOHOL)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE FATAL IF
INHALED, SWALLOWED, ABSORBED THROUGH SKIN. VAPOR OR MIST IS
IRRITATING TO EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
CAUSES SKIN IRRITATION. CAN CAUSE CNS DEPRE SSION. EXPOSURE CAN
CAUSE DAMAGE TO EYES, NAUSEA, DIZZINESS AND HEADACHE. CHRONIC
EFFECTS: DAMAGE TO THE LIVER. DAMAGE TO THE HEART. DAMAGE TO THE
KIDNEYS. TARGET ORGANS: NERVES, EYES, LIVER, KIDNEYS. ADDITIONAL
INFORMATION: WARNING: CONTAINS METHANOL. MAY BE FATAL OR CAUSE
BLINDNESS IF SWALLOWED. CANNOT BE MADE NONPOISIONOUS.
Effects of Overexposure:SEE HEALTH HAZARDS ACUTE AND CHRONIC.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF THE
EYES BY SEPARATI NG THE EYELIDS WITH FINGERS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH
WITH WATER PROVIDED PER SON IS CONSCIOUS. CALL A PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Flash Point:=12.8C, 55.F
Autoignition Temp:=361.7C, 683.F
Lower Limits:3.3%
Upper Limits:24.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR NIOSH-APPROVED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. USE
WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WARNING: FLAMMABLE
LIQUID.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. EVACUATE
AREA. WEAR SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED - ),
RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE
AND PLACE IN CLOSE D OCNTAINERS FOR DISPOSAL. USE NONSPARKING
TOOLS. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING. POISON. IRRITANT. KEEP TIGHTLY
CLOSED. KEEP AWAY FROM HEAT, SPARKS , AND OPEN FLAME. STORE IN A
COOL DRY PLACE.
Other Precautions:LABEL PRECAUTIONARY STATEMENTS: FLAMMABLE (USA
DEFINITION). HIGHLY FLAMMABLE (EUROPEAN DEFINITION). TOXIC. DANGER:
POISON. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. VAPOR
HARMFUL. CANNOT BE MADE N ON-POISONOUS. KEEP CONTAINER TIGHTLY
CLOSED. KEEP AWAY FROM SOURCES OF IGNITION. NO SMOKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:SAFETY GOGGLES (ANSI APPROVED - ).
Other Protective Equipment:SAFETY SHOWER AND EYE BATH MEETING ANSI
DESIGN CRITERIA . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:AVOID PROLONGED OR REPEATED EXPOSURE. WASH
THOROUGHLY AFTER HANDLING. DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING.
Supplemental Safety and Health
SARA TITLE III (CONT'D): DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLETE INFORMATION.
================== Physical/Chemical Properties ==================
Vapor Pres:44.6 MM 20 C
Vapor Density:1.59
Spec Gravity:0.791
Appearance and Odor:LIQUID. ODOR: NONE SPECIFIED BY MANUFACTURER .
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALKALI METALS, AMMONIA, MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:IRRITATION DATA: SKN-RBT 400 MG OPEN MLD;
UCDS 7/22/70. SKN-RBT 20 MG/24H MOD; 85JCAE -,189,86. EYE-RBT 500
MG SEV; AJOPAA 29,1363,46. EYE-RBT 500 MG/24H MLD; 85JCAE -,189,86.
EYE-RBT 100 MG/4S RINSE MOD; FCTOD7 20,573,82. TOXICITY DATA:
ORL-CHO LDLO: 2 GM/KG; ATXKA8 17,183,58. ORL-HMN LDLO: 1400 MG/KG;
NPIRI 1,44,74. SCU-INF LDLO: 944 MG/KG; AJCPAI 5,466,35. ORL-RAT
LD50: 7060 MG/KG; TXAPA9 16,7 18,70. IHL-RAT LC50: 20000 PPM/10H;
NPIRI* 1,44,74. IPR-RAT LC50: 3600 UG/KG; PHMGBN 2,27,69. IV-RAT
LD50: 1440 MG/KG; TXAPA9 18,60,71. IAT-RAT LD50: 11 MG/KG; TXAPA9
18,60,71. ORL-MUS LD50: 3450 MG/K G; GISAAA 32(3),31,67.
