Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name: 101MA COPPER SPRAY-A-GASKET 9 OZ AE
Item No: 80697
Product Type: Aerosol sealant
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients Percent ACGIH 8 Hr. TWA: OSHA 8 Hr. TWA:
500 ppm TWA; 1188 mg/m3 TWA 1000 ppm TWA; 2400 mg/m3 TWA
ACETONE <35
67-64-1
400 ppm TWA; 1400 mg/m3 TWA
ETHYL ACETATE <35 400 ppm TWA
141-78-6
800 ppm TWA; 1900 mg/m3 TWA 800 ppm TWA; 1900 mg/m3 TWA
BUTANE [1], ISOBUTANE [2] <25
106-97-8
simple asphyxiant; 2500 ppm TWA 1000 ppm TWA; 1800 mg/m3 TWA
PROPANE <25
74-98-6
50 ppm TWA; 174 mg/m3 TWA
DICHLOROMETHANE <20 25 ppm TWA; 125 ppm STEL (15
75-09-2 min. TWA)
SOLVENT NAPHTHA <5 Not Listed Not Listed
(PETROLEUM), LIGHT ALIPH.
64742-89-8
1.0 mg/m3 (dust and mist); 0.2 1.0 mg/m3 (dust and mist); 0.1
COPPER <5
mg/m3 (fumes) mg/m3 (fumes)
7440-50-8
3. HAZARDS IDENTIFICATION
May cause nose, throat and respiratory irritation. May cause eye and skin irritation. Intentional misuse
Toxicity:
by concentrating and inhaling the vapor may be harmful or fatal. Excessive inhalation causes
headache, dizziness, nausea, and incoordination. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage (sometimes referred to
as "solvent" or "painter's syndrome"). Symptoms include fatigue, concentration difficulties, anxiety,
depression, rapid mood swings, and short-term memory loss. Ethyl acetate may cause anemia.
Methylene chloride will have an effect on the cardiovascular system. Inhalation of high concentrations
of Methylene chloride over long periods of time has caused cancer in laboratory animals. Long term
exposure to high concentrations of vapor may cause lung, liver or kidney damage.
Eye and skin contact, ingestion, inhalation.
Primary Routes of Entry:
Signs and Symptoms of Exposure: Excessive overexposure may cause giddiness, dizziness, headache, nausea and in extreme cases,
unconsciousness and respiratory depression. Inhaling may cause mild irritation to the nose, throat and
respiratory tract and may result in central nervous system (CNS) depression. May cause pain, redness
or swelling of the eyes and excessive blinking and tear production. Skin: Exposure may cause mild
skin irritation. Prolonged or repeated exposure may dry the skin. Symptoms may include redness,
burning, drying, cracking and skin burns. Preexisting skin disorders may be aggravated by exposure.
Skin absorption is possible, but harmful effects are not expected from this route under normal
conditions of handling and use. Swallowing: This material can enter the lungs during swallowing or
vomiting and cause lung inflammation and/or damage. Aspiration into the lungs can cause chemical
pneumonia which can be fatal.
Ingredients Percent NTP: ACGIH IARC:
Carcinogens
ACETONE <35 Not known A4 - Not Classifiable Not known
67-64-1 as a Human
Carcinogen
ETHYL ACETATE <35 A4 - Not Classifiable
141-78-6 as a Human
Carcinogen
DICHLOROMETHANE <20 Group 2: Suspect A3 - Animal Group 2B: Monograph 41,
75-09-2 Carcinogen Carcinogen Supplement 7, Monograph
71; 1998
Medical Conditions Recognized as Cardiovascular problems may be aggravated by overexposure to methylene chloride. Persons with
preexisting respiratory, liver, kidney, eye or skin diseases may be adversely affected.
Being Aggravated by Exposure:
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Product name: 101MA COPPER SPRAY-A-GASKET 9 Item 80697
OZ AE
4. FIRST AID MEASURES
If swallowed, DO NOT induce vomiting. If spontaneous vomiting occurs, hold the victim麓s head lower
Ingestion:
than hips to prevent aspiration. Get immediate medical attention. Never give fluids or induce vomiting
if the victim is unconscious or having convulsions.
If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
Inhalation:
breathing is difficult give oxygen. Get medical attention.
Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical
Skin Contact:
attention.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
Eye Contact:
attention if irritation persists.
