Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
Revision Date: 09/26/2006
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
Product Name
102000002217
MSDS Number
264-1048
EPA Registration No.
Bayer CropScience
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-866-99BAYER (1-866-992-2937)
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Thiodicarb 59669-26-0 34.00
Dodecylbenzene sulphonate, isopropylamine salt 26264-05-1 2.20
Synthetic amorphous silica 112926-00-8 1.00
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Warning! May be fatal if swallowed. Harmful if inhaled or absorbed through skin.
Emergency Overview
May cause eye irritation. May cause sensitization by skin contact. Do not take
internally. Avoid contact with skin, eyes and clothing. Avoid breathing spray mist.
Toxic to fish. Toxic to aquatic invertebrates. Toxic to bees.
suspension
Physical State
characteristic
Odor
beige
Appearance
Skin Absorption, Inhalation, Eye contact, Ingestion
Routes of Exposure
Immediate Effects
May cause eye irritation. Avoid contact with eyes.
Eye
Harmful if absorbed through skin. May cause sensitisation by skin contact. Avoid
Skin
contact with skin and clothing.
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
This product causes reversible cholinesterase inhibition. Do not take internally.
Ingestion
May be fatal if swallowed.
Harmful if inhaled. Avoid breathing spray mist.
Inhalation
This product contains ingredients that are considered to be probable or
Chronic or Delayed
suspected human carcinogens (see Section 11 - Chronic). This product or its
Long-Term
components may have target organ effects.
This product contains a cholinesterase inhibitor carbamate. Allow no further
Medical Conditions
exposure to any cholinesterase inhibitor until full recovery is assured. Prolonged
Aggravated by Exposure
exposure and inhalation may aggravate pre-existing conditions of the respiratory
system.
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Rinse immediately with plenty of water, also under the eyelids, for at least 15
Eye
minutes. Remove contact lenses, if present, after the first 5 minutes, then
continue rinsing eye. Call a physician or poison control center immediately.
Wash off with soap and water. Take off contaminated clothing and shoes
Skin
immediately. Call a physician or poison control center immediately.
Do not leave victim unattended. Call a physician or poison control center
Ingestion
immediately. Rinse out mouth and give water in small sips to drink. Never give
anything by mouth to an unconscious person. DO NOT induce vomiting unless
directed to do so by a physician or poison control center.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
Local:
Signs and
Temporary blurred vision due to contraction of the pupils (miosis) following
Symptoms
contact with the eyes.
Systemic:
bradycardia
low blood pressure
salivation
bronchial hypersecretion
nausea
vomiting
diarrhoea
sweating
muscular fasciculation
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
spasm
breathing difficulties
respiratory paralysis
somnolence
coma
respiratory failure
hypothermia
convulsions
This product contains a cholinesterase inhibitor carbamate.
Hazards
The product inhibits cholinesterase resulting in stimulation of the central nervous
Treatment
system, the parasympathetic nervous system, and the somatic motor nerves. If
symptoms of carbamate poisoning are present, the administration of atropine
sulfate is indicated.
ANTIDOTE: Administer atropine sulfate in large therapeutic doses. Repeat as
necessary to the point of tolerance. In mild cases, start treatment by giving 1-2
mg of atropine intravenously every 15 minutes until signs of atropinization
appear (dry mouth, flushing and dilated pupils if pupils were originally pinpoint).
In severe cases 2 to 4 mg should be injected intravenously every 10 minutes
until fully atropinized, then intramuscularly every 30 to 60 minutes as needed to
maintain the effect for at least 12 hours. Dosages for children should be
appropriately reduced.
Do not use oximes such as 2-PAM unless organophosphate intoxication is
suspected. Do not give morphine. Watch for pulmonary edema, which may
develop in serious cases of poisoning even after 24-48 hours. At first sign of
pulmonary edema, the patient should be placed in an oxygen tent and treated
symptomatically.
SECTION 5. FIRE FIGHTING MEASURES
no data available
Flash point
580 掳C / 1076 掳F
Autoignition
Temperature
The product itself does not burn.
Fire and Explosion
In the event of fire the following can be released:
Hazards
carbon monoxide (CO)
Sulphur oxides
nitrogen oxides (NOx)
water spray, foam, carbon dioxide (CO2), dry powder
Suitable Extinguishing
Media
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
Keep out of smoke. Fight fire from upwind position. Cool closed containers
Fire Fighting
exposed to fire with water spray. Dike area to prevent runoff and contamination
Instructions
of water sources. Equipment or materials involved in pesticide fires may become
contaminated.
Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled
Personal Precautions
product or contaminated surfaces.
Recover the product by pumping, suction or absorption using a dry and inert
Methods for Cleaning Up
absorbent clay. Take up with absorbent material (e.g. sand, diatomaceous earth
or a proprietary absorbent material). Pick up and fill the product into a tightly
closed container. When picked up, treat material as prescribed in Ch. 13.
