===================== Product Identification =====================
MSDS NAME:MALATHION 8 SPRAY
NIIN:00N011386
MSDS Number: BHZDD
=== Responsible Party ===
Company:WILBUR-ELLIS CO (AG SERVICES CORPORATE OFFICE)
Box:16458
City:FRESNO
State:CA
ZIP:93755
Country:US
Info Phone Num:209-226-1934
Emergency Phone Num:209-226-1934;800-424-9300 CHEMTREC
Preparer's Name:THOMAS L SLATTERLY
CAGE:5M441
=== Contractor Identification ===
Company:WILBUR-ELLIS CO
Box:16458
City:FRESNO
State:CA
ZIP:93755
Country:US
Phone:209-226-1934
CAGE:5M441
============= Composition/Information on Ingredients =============
Name:MALATHION (SARA III)
CAS:121-75-5
RTECS #:WM8400000
Fraction by Wt: 81.2%
Other REC Limits:N/K
OSHA PEL:S, 15 MG/M3
ACGIH TLV:S, 10 MG/M3; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Other REC Limits:N/K
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Other REC Limits:N/K
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:NAPHTHA SOLVENT.PART OF INGREDIENT 5.
CAS:64742-95-6
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TENNECO 500-100
Fraction by Wt: 8.8%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 RAT ORAL ACUTE 370 MG/KG,(SEE SUPP)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAN BE FATAL.CAN BE A SKIN
SENSITIZER.CAN BE ABSORBED THROUGH THE SKIN.MALATHION IS A
CHOLINESTERASE INHIBITOR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:N/K .SKIN:CAN BE A
SENSITIZER.INGESTION/INHALATION/SKIN ABSORPTION:(MALATHION IS A
CHOLINESTERASE INHIBITOR.)WEAKNESS,HEADACHE,TIGHT CHEST,BLURRED
VISION,EXCESSIVE SWEATING AND SALIVAT
ION,NAUSEA,VOMITING,DIARRHEA,PINPOINT PUPILS,ABDOMINAL
CRAMPS.CHRONIC EXPOSURE:POSSIBLE CHOLINESTERASE DEPRESSION.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS INVOLVING
SYMPTOMS OF OVEREXPOSURE MAY BE AGGRAVATED.
======================= First Aid Measures =======================
Eyes:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.GET PROMPT
MEDICAL ATTENTION.SKIN:REMOVE CONTAMINATED CLOTHING AND SHOWER WITH
SOAP AND WATER.GET PROMPT MEDICAL ATTENTION.INGESTION:GIVE SEVERAL
GLASSES OF WATER AND INDUCE VOMITING.DO NOT INDUCE VOMITING IF
PERSON IS UNCONSCIOUS.GET PROMPT MEDICAL
ATTENTION.INHALATION:REMOVE VICTIM TO FRESH AIR.GET PROMPT MED
ATTN.NOTE:ATROPINE & 2-PAM ARE ANTIDOTAL.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:114F,46C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER FOG,FOAM,CO*2,DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD POS PRESS SCBA,FULL
PROT EQUIP.FIGHT FIRE UPWIND.EVACUATE PERS DOWNWIND.VAP/FUME
HAZARDOUS.DIKE TO PVNT ENTRY TO DRAIN,SEWER,WATERWAYS.
Unusual Fire/Explosion Hazard:VAPORS CAN READILY FORM EXPLOSIVE
MIXTURES IN AIR.VAPORS AND FUMES ARE HAZARDOUS.HAZARDOUS
DECOMPOSITION PRODUCTS:CO,CO*2,SO*2,H*2S,PHOSPHORUS TRIOXIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE RESP PROT EQUIP.ABSORB W/
INERT MATL & PLACE IN APPRVD DISP CONTRS.TREAT CONTAM AREA W/ LIQ
HOUSEHOLD CHLORINE.LEAVE 15 MIN & REPEAT.FLUSH W/ H*2O.ABSORB W/
INERT MATL.DIKE TO PVNT EN TRY TO DRAINS,SEWERS,WATERWAYS (TOX TO
BEES,FISH).
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR HEAT,SPARKS,OPEN
FLAME,FOOD,FEED.DO NOT INGEST.AVOID PRLNG/RPTD BREATHING OF
VAP,FUME,SPRAY MIST.AVOID SKIN CONT.KEEP OUT OF EYES.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.READ AND FOLLOW ALL
LABEL INSTRUCTIONS.STORE IN A WELL-VENTILATED AREA.ALLOW CLOSED
TRUCKS ADEQUATE TIME TO VENTILATE PRIOR TO ENTERING.WASH BEFORE
EATING,DRINKING,SMOKIN G.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NEOPRENE BOOTS,APRON,HAT,LONG-SLEEVED
COVERALLS.SHOWER AFTER WORK SHIFT (PROD
MANUFACTURE,FORMULATION,APPLICATION).
Work Hygienic Practices:WASH BEFORE EATING,DRINKING OR SMOKING.SHOWER
AFTER WORK SHIFT (PROD MANUFACTURE,FORMULATION,APPLICATION).
Supplemental Safety and Health
VP:0.00004 MMHG @ 30C,86F (TECHNICAL MATL).MP:37.13F,3C (TECHNICAL
MATL).LD50-LC50 MIX:RABBIT DERMAL 4100 MG/KG (TECHNICAL
MATL).ROUTES OF ENTRY:INHALATION,SKIN,INGESTION .SARA HAZARD
CATEGORIES :ACUTE,CHRONIC AND FLAMMABLE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:N/K
Melt/Freeze Pt:M.P/F.P Text:SEE SUPP
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Spec Gravity:1.18 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:SLIGHT
Appearance and Odor:MERCAPTAN ODOR/YELLOW LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES,ALKALIES,OXIDIZERS.
Stability Condition to Avoid:AVOID TEMPERATURES >120F,49C (UNSTABLE).
Hazardous Decomposition Products:CO,CO*2,SO*2,H*2S,PHOSPHORUS TRIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .PLACE IN DOT-APPROVED
CONTAINERS AND DISPOSE OF IN AN EPA CLASS I DISPOSAL SITE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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