5. FIRE FIGHTING MEASURES
<-100 degrees F.
Flash Point (掳F/C):
Water fog, carbon dioxide, foam, dry chemical.
Recommended Extinguishing Media:
Firefighters should wear self-contained breathing apparatus. Keep
Special Fire-Fighting Procedures:
containers cool. Use equipment or shielding required to protect against
bursting or venting of containers. Water spray may be ineffective on
flames but should be used to keep fire-exposed containers cool.
Carbon dioxide, Carbon monoxide, Chlorine, Hydrogen chloride.
Hazardous Products Formed by Fire or Thermal
Phosgene
Decomposition:
Contents under pressure. Exposure to temperatures over 120 degrees F.
Unusual Fire/Explosion Hazards:
may cause bursting or venting. Use equipment or shielding to protect
personnel from bursting containers.
Not determined.
Lower Explosive Limit:
Not determined.
Upper Explosive Limit:
6. ACCIDENTAL RELEASE MEASURES
Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until
Spill Procedures:
disposal.
7. HANDLING AND STORAGE
Store away from heat, sparks or open flame. Do not store at temperatures above 120 degrees F.
Storage:
Exposure to high temperatures may cause container to burst.
Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with
Handling:
skin and eyes. Do not puncture or incinerate container. Do not use near heat, sparks or open flame.
Intentionally concentrating and inhaling the vapor may be harmful or fatal. Use in a well ventilated area
to prevent irritation by vapors. Wash hands before eating, drinking, chewing gum, using tobacco or
using the toilet.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Safety glasses or goggles.
Eyes:
Rubber or plastic gloves
Skin:
Sufficient mechanical ventilation to maintain exposures below the TLV, but general mechanical
Ventilation:
ventilation is not recommended as the sole means of controlling exposure. Make up air should always
be supplied to balance air exhausted.
An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the
Respiratory Protection:
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Copper colored
Appearance:
SOLVENT
Odor:
Not determined.
Boiling Point (掳F):
Does not apply
pH:
Nil
Solubility in Water:
0.93 g/ml
Specific Gravity:
<45% by weight
VOC Content(Wt.%):
41-51 psig
Vapor Pressure:
>1 (air = 1)
Vapor Density (Air=1):
>1 (butyl acetate = 1)
Evaporation Rate:
10. STABILITY AND REACTIVITY
Stable at normal conditions
Chemical Stability:
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Product name: 101MA COPPER SPRAY-A-GASKET 9 Item 80697
OZ AE
WILL NOT OCCUR
Hazardous Polymerization:
Strong oxidizers, strong alkalies, reactive metals
Incompatabilities:
Do not expose to heat or store at temperatures above 120 F.
Conditions to Avoid:
Carbon dioxide, Carbon monoxide, Chlorine, Hydrogen chloride.
Hazardous Products Formed by Fire or Thermal
Phosgene
Decomposition:
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Dispose of in accordance with local, state and federal regulations This container may be recycled in
aerosol recycling centers. Before offering for recycling, empty the can by using the product according
to the label. If recycling is not available, wrap the container and discard in the trash.
D001/F002 - Hazardous waste per 40CFR 261.21 and 261.31 (Methylene Chloride)
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Domestic Ground Transport
CONSUMER COMMODITY
DOT Shipping Name:
ORM-D
Hazard Class:
None
UN/ID Number:
None
Marine Pollutant:
IATA
Aerosols, flammable, containing substances in Division 6.1, Packing Group III
Proper Shipping Name:
Division 2.1, Subsidiary Risk 6.1
Class or Division:
UN 1950
UN/NA Number:
IMDG
Aerosols, Limited Quantity
Proper Shipping:
Class 2.1
Hazard Class:
UN 1950
UN Number:
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
SARA 313 Information
DICHLOROMETHANE, COPPER
CALIFORNIA PROP 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
TSCA Inventory Status:
Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 2, FLAMMABILITY 4 , REACTIVITY 0
Estimated NFPA Rating:
HEALTH 2, FLAMMABILITY 4, PHYSICAL HAZARD 0
Estimated HMIS Classification:
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
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Product name: 101MA COPPER SPRAY-A-GASKET 9 Item 80697
OZ AE
Denise Boyd, Health and Safety Manager
Prepared By: Revision Date: 02/28/2003
Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 8
Company: Revision
06106 Number:
Telephone Number: 1-87-Permatex (877) 376-2839
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