MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
1. PRODUCT AND COMPANY IDENTIFICATION
CASORON庐 CS EPA Reg. No.: 400-541
Product name :
Dichlobenil
Chemical name:
Herbicide
Use of substance/preparation:
Chemtura Corporation
Supplier:
199 Benson Road
Middlebury, CT 06749 USA
CHEMTREC (24 hours) 800-424-9300
Emergency telephone
Chemtura Corporation Emergency Response (24 hours) 800-292-5898
number:
866-430-2775
Environmental, Health and
Safety Department:
Product Safety Department Date of Issue: 06/25/2007
Prepared by
(US) +1 866-430-2775
(EU) +44 (0) 1753.603.000
Email: MSDSRequest@chemtura.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION!
MAY CAUSE EYE AND SKIN IRRITATION.
MAY CAUSE SKIN SENSITIZATION.
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT
2,6-Dichlorobenzonitrile 15
CAS# 1194-65-6
Ammonium chloride < 10
CAS# 12125-02-9
Formaldehyde <1
CAS# 50-00-0
Sodium hydroxide <2
CAS# 1310-73-2
(M)SDS# 000000026969 Page: 1 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
4. FIRST AID MEASURES
Swallowing
Do not induce vomiting. Rinse mouth with water. Obtain medical attention.
Inhalation
Remove to fresh air. Obtain medical attention.
Skin contact
Remove contaminated clothing. Wash thoroughly with warm water using a mild soap. Obtain medical attention if irritation persists.
Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes. Obtain medical attention if irritation persists.
5. FIRE-FIGHTING MEASURES
Hazardous combustion products
Irritating fumes.
Oxides of carbon.
Special fire fighting procedures
Do not discharge extinguishing waters into streams, rivers and lakes.
Special protective equipment for firefighters
Body covering protective clothing, full "turn-out" gear.
Self-contained breathing apparatus.
Extinguishing media
Suitable: Large fires:
- alcohol-type foam or universal-type foams
Small fires:
- CO2
- dry chemical
Unsuitable: - water jets
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Wear suitable protective equipment., Avoid contact with eyes and skin.
Environmental precautions
Prevent from entering sewer system, surface water or soil.
Methods for cleaning up
Observe government regulations.
Small spills: Absorb on inert material such as sand, earth, vermiculite.
Collect for disposal.
Large spills Dike to contain spill.
Pump excess material into suitable container (metal drums, metal tank, or such).
(M)SDS# 000000026969 Page: 2 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Do not get in eyes., Avoid prolonged or repeated contact with skin., Avoid breathing vapor., Use with adequate ventilation., Wash thoroughly after handling.
STORAGE
Storage requirements
Keep container closed., Store in a cool, dry place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Component Country Type Value Remark
Ammonium chloride Ireland STEL 20 mg/m3
USA TWA, OSHA 100 ppm See 29 CFR 1910.1048
Formaldehyde 100 ppm
TWA, ACGIH 100 ppm IARC 2B
100 ppm
STEL, ACGIH 125 ppm
125 ppm
Ireland STEL 2.5 mg/m3
USA Ceiling, ACGIH 2 mg/m3
Sodium hydroxide
TWA, OSHA 2 mg/m3
PERSONAL PROTECTION
Respiratory protection
Self-contained breathing apparatus in high vapor concentrations.
Hand protection / protective gloves
Chemical resistant protective gloves
Eye protection
Safety glasses with side shields.
Skin protection
Wear protective clothing, such as long sleeves to minimize skin contact.
Other protective equipment
Eye bath, Safety shower
ENGINEERING CONTROLS
Ventilation
Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Liquid
Physical state
Opaque off-white/Yellow.
Color
Characteristic
Odor
(M)SDS# 000000026969 Page: 3 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
OTHER PROPERTIES
Not available
Boiling point
6.5 - 7.5
pH
1.09 - 1.13 g/cm3
Density
Vapor pressure
Dispersible
Solubility in water
Flash point
Not available
150 - 250 mPa.s
Dynamic viscosity
10. STABILITY AND REACTIVITY
Stability: This product is stable under normal storage and handling conditions.
Incompatible materials:
Oxidizing agents.
Strong acids.
Strong bases.
Hazardous combustion products:
Irritating fumes.
Oxides of carbon.
Hazardous polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
GENERAL
The following information is based on analogy with a similar material.
SWALLOWING
Test results
Acute toxicity: LD50 Rat
Result: > 5,000 mg/kg
SKIN ABSORPTION
Test results
Acute toxicity: LD50 - Rat
Result: > 5,000 mg/kg
INHALATION
Test results
Acute toxicity: LC50 - Rat
Result: > 1.42 mg/l
Exposure time: 4 h
SKIN CONTACT
Test results
Skin irritation: Species: Rabbit
Classification: Not irritating
EYE CONTACT
(M)SDS# 000000026969 Page: 4 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
Test results
Eye irritation: Species: Rabbit
Result: Minor irritation
Classification: Not irritant to the eyes
SENSITIZATION
Test results: Species: - Guinea pigs
Result: May cause sensitization by skin contact.