"Disposal considerations".
Contact Bayer for further assistance if necessary. Use personal protective
Additional Advice
equipment. Do not allow product to enter streams, sewers or other waterways.
SECTION 7. HANDLING AND STORAGE
Smoking, eating and drinking should be prohibited in the application area.
Handling Procedures
Keep out of the reach of children.
Storing Procedures
Store in a cool, dry place and in such a manner as to prevent cross
contamination with other pesticides, fertilizers, food, and feed. Store in original
container and out of the reach of children, preferably in a locked storage area.
Wash hands thoroughly with soap and water after handling and before eating,
Work/Hygienic
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.
Procedures
Take off contaminated clothing and shoes immediately. Then wash thoroughly
and put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after handling this
product. Before removing gloves clean them with soap and water. As soon as
practical, wash thoroughly and change into clean clothing.
Do not transport or store above 46 掳C / 115 掳F
Min/Max Storage
Temperatures
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Cholinesterase activity of the worker should be supervised.
General Protection
Train employees in safe use of the product. Follow all label instructions.
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such
instructions for washables, use detergent and warm/tepid water. Keep and wash
PPE separately from other laundry.
Maintain exposure levels below the exposure limit through the use of general
Engineering Controls
and local exhaust ventilation.
tightly fitting safety goggles
Eye/Face Protection
Chemical resistant nitrile rubber gloves
Hand Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Body Protection
When respirators are required, select NIOSH approved equipment based on
Respiratory Protection
actual or potential airborne concentrations and in accordance with the
appropriate regulatory standards and/or Industry recommendations.
Exposure Limits
1,2-Propanediol 57-55-6 WEEL TWA 10 mg/m3
Form of Exposure Aerosol.
Synthetic amorphous 112926-00-8 ACGIH TWA 10 mg/m3
silica
OSHA Z1A TWA 6 mg/m3
NIOSH REL 6 mg/m3
OSHA Z1 PEL 5 mg/m3
Form of Exposure Respirable fraction.
OSHA Z1 PEL 15 mg/m3
Form of Exposure Total dust.
Z3 TWA 15 millions of particles per
cubic foot of air
Form of Exposure Respirable fraction.
Z3 TWA 50 millions of particles per
cubic foot of air
Form of Exposure Total dust.
Z3 TWA 5 mg/m3
Form of Exposure Respirable fraction.
Z3 TWA 15 mg/m3
Form of Exposure Total dust.
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
Z3 TWA 20 millions of particles per
cubic foot of air
Z3 TWA 0.8 mg/m3
Remarks The value is calculated from
a specified equation using a
value of 100%. Lower values
of % will give higher
exposure limits. See
regulation for specific
equation.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
beige
Appearance
suspension
Physical State
characteristic
Odor
4.0 - 6.5 (100 %)
pH
ca. 1.14 g/cm鲁 at 20 掳C
Density
100 掳C / 212 掳F
Boiling Point
-5 掳C / 23 掳F
Melting / Freezing Point
dispersible
Water solubility
log Pow: 1.62
Partition coefficient (n-
octanol/water)
700 - 1,000 mPa.s
Viscosity
SECTION 10. STABILITY AND REACTIVITY
Stable under recommended storage conditions.
Chemical Stability
Heat, flames and sparks.
Conditions to Avoid
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
bases
Incompatibility
brass
cupric chloride
iron chlorides
metal salts
mineral acids
rust
Thermal decomposition can lead to release of:
Hazardous
Carbon monoxide
Decomposition Products
Sulphur oxides
nitrogen oxides (NOx)
SECTION 11. TOXICOLOGICAL INFORMATION
Only acute toxicity studies have been performed on this product as formulated. The non-acute information
pertains to the active ingredient, thiodicarb technical.
male rat: LD50: 357 mg/kg
Acute Oral Toxicity
female rat: LD50: > 330 - < 558 mg/kg
male/female rabbit: LD50: > 2,000 mg/kg
Acute Dermal Toxicity
male/female rat: LC50: 1.51 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Determined in the form of liquid aerosol.
male/female rat: LC50: > 2.53 mg/l
Exposure time: 1 h
Determined in the form of liquid aerosol.
rabbit: Slight irritation.
Skin Irritation
rabbit: Slight irritation.
Eye Irritation
guinea pig: sensitizing
Sensitization
Thiodicarb caused cholinesterase inhibition in a chronic toxicity study in dogs. In
Chronic Toxicity
rats and mice, the principal organs affected from long-term dietary exposure to
thiodicarb included the liver, spleen and testis.
Assessment Carcinogenicity
Thiodicarb has been classified by EPA as a Group B2 (probable human carcinogen) based on its
oncogenic potential at high dose levels in mice (liver tumors) and rats (benign testicular tumors). At low
doses the product would not be expected to cause these tumors in humans.
