===================== Product Identification =====================
MSDS NAME:DIAZINON 4 SPRAY
NIIN:00N011366
MSDS Number: BHZCY
=== Responsible Party ===
Company:WILBUR-ELLIS CO (AG SERVICES CORPORATE OFFICE)
Box:16458
City:FRESNO
State:CA
ZIP:93755
Country:US
Info Phone Num:209-226-1934
Emergency Phone Num:209-226-1934;800-424-9300 CHEMTREC
Preparer's Name:THOMAS L SLATTERLY
CAGE:5M441
=== Contractor Identification ===
Company:WILBUR-ELLIS CO
Box:16458
City:FRESNO
State:CA
ZIP:93755
Country:US
Phone:209-226-1934
CAGE:5M441
============= Composition/Information on Ingredients =============
Name:DIAZINON (SARA III)
CAS:333-41-5
RTECS #:TF3325000
Fraction by Wt: 48.72%
Other REC Limits:N/K
OSHA PEL:S, 0.1 MG/M3
ACGIH TLV:S, 0.1 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Other REC Limits:N/K
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Other REC Limits:N/K
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:NAPHTHA SOLVENT.PART OF INGREDIENT 5.
CAS:64742-95-6
Other REC Limits:100 PPM
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TENNECO 500-100
Fraction by Wt: 8.8%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 RAT ORAL ACUTE 76 MG/KG,(SEE SUPP)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAN BE ABSORBED THROUGH SKIN.INGESTION
CAN BE FATAL.CAN CAUSE RESPIRATORY DEPRESSION,WHICH CAN BE
FATAL.DIAZINON IS A CHOLINESTERASE INHIBITOR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:MILD IRRITATION.SKIN:CAN BE
ABSORBED.INGEST/INHALATION/SKIN ABSORPTION:DIAZINON IS A
CHOLINESTERASE INHIBITOR.HEADACHE,DIZZINESS,WEAKNESS,BLURRED
VISION,EXCESSIVE SWEATING AND SALIVATION,TIGHT CH
EST,NAUSEA,TREMORS,DIARRHEA,REPIRATORY DEPRESSION,(WHICH CAN BE
FATAL).CHRONIC EXPOS CAUSES CHOLINESTERASE DEPRESSION.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS INVOLVING
SYMPTOMS OF OVEREXPOSURE MAY BE AGGRAVATED.
======================= First Aid Measures =======================
Eyes:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.GET PROMPT
MEDICAL ATTENTION.SKIN:REMOVE CONTAMINATED CLOTHING AND SHOWER WITH
SOAP AND WATER.GET PROMPT MEDICAL ATTENTION.INGESTION:GIVE SEVERAL
GLASSES OF WATER AND INDUCE VOMITING.DO NOT INDUCE VOMITING IF
PERSON IS UNCONSCIOUS.GET PROMPT MEDICAL
ATTENTION.INHALATION:REMOVE VICTIM TO FRESH AIR.GET PROMPT MED
ATTN.NOTE:ATROPINE & 2-PAM ARE ANTIDOTAL.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:122F,50C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER FOG,FOAM,CO*2,DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD POS PRESS SCBA,FULL
PROT EQUIP.FIGHT FIRE UPWIND.AVOID BRTHG MIST/VAP,CONT W/
FALLOUT,RUNOFF.DIKE (PVNT ENTRY TO WATERWAYS,(SEE SUPP)
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION
PRODUCTS:NO*X,PO*X,SO*X.TRACES OF WATER CAUSE HYDROLYSIS TO TEPP
DERIVATIVES (WILL NOT OCCUR WITH EXCESS WATER).
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROP RESP,PERSONAL PROT
EQUIP.VACUUM/SWEEP UP,PUT IN APPRVD DISP CONTR.TREAT CONTAM AREA W/
CAUSTIC SODA,ABSORB W/ INERT MATL.REPEAT W/ DETERGENT & H*2O.PLACE
IN APPRVD CONTR.DIKE TO PVNT ENTRY TO DRAINS,SEWERS,WATERWAYS:TOX
TO FISH,WILDLIFE.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY PLACE AWAY FROM OPEN
FLAME,SPARKS,IGNITION SOURCES,FOOD,FEED.DO NOT INGEST.DO NOT
BREATHE VAP,SPRAY MIST,DUST.AVOID SKIN CONTACT.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.READ AND FOLLOW ALL
LABEL INSTRUCTIONS.STORE IN A WELL-VENTILATED AREA.ALLOW CLOSED
TRUCKS ADEQUATE TIME TO VENTILATE PRIOR TO ENTERING.WASH THOROUGHLY
BEFORE EATING,DRIN KING,SMOKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RUBBER
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NEOPRENE BOOTS,HAT,LONG-SLEEVED
COVERALLS.SHOWER REC AFTER WORK SHIFT (PROD
MANUFACTURE,FORMULATION,APPLICATION).
Work Hygienic Practices:WASH BEFORE EATING,DRINKING OR SMOKING.SHOWER
AFTER WORK SHIFT (PROD MANUFACTURE,FORMULATION,APPLICATION).
Supplemental Safety and Health
LD50-LC50 MIX:RABBIT DERMAL ACUTE 400 MG/KG (TECHNICAL MATERIAL).ROUTES
OF ENTRY:INHALATION,SKIN,INGESTION .FIRE FIGHT
PROC:SEWER,DRAIN).EVACUATE PEOPLE DOWNWIND.SARA HAZARD
CATEGORY:ACUTE,CHRON IC AND FLAMMABLE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:3 MMHG
Spec Gravity:0.99 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:EMULSIFIABLE
Appearance and Odor:LIGHT BROWN LIQUID WITH ESTER ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS,ALKALIES.
Stability Condition to Avoid:HIGH TEMPERATURE,MOISTURE.
Hazardous Decomposition Products:NO*X,PO*X,SO*X.TRACES OF WATER CAUSE
HYDROLYSIS TO TEPP DERIVATIVES (WILL NOT OCCUR WITH EXCESS WATER).
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .PLACE IN DOT-APPROVED
CONTAINERS AND DISPOSE OF IN AN EPA CLASS I DISPOSAL SITE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|