MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : CASORON庐 4G EPA Reg. No. 400-168
Dichlobenil
Chemical name:
Herbicide
Use of substance/preparation:
Chemtura USA Corporation
Supplier:
Chemtura Corporation (Worldwide HQ)
199 Benson Road
Middlebury, CT 06749 USA
CHEMTREC (24 hours) 800-424-9300
Emergency telephone number
Chemtura Corporation Emergency Response
(24 hours) 800-292-5898
For additional emergency telephone numbers
see section 16 of the Safety Data Sheet.
866-430-2775
Environmental, Health and Safety Department:
2. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT
2,6-Dichlorobenzonitrile 4
CAS# 1194-65-6
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
NORMAL PRECAUTIONS COMMON TO SAFE MANUFACTURING PRACTICE SHOULD BE FOLLOWED
IN HANDLING AND STORAGE.
HARMFUL TO AQUATIC ORGANISMS.
AVOID DISPERSION OF DUST IN AIR TO REDUCE POTENTIAL FOR DUST IGNITION/EXPLOSIONS.
MAY CAUSE EYE AND SKIN IRRITATION.
INDIVIDUALS INVOLVED IN THE MANUFACTURE OF BETHOXAZIN HAVE REPORTED SEVERE
IRRITATION OF THE SKIN AND MUCOUS MEMBRANES
SEE SECTION 11 FOR INFORMATION ON CHRONIC HEALTH EFFECTS.
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
4. FIRST AID MEASURES
Swallowing
Call a poison control center or doctor immediately for treatment advice.
Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by the poison control center or doctor.
Do not give anything by mouth to an unconscious person.
Skin contact
Take off contaminated clothing.
Rinse skin immediately with plenty of water for 15 to 20 minutes.
Call a poison control center or doctor for treatment advice.
Inhalation
Move person to fresh air.
If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if
possible.
Call a poison control center or doctor for further treatment advice.
Eye contact
Hold eye open and rinse slowly and gently with water for 15 to 20 minutes.
Remove contact lens, if present, after the first 5 minutes, then continue rinsing eye.
Call a poison control center or doctor for further treatment advice.
Notes to physician
ROUTES OF ENTRY:, Skin, Eyes, Ingestion, Inhalation
5. FIRE-FIGHTING MEASURES
Flammable limits
Lower Not
limit: applicable
Upper Not
limit: available
> 400 掳C
Autoignition
temperature:
Hazardous combustion products
Irritating fumes.
Oxides of carbon.
Oxides of nitrogen.
Special fire fighting procedures
Do not discharge extinguishing waters into streams, rivers and lakes.
Special protective equipment for firefighters
Body covering protective clothing, full "turn-out" gear.
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
Self-contained breathing apparatus.
Extinguishing media
Suitable: - CO2
- dry powder
- foam
- water fog
Unsuitable: - water spray
Unusual fire and explosion hazards
Avoid dispersion of dust in air to reduce potential for dust ignition/explosions.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Wear suitable protective equipment.
Environmental precautions
Prevent from entering sewer system, surface water or soil., May be harmful to aquatic life.
Methods for cleaning up
Sweep up and collect in a suitable container for disposal.
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Avoid dust formation., Use only with adequate ventilation.
Other precautions
NOTE TO END-USERS: The employee protection recommendations on this MSDS may differ from those on the product label.
For normal use of this product, always refer to the personal protective equipment requirements on the product label.
STORAGE
Storage requirements
Store in a cool, dry place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
No other exposure limits have been established
PERSONAL PROTECTION
Respiratory protection
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
In case of occurence of dust respiratory protective equipment required.
Hand protection / protective gloves
Chemical resistant protective gloves
Eye protection
Safety glasses with side shields.
Skin protection
Wear protective clothing, such as long sleeves to minimize skin contact.
ENGINEERING CONTROLS
Ventilation
Local exhaust suggested to prevent dust buildup.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Granular solid
Physical state
Gray
Color
Aromatic
Odor
Not available
Odor threshold
OTHER PROPERTIES
Not applicable
Boiling point
Not available
Melting point
Not applicable
pH
Not available
Specific gravity (H2O=1)
Not available
Density
1.2 kg/m3
Bulk density
Not available
Solubility in water
Slightly soluble
Solubility in organic solvents
Flash point
Not applicable
> 400 掳C
Autoignition temperature
Not available
Upper explosion limits
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
Not applicable
Lower explosion limits
Not available
Percent volatiles
Not applicable
Explosive properties
10. STABILITY AND REACTIVITY
Stability: This product is stable under normal storage and handling conditions.
Incompatible materials
Oxidizing agents.
Strong acids.
Strong bases.
Hazardous combustion products
Irritating fumes.
