===================== Product Identification =====================
MSDS NAME:NITROGEN
NIIN:00-616-9183
MSDS Number: BHFRH
=== Responsible Party ===
Company:UNION CARBIDE CORPORATION
Address:39 OLD RIDGEBURY ROAD
Box:NA
City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Info Phone Num:ROUTINE INFO CONTACT LOCAL SUPPLIER
Emergency Phone Num:1-800-822-4357 CANADA 514-640-6400
CAGE:36346
=== Contractor Identification ===
Company:HAMPTON ROADS SUPPLY UNION CARBIDE LINDE DIVISION
Address:3450 VIRGINIA BEACH BLVD
Box:12567
City:NORFOLK
State:VA
ZIP:23502-3123
Country:US
CAGE:7D711
Company:UNION CARBIDE CORP LINDE DIV
Address:39 OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Phone:800-822-4357; 304-744-3487
CAGE:36346
============= Composition/Information on Ingredients =============
Name:NITROGEN
CAS:7727-37-9
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SWALLOW: GAS AT NORMAL TEMP &
PRESSURE. SKIN: NO EVIDENCE OF ADVERSE EFFECTS FROM AVAILABLE INFO.
INHAL: ASPHYXIANT. MODERATE CONCEN MAY CAUSE
HEADACHE,DROWS,DIZZ,EXCITATION, EXCESS SALIVATION, VOMIT & UNCONS.
LACK OF OXYGEN-DEATH. SKIN: NOHARMFUL EFFECT EXPECTED FROM VAPOR.
LIQ FROSTBITE. EYE: NO HARMFUL EFFECT EXPECT
Effects of Overexposure:SWALLOW: GAS AT NORMAL TEMP & PRESSURE SKIN: NO
EVID/ADVERSE EFFECTS FROM AVAILABLE INFO. INHAL: ASPHYXIANT. MOD
CONCEN; HEADACHE,DROWS,DIZZ,EXCITATION,EXCESS SALIVATION, VOMIT &
UNCONS. LACK OF OXYGE N-DEATH. EYE: NO HARMFUL EFFECT EXPECTEDFROM
VAPOR
Medical Cond Aggravated by Exposure:TOXICOLOGY AND THE PHYSICAL & CHEM
PROPERTIES OF THE MATERIAL DO NOT SUGGEST THAT OVEREXPOSURE IS
LIKELY TO AGGRAVATE EXISTING MEDICAL CONDITIONS
======================= First Aid Measures =======================
First Aid:SWALLOW: GAS AT NORMAL TEMP & PRESSURE. SKIN: EXPOSURE TO
LIQ, IMMED WARM FROSTBITE AREA WITH WARM WATER (NOT TO EXCEED 105F)
IN CASE OF MASSIVE EXPOSURE, REMOVE CLOTHING HWILE SHOWERING WITH
WARRM WA TER. CALL PHYSICIAN. INHAL: REMOVE TO FRESH AIR. GIVE CPR.
GIVE OXYGEN IF BREATH DIFF. CALL PHYSICIAN. EYE: IMMED FLUSH
THOROUGHLY WITH WATER 15 MIN. SEE PHYSICIAN, PREFERABLEY AN
OPHTHALMOLOGIST IMMD
===================== Fire Fighting Measures =====================
Flash Point:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NITROGEN CANNOT CATCH FIRE. USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE
Fire Fighting Procedures:EVACUATE ALL PERSONNEL FROM DANGER AREA.
IMMEDIATELY DELUGE CONTAINERS WITH WATER SPRAY FROM MAX DISTANCE
UNTIL COOL, MOVE CONTAINER AWAY FROM FIRE IF NO RISK
Unusual Fire/Explosion Hazard:GAS CANNOT CATCH FIRE. MAY RUPTURE DUE TO
HEAT OF FIRE. NO PART OF CONT SHOULD BE SUBJECTED TO A TEMP HIGHER
THAN APPR 125F. MOST CONT DESIGN TO VENT ELE TEMP
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE DANGER AREA. SELF CONTAINED BREATHING
APPARATUS WHERE NEEDED. SHUT OFF LEAK IF WITHOUT RISKVENT AREA OR
MOVE LEAKING CONTAINER TO WELL VENTEDAREA. TEST AREA, ESP CONFINED
AREAS, FOR SUFFICIEN T OXYGEN CONTENT PRIOR TO RE-ENTRY OF
PERSONNEL
====================== Handling and Storage ======================
Handling and Storage Precautions:NEVER WORK ON PRESSURIZED SYSTEM. IF
THERE IS A LIAK, CLOSED THE CYLINDER VALVE, BLOW DOWN THE SYSTEM BY
VENTING TO A SAFE PLACE, THEN REPAIR THE LEAK
Other Precautions:HIGH PRESSURE GAS. USE PIPING & EQUIPMENT ADEQUATELY
DESINGED TO WITHSTAND PRESSURES TO BE ENCOUTERED. CAN CAUSE RAPID
SUFFOCATION DUE TO OXYGEN DEFICIENCY. STORE & USE WITH ADEQUATE
VENT. CLOSE VALVE WHEN NOT IN USE AND WHEN EMPTY
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT IN ACCORDANCE WITH OSHA 29 CFR 1910.134.
RESPIRATORS SHALL BE ACCEPTABLE TO MSHA AND NIOSH
Ventilation:LOCAL PREFERRED. MECHANICAL ACCEPTABLE.
Protective Gloves:PREFERRED FOR CYLINDER HANDLING
Eye Protection:SELECT IN ACCORDANCE WITH OSHA
Other Protective Equipment:METATARSAL SHOES FOR CYLINDER HANDLING.
SELECT IN ACCORDANCEWITH OSHA 29 CFR 1910.132 AND 1910.133
Work Hygienic Practices:GOOD GENERAL HYGIENE PRACTICES
Supplemental Safety and Health
NOTE TO PHYSICIAN: THERE IS NOT SPECIFIC ANTIDOTE. TREATMENT SHOULD BE
DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION.
ALSO SUITABILITY FOR USE AS A COMPONENT IN UNDERWATER BREATHING G
AS MIXTURES IS TO BE DETERMINED BY OR UNDER THE SUPERVISION OF
PERSONNEL EXPERIENCED IN THE USE OF UNDERWATER BREATHING
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:210.36 F
Vapor Pres:GAS
Vapor Density:0.967
Spec Gravity:GAS
Evaporation Rate & Reference:NA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS AT NORMAL TEMPERATURE AND
PRESSURE
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
UNDER CERTAIN CONDITION, NITROGEN CAN REACT VIOLENTLY WITH LITHIUM,
NEODYMIUM, TITANIUM, & OZONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:SLOWLY RELEASE INTO ATMOSPHERE. DISCARD ANY
PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIR
ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDSTATE AND LOCAL REG.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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