(ECOLOGICAL)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE. TOXICOLOGICAL INFO (CONT): IHL-MUS
LC50: 39 G/M3/4H; GTPZAB 26(8),53,82. IPR-MUS LD50: 933 MG/KG;
SCCUR* -,5,61. SCU-MUS LD50: 8285 MG/KG FAONAU 48A,99,70. IVN-MUS
LD50: 1973 MG/KG; HBTXAC 1,128,55. ORL-RBT LD50: 6300 MG/KG;
HBTXAC 1,130,55. IPR-RBT LD50: 963 MG/KG; EVHPAZ 61,321,85. IVN-RBT
LD50:2374 MG/KG; EVHPAZ 61,321,85. ORL-GPG LD50: 5560 MG/KG; JIHTAB
23,259,41. IPR -GPG LD50: 3414 MG/KG; EVHPAZ 61,321,85. IPR-HAM
LD50: 5068 MG/KG; EVHPAZ 61,321,85. IRP-MAM LD50: 4300 MG/KG;
TXAPA9 13,358,68. TARGET ORGAN DATA: BEHAVIORAL (SLEEP, CHANGE IN
MOTOR ACTIVITY, ATAXIA , ANTOPSYCHOTIC, HDCH, (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULAT IONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORATION
INFORMATION. ECOLOGICAL INFO (CONT): BEHAVIORAL (CHANGE IN
PSYCHOPHYSIOLOGICAL TESTS). LUNGS, THORAX OR RESPIRATION (CHRONIC
PULMONARY EDEMA OR CONGES TION). LUNGS, THORAX OR RESPIRATION
(DYSPNAE). LUNGS, THORAX OR RESPIRATION (OTHER CHANGES).
GASTROINTESTINAL (ALTERATION IN GASTRIC SECRETION). GI
(HYPERMOTILITY, DIARRHEA). GI (NAUSEA OR VOMITING). GI (OTHER
CHANGES). LIVER (FATTY LIVER DEGENERATION). LIVER (TUMORS). BLOOD
(OTHER CHANGES). BLOOD (LYMPHOMA INCLUDING HODGKIN'S DISEASE).
PATERNAL EFFECTS (TESTES, EPIDIDYMUS, SPERM DUCT). EFFECTS ON
FERTILITY: FEMALE (SARA III)
===================== Regulatory Information =====================
SARA Title III Information:5.0% METHANOL 67-56-1. THIS PRODUCT IS
SUBJECT SARA SECTION 313 REPORTING REQUIREMENTS. TRANSPORT
INFO (CONT): FERTILITY INDEX, MALE FERTILITY INDEX,
POST-IMPLANTATION MORTALITY, OTHER MEASUR ES OF FERTILITY. EFFECTS
ON EMBRYO OR FETUS: EXTRA EMBRYONIC STRUCTURES, CYTOLOGICAL
CHANGES, FETOTOXICITY, FETAL DEATH, OTHER EFFECTS TO EMBRYO OR
FETUS. SPECIFIC DEVELOPMENTAL ABNORMALITIES: EYE, EA R,
CRANIOFACIAL, MUSCULOSKELETAL & RESPIRATORY SYSTEM. EFFECTS ON
NEWBORN (GROWTH STATISTICS). TUMORIGENIC (EQUIVOCAL TUMORIGENIC
AGENT BY RTECS CRITERIA. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF
CH EMICAL SUBSTANCES (RTECS) (SUPP SAFETY)
Federal Regulatory Information:EUROPEAN INFO: EC INDEX NO:
603-002-00-5. HIGHLY FLAMMABLE. TOXIC. HIGHLY FLAMMABLE. S 7 - KEEP
CONTAINER TIGHTLY CLOSED. S 16 - KEEP AWAY FROM SOURCES OF
IGNITION. NO SMOKING. S 23 - DO NOT BREATHE V APOR. REVIEWS,
STANDARDS & REGULATIONS:ACGIH TLV-TWA 1000 PPM; 85INA8 6,575,91.
IARC CANCER REVIEW: ANIMAL INADEQUATE EVIDENCE; IMEMDT 44,35,88.
EPA FIFRA 1988 PESTICIDE SUBJECT TOREGISTRATION OR RE-R
EGISTRATION; FEREAC 54,7740,89. MSHA STANDARD-AIR: TWA 1000 PPM
(1900 MG/M3); DTLVS 3,103,71. OSHA P EL (GEN INDU): 8H TWA 1000 PPM
(1900 MG/M3); CFRGBR 29,1910.1000,94. OSHA PEL (CONSTRUC): 8H TWA
1000 PPM (1900 MG/M3). (STATE REGS)
State Regulatory Information:FEDERAL REGS (CONT): OSHA PEL (SHIPYARD):
8H TWA 1000 PPM (1900 MG/M3). OSHA PEL (FED CONT): 8H TWA 1000 PPM
(1900 MG/M3).NIOSH REL TO ETHYL ALCOHOL - AIR: 10H TWA 1000 PPM:
NIOSH DHHS #92-100,92. NOH S 1974: HZD 31500; NIS 430; TNF 157709;
NOS 242;TNE 2088926. NOES 1983: HZD 31500; NIS 334; TNF 86077; NOS
222; TNE 2069125; TFE 1014002. EPA GENETOX PROGRAM 1988, POSITIVE:
RODENT DOMINANT LETHAL; NE GATIVE: ASPERGILLUS-FORWARD MUTATION,
CELL TRANSFORM., IN VITRO CYTOGENETICS-NONHUMAN, N CRASSA-ANEU
PLOIDY, IN VITRO SCE. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY.
(CONTACT NAVY ENVIRONMENTAL HEALTH CENTER FOR ADDITIONAL INFO).
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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