Oxides of carbon.
Oxides of nitrogen.
Hazardous polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
SWALLOWING
Test results
Acute toxicity: LD50 Rat
Result: > 5,000 mg/kg
SKIN ABSORPTION
Test results
Acute toxicity: LD50 - Rabbit
Result: > 2,000 mg/kg
INHALATION
Test results
Acute toxicity: Remark: Not applicable
SKIN CONTACT
Test results
Skin irritation: Species: Rabbit
Classification: Not irritant
EYE CONTACT
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
Test results
Eye irritation: Species: Rabbit
Classification: Not irritant
SENSITIZATION
Test results: Remark: Non sensitizing.
MUTAGENICITY
Assessment Negative
CARCINOGENICITY
AssessmentNegative
TOXICITY TO REPRODUCTION/FERTILITY
AssessmentNegative
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY
Acute toxicity fish: - LC50 -
Result: 317 mg/l
Exposure time: 96 h
Aquatic toxicity to - IC50 - Algae
plants: Result: 50 mg/l
Exposure time: 72 h
Acute toxicity to - EC50 - Water flea (Daphnia magna)
aquatic Result: 155 mg/l
invertebrates: Exposure time: 48 h
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with appropriate Federal, State, and local regulations., Avoid
General:
discharge to sewers and natural waters.
Non-cleaned packages
Empty drums should be decontaminated and either passed to an an approved drum reconditioner or destroyed., Containers that
cannot be cleaned must be treated as waste.
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
14. TRANSPORT INFORMATION
DOT Classification
This product is not regulated by DOT.
IMDG Classification
This product is not regulated by IMDG.
ICAO Classification
This product is not regulated by ICAO.
15. REGULATORY INFORMATION
Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification of the
National Response Center of release of quantities of hazardous substances equal to or greater than the reportable
quantities (RQ's) in 40CFR302.4.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
2,6-Dichlorobenzonitrile 1194-65-6 4.00
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of
release of toxic chemicals that appear in 40CFR372 (for SARA 313). This information must be included in MSDS's that
are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
2,6-Dichlorobenzonitrile 1194-65-6 4.00
New Jersey Worker and Community Right-To-Know Act (Labeling Requirements)
Chemical name CAS# New Jersey TS Number
2,6-Dichlorobenzonitrile 1194-65-6
Thickening Agent Trade secret CHEM900
Proprietary Carrier Trade secret CHEM901
Water 7732-18-5
CHEMICAL INVENTORY
Canada: All substances in this product are exempt from the DSL as this product is registered under
the Pest Control Products Act., PCP# 12533, 23767
Europe: The ingredients of this product are on the EINECS inventory.
United States: This product is subject to regulation under the US Federal Insecticide, Fungicide and
Rodenticide Act (FIFRA) and is therefore exempt from TSCA Inventory listing
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MATERIAL SAFETY DATA SHEET
1.0
Version:
CASORON庐 4G DATE OF ISSUE: 02/09/2006
Date printed: 09/12/2006
________________________________________________________________________________________________________
requirements.
Australia: The ingredients of this product are on the AICS inventory.
China: The ingredients of this product are on the IECSC inventory.
Japan: The ingredients of this product are on the ENCS inventory.
Korea: The ingredients of this product are on the ECL.
Philippines: The ingredients of this product are on the PICCS.
16. OTHER INFORMATION
RECOMMENDED USES AND RESTRICTIONSNOTE TO END-USERS: This MSDS is being provided to all interested
persons in accordance with federal and state right-to-know laws. Precautionary Statements, First Aid Statements and Directions
for Use of this product by end-users are contained on the product label and must be followed at all times.
FURTHER INFORMATION
MAY BE ON THE INVENTORY LIST BUT NOT NECESSARILY REGISTERED, (Korea, China, New Zealand) CONSULT
REGULATORY SPECIALIST.
Emergency Telephone Numbers
All +44 (0)208 762 8322
Latin America:
HMIS RATING
Health: 2 Flammability: 3 (DUST) Reactivity: 0 PPI: X
STP Standard temperature and pressure
W/W Weight/Weight
0 (HMIS)
1 (HMIS) Slight hazard
2 (HMIS) Moderate hazard Copyright
2005
3 (HMIS) Serious hazard
Chemtura
4 (HMIS) Severe hazard
Corporati
X (HMIS) Personal protection rating to be supplied by user depending on use
on
conditions
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN CHEMTURA CORPORATION.
WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS CURRENT AS OF THE DATE OF THIS SAFETY
DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE
OF THIS PRODUCT ARE NOT WITHIN THE CONTROL OF CHEMTURA CORPORATION, IT IS THE USER'S
OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS.
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