ACGIH
None.
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
NTP
None.
IARC
OSHA
None.
REPRODUCTION: Thiodicarb is not a primary reproductive toxicant based on a
Reproductive &
two-generation study in rats. Reproductive effects (e.g., decreased viability)
Developmental Toxicity
were considered secondary to maternal toxicity.
DEVELOPMENTAL TOXICITY: Thiodicarb is not teratogenic based on
developmental toxicity studies in rats, mice and rabbits. Developmental effects
(e.g., delayed ossifications) were observed in rats and were considered
secondary to maternal toxicity.
Thiodicarb caused transient neurobehavioral effects related to cholinergic toxicity
Neurotoxicity
in acute and/or subchronic neurotoxicity screening studies in rats. There were
no neuropathological changes observed in either study. Thiodicarb did not
cause neurotoxic effects in a delayed neurotoxicity study with atropine-
pretreated hens.
The overall weight of evidence indicates thiodicarb is non-genotoxic or non-
Mutagenicity
mutagenic based on a battery of in vitro and in vivo mutagenicity studies.
SECTION 12. ECOLOGICAL INFORMATION
Rainbow trout (Oncorhynchus mykiss)
Toxicity to Fish
LC50: 14.4 mg/l
Exposure time: 96 h
Toxicity to Aquatic Plants Selenastrum capricornutum
EC50: > 18 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient.
Water flea (Daphnia magna)
Acute Toxicity to Aquatic
EC50: 0.29 mg/l
Invertebrates
Exposure time: 48 h
Bluegill sunfish BCF: 6.3
Bioaccumulation
Information refers to the main component.
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
For terrestrial uses, do not apply directly to water, or to areas where surface
Environmental
water is present, or to intertidal areas below mean high water mark. Do not apply
Precautions
when weather conditions favor runoff or drift. Drift or run-off from treated areas
may be hazardous to aquatic organisms in neighboring areas. Do not
contaminate surface or ground water by cleaning equipment or disposal of
wastes, including equipment wash water. Apply this product as specified on the
label.
Do not apply this product or allow it to drift to blooming crops or weeds if bees
are visiting the treatment area.
SECTION 13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food, or feed by disposal. Pesticide, spray mixture or
General Disposal
rinse water that cannot be used according to label instructions may be disposed
Guidance
of on site or at an approved waste disposal facility.
Do not re-use empty containers. Triple rinse containers. Puncture container to
Container Disposal
avoid re-use. Dispose of empty container in a sanitary landfill or by incineration,
or, if allowed by State/Provincial and local authorities, by burning. If burned, stay
out of smoke.
The RCRA Classifications may be on the individual component(s) and not
RCRA Classification
necessarily on the product as a whole.
59669-26-0 Thiodicarb
US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous
Wastes and Appendix VIII Hazardous Constituents (40 CFR 261): U410
59669-26-0 Thiodicarb
US. EPA Resource Conservation and Recovery Act (RCRA) U List of Hazardous Wastes (40
CFR 261.33(f) and 40 CFR 302 [CERCLA]): U410
SECTION 14. TRANSPORT INFORMATION
DOT CLASSIFICATION:
Carbamate Pesticides, Liquid, Toxic // 6.1 // UN2992 // PG III
IMDG CLASSIFICATION:
Carbamate Pesticides, Liquid, Toxic(Thiodicarb) // 6.1 // UN2992 // PG III
FREIGHT CLASSIFICATION:
Insecticides or Fungicides, N.O.I.; poison, other than gases that are poisonous by inhalation
SECTION 15. REGULATORY INFORMATION
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
264-1048
EPA Registration No.
US Federal Regulations
TSCA list
Dodecylbenzene sulphonate, isopropylamine 26264-05-1
salt
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
Thiodicarb 59669-26-0 1.0%
US States Regulatory Reporting
CA Prop65
This product contains a chemical known to the State of California to cause cancer.
Thiodicarb 59669-26-0
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
Thiodicarb 59669-26-0 NJ
Synthetic amorphous silica 112926-00-8 CA, IL, MN, RI
Canadian Regulations
Canadian Domestic Substance List
Dodecylbenzene sulphonate, isopropylamine 26264-05-1
salt
Synthetic amorphous silica 112926-00-8
Environmental
CERCLA
Thiodicarb 59669-26-0 1 lbs
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
Thiodicarb 59669-26-0
Dodecylbenzene sulphonate, isopropylamine 26264-05-1
salt
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000002217
MSDS Version 2.0
EXP3 SEED APPLIED NEMATICIDE/INSECTICIDE
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 2 Flammability - 1 Reactivity - 1 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: Re-numbered due to system update.
Revision Date: 09/26/2006
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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