MUTAGENICITY
Assessment: Negative
CARCINOGENICITY
Assessment: Negative
TOXICITY TO REPRODUCTION/FERTILITY
AssessmentNegative
12. ECOLOGICAL INFORMATION
Component ecotoxicology LC50 -
2,6-Dichlorobenzonitrile Result: 4.93 - 12.7 mg/l
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Fathead minnow (Pimephales promelas)
2,6-Dichlorobenzonitrile Result: 6 ppm
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Rainbow trout (Oncorhynchus mykiss)
2,6-Dichlorobenzonitrile Result: 6.3 ppm
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Bluegill (Lepomis macrochirus)
2,6-Dichlorobenzonitrile Result: 8.3 ppm
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology LC50 - Sheepshead minnow (Cyprinodon variegatus):
2,6-Dichlorobenzonitrile Result: 12.7 ppm
Acute toxicity fish: Exposure time: 96 h
Component ecotoxicology - Rainbow trout (Oncorhynchus mykiss)
2,6-Dichlorobenzonitrile Result: 0.7 ppm
Chronic toxicity fish: Early Life Stage MATC
Component ecotoxicology IC50 - Algae
2,6-Dichlorobenzonitrile Result: 2 - 2.7 mg/l
Aquatic toxicity to plants: Exposure time: 72 h
Component ecotoxicology EC50 - Water flea (Daphnia magna)
2,6-Dichlorobenzonitrile Result: 6.2 mg/l
Acute toxicity to aquatic invertebrates: Exposure time: 48 h
(M)SDS# 000000026969 Page: 5 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
Component ecotoxicology LC50 - Mysid shrimp (Mysis litoralis)
2,6-Dichlorobenzonitrile Result: 2.35 ppm
Acute toxicity to aquatic invertebrates: Exposure time: 96 h
Component ecotoxicology - - Water flea (Daphnia magna)
2,6-Dichlorobenzonitrile Result: 1.5 ppm
Chronic toxicity to aquatic invertebrates: Life Cycle MATC
Component ecotoxicology - EC50 - Eastern Oyster (Crassostrea virginica)
2,6-Dichlorobenzonitrile Result: 1.92 ppm
Chronic toxicity to aquatic invertebrates: Shell Desposition
Exposure time: 4 d
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with appropriate Federal, State, and local regulations., Avoid discharge to sewers and natural
General:
waters.
14. TRANSPORT INFORMATION
DOT Classification
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Dichlobenil)
Proper shipping name:
9
Class:
UN3082
UN ID #:
III
Packing group:
MARINE POLLUTANT
marine pollutant:
Not regulated by ground or rail if shipped or transported in containers less than 450 liters.
IMDG Classification
Environmentally hazardous substance, liquid, n.o.s.
Proper shipping name:
9
Class:
marine pollutant
Subsidiary risk:
UN 3082
UN ID #:
III
Packing group:
(Dichlobenil)
Technical description
ICAO Classification
Environmentally hazardous substance, liquid, n.o.s.
Proper shipping name:
9
Class:
UN 3082
UN ID #:
III
Packing group:
(Dichlobenil)
Technical description
Only regulated by air Into, Out of or Within the United States in containers 666 lbs (302 kg) or greater.
15. REGULATORY INFORMATION
(M)SDS# 000000026969 Page: 6 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification of the National Response Center of
release of quantities of hazardous substances equal to or greater than the reportable quantities (RQ's) in 40CFR302.4.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
2,6-Dichlorobenzonitrile RQ Dichlobenil is 1194-65-6 15.00
100 pounds
Ammonium chloride RQ Ammonium 12125-02-9 < 10.00
chloride is 5000
pounds
Formaldehyde RQ Formaldehyde is 50-00-0 < 1.00
100 pounds
Sodium hydroxide RQ Sodium 1310-73-2 < 2.00
Hydroxide is 1000
pounds
Inerts -
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that
appear in 40CFR372 (for SARA 313). This information must be included in MSDS's that are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Ammonium chloride 12125-02-9 < 10.00
Formaldehyde 50-00-0 < 1.00
Sodium hydroxide 1310-73-2 < 2.00
New Jersey Worker and Community Right-To-Know Act (Labeling Requirements)
Chemical name CAS# New Jersey TS Number
2,6-Dichlorobenzonitrile 1194-65-6
Ammonium chloride 12125-02-9
Formaldehyde 50-00-0
Sodium hydroxide 1310-73-2
California Proposition 65
Contains Formaldehyde.
CHEMICAL INVENTORY
United States: This product is subject to regulation under the US Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA) and is therefore exempt from TSCA Inventory listing requirements.
16. OTHER INFORMATION
STP Standard temperature and pressure
W/W 0 (HMIS)
1 (HMIS) Slight hazard
2 (HMIS) Moderate hazard
3 (HMIS) Serious hazard
Copyright
2007
4 (HMIS) Severe hazard
Chemtura
X (HMIS) Personal protection rating to be supplied by user depending on use conditions
Corporation
(M)SDS# 000000026969 Page: 7 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.4
庐
CASORON CS Date of Issue: 06/25/2007
Date printed: 06/26/2007
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN CHEMTURA CORPORATION. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS
CURRENT AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE OF THIS PRODUCT
ARE NOT WITHIN THE CONTROL OF CHEMTURA CORPORATION, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS.
(M)SDS# 000000026969 Page: 8 of 8
|