===================== Product Identification =====================
MSDS NAME:SB 1231 A
NIIN:00N011363
MSDS Number: BHZCX
=== Responsible Party ===
Company:ASHLAND CHEMICAL COMPANY (ASHLAND OIL)
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Info Phone Num:614-790-3333
Emergency Phone Num:606-324-1133
CAGE:7L600
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC
Address:3849 FISHER RD
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Phone:614-790-3333 / 800-325-3751
CAGE:7L600
============= Composition/Information on Ingredients =============
Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)
CAS:123-91-1
RTECS #:JG8225000
Other REC Limits:N/K
OSHA PEL:S, 100 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 51%
Other REC Limits:N/K
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 49%
Other REC Limits:N/K
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRLNG/RPTD CONT CAN CAUSE
DERM.EXCESSIVE VAP INHAL CAN CAUSE DEATH.ASPIR OF MATL INTO LUNGS
CAN CAUSE FATAL CHEM PNEUM.OVEREXPOS TO THIS MATL/ITS COMPONENTS
MAY CAUSE THE FOLLOWING EFTS IN HUMANS:CARD IAC/LIVER
ABNORM,KIDNEY/LUNG DMG.DO NOTGIVE STIMULANTS FOR OVEREXP-THEY MAY
ADVERSELY AFFECT HEART W/ FATAL RESULTS.
Explanation of Carcinogenicity:DIETHYLENE ETHER:INADEQ EVID FOR CARC IN
HUM;SUFF EVID FOR CARC IN ANIM (IARC,1987).LIMITED EVID FOR CARC IN
(SEE SUPP)
Effects of Overexposure:EYES:SEV IRRIT,REDNESS,TEARING,BLURRED
VISION.SKIN:MOD IRRIT,DEFAT,DERM POSS W/ PRLNG/RPTD
CONT.INGEST:POSS GI IRRIT,NAUSEA,VOMITING,DIARRHEA.ASPIR OF MATL
INTO LUNGS CAN CAUSE FATAL CHEM PNEUM.INHAL: POSS NASAL/RESP
IRRIT,CNS EFTS (DIZZINESS,WEAKNESS,FATIGUE,NAUSEA,HEADACHE & POSS
UNCONSCIOUSNESS,EVEN DEATH).
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
Eyes:FLUSH W/ LG AMTS OF H*2O FOR AT LEAST 15 MIN;LIFT LIDS
OCCASNLY.GET MED ATTN.SKIN:WASH W/ SOAP & H*2O.REMOVE CONTAM
CLTHG.INGEST:DO NOT INDUCE VOMIT.KEEP WARM,QUIET.GET MED
ATTN.ASPIR-FATAL CHEM PNEUM POSS.INH:MOVE TO FRESH AIR.IF BRTHG
DFCLT,GIVE O*2.IF BRTHG STOPS,GIVE ARTF RESP.KEEP WARM,QUIET.GET
MED ATTN.DO NOT GIVE STIMULANTS (EPINEPHRINE,EPHEDRINE):MAY AFFECT
HEART/BE FATAL.
===================== Fire Fighting Measures =====================
Flash Point:100-200F,39-94C
Lower Limits:N/K
Upper Limits:1.0%
Extinguishing Media:REGULAR FOAM,WATER FOG,CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NEVER CUT/WELD ON/NEAR DRUM (EVEN
EMPTY).PROD/RESIDUE MAY EXPLODE.VAP HEAVIER THAN AIR,MAY TRAVEL
ALONG GROUND/MOVE BY VENT,IGNITE BY HEAT,PILOT LIGHT,(SUP DA)
================== Accidental Release Measures ==================
Spill Release Procedures:SM:ABSORB ON PAPER,VERMICULITE,FLOOR
ABSORB,OTHER.MOVE TO HOOD.LG:ELIM IGNIT SOURCES.EXCLUDE UNPROT
PERS.STOP SPILL,DIKE,PUMP TO SALV TANK.TAKE UP REST ON
SAND,CLAY,EARTH,OTHER ABSORB.SHOVEL INTO CONT R.PVNT RUNOFF TO
WATER.IF RUNOFF OCCURS,CALL AUTH.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:EMPTY CONTAINERS CAN BE
HAZARDOUS.EMPTY CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,LIQUID
AND/OR SOLID).ALL HAZARD PRECAUTIONS MUST BE OBSERVED.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT AND/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RESISTANT (NITRILE RUBBER).
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS TO
PREVENT REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ:FLAME,OTHER IGNIT SOURCES AT DIST.HAZ DECOMP
PROD:HCL,PHOSGENE ,CO,CO*2,OTHER HYDROCARB,ETC.ROUTES OF
ENTRY:INGEST .EXPLAN OF CARC:HUM;SUFF EVID FOR CARCIN IN ANIM
(NTP,1989).KNO WN TO CAUSE CANCER (CAL PROP 65,1988).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:161.6F,72C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:100 MMHG
Vapor Density:>1 (AIR=1)
Spec Gravity:>1 (WATER=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:N/K
Appearance and Odor:N/K
Percent Volatiles by Volume:100.00
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ALKALIES.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:HCL AND PHOSGENE ,CARBON
DIOXIDE,CARBON MONOXIDE,VARIOUS HYDROCARBONS,ETC.
Conditions to Avoid Polymerization:CANNOT OCCUR
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .SM:LET VOLAT EVAP IN HOOD.LET
VAP CLEAR HOOD DUCT WORK.LG:DESTROY BY LIQ INCINERATION WITH
OFF-GAS SCRUBBER.DEPOSIT CONTA M ABSORB IN LANDFILL IAW ALL REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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