3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 07/06/2005
Supercedes Date: 04/06/2005
Document Group: 07-3667-8
Product Use:
Specific Use: Seam Sealer
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
Limestone 1317-65-3 30 - 60
Calcium Carbonate 471-34-1 15 - 40
Silyl Terminated Polyether NJ Trade Secret Registry No. 04499600-6009P Trade Secret 10 - 30
Plasticizer - NJ Trade Secret Registry No. 04499600-5988P Trade Secret 7 - 13
Naphthol Spirits 64742-48-9 1- 5
Diisodecyl Phthalate 68515-49-1 1- 5
Stearic Acid 57-11-4 1- 5
(TRIMETHOXYSILYLPROPYL)ETHYLENEDIAMINE 1760-24-3 <1
1-Methyl-2-Pyrrolidinone 872-50-4 < 0.6
BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDINYL) SEBACATE 52829-07-9 < 0.2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous MITS data
Odor, Color, Grade: Thick gray creamy paste
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Reacts violently with water. May cause allergic skin reaction.
_________________________________________________________________________________________________
Page 1 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
_________________________________________________________________________________________________
Page 2 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
152 潞F [Test Method: Pensky-Martens Closed Cup]
Flash Point
[Details: SPECIFIC METHOD: ASTM D93]
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
DO NOT USE WATER Foam, carbon dioxide, dry chemical.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable. None expected.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill
inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Collect as much of the spilled material as possible. Collect as much of the spilled material as possible using non-
sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with
fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place
in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
For industrial or professional use only. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures
to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Avoid eye contact.
Avoid skin contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
_________________________________________________________________________________________________
Page 3 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Neoprene.
8.2.3 Respiratory Protection
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half mask or full facepiece air-purifying respirator with N100 particulate filters, Half facepiece or fullface air-
purifying respirator with P100 particulate filters, Half facepiece or fullface air-purifying respirator with P95 particulate filters, Half
facepiece or fullface air-purifying respirator with N95 particulate filters. Consult the current 3M Respiratory Selection Guide for
additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not ingest.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1-Methyl-2-Pyrrolidinone AIHA TWA 10 ppm Skin Notation*
BIS(2,2,6,6-TETRAMETHYL-4- CMRG TWA 1 mg/m3
PIPERIDINYL) SEBACATE
Calcium Carbonate ACGIH TWA 10 mg/m3
Naphthol Spirits 3M TWA 100 ppm
Naphthol Spirits CMRG TWA 300 ppm
Limestone ACGIH TWA 10 mg/m3
Limestone OSHA TWA, respirable 5 mg/m3 Table Z-1
Limestone OSHA TWA, as total dust 15 mg/m3 Table Z-1
Diisodecyl Phthalate CMRG TWA 5 mg/m3
STEARATES ACGIH TWA, as total dust 10 mg/m3 Table A4
TIN, INORGANIC COMPOUNDS, EXCEPT ACGIH TWA, as Sn 2 mg/m3
SnH4
TIN, ORGANIC COMPOUNDS ACGIH TWA, as Sn 0.1 mg/m3 Skin Notation*; Table A4
TIN, ORGANIC COMPOUNDS ACGIH STEL, as Sn 0.2 mg/m3 Skin Notation*
TIN, ORGANIC COMPOUNDS OSHA TWA, as Sn 0.1 mg/m3 Skin Notation*; Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
_________________________________________________________________________________________________
Page 4 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Viscous MITS data
Specific Physical Form:
Thick gray creamy paste
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
152 潞F [Test Method: Pensky-Martens Closed Cup] [Details:
Flash Point
SPECIFIC METHOD: ASTM D93]
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Not Applicable
Boiling point
Not Applicable
Vapor Density
Not Applicable
Vapor Pressure
1.68 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
Negligible
Solubility in Water
Nil
Evaporation rate
0.34 lb/gal [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
<=5.0 %
Percent volatile
41 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
15000 - 20000 poise [Test Method: Brookfield] [Details:
Viscosity
CONDITIONS: Spindle #7, 2 rpm]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat Additional Information: Open flame, heat.
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hazardous Decomposition: Carbon monoxide, carbon dioxide, oxides of nitrogen.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
_________________________________________________________________________________________________
Page 5 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
As a disposal alternative, incinerate in an industrial or commercial facility.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-4300-4987-8, 60-9800-2404-0, 60-9800-2683-9, 60-9800-2686-2, 60-9800-3696-0, XS-0414-1253-6
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
Diisodecyl Phthalate 68515-49-1 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
Diisodecyl Phthalate (ALKYL PHTHALATES) 68515-49-1 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
_________________________________________________________________________________________________
Page 6 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
1-Methyl-2-Pyrrolidinone 872-50-4 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
1-Methyl-2-Pyrrolidinone 872-50-4 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards
of the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:
Section 2: Ingredient table was modified.
Section 15: California proposition 65 ingredient information was modified.
_________________________________________________________________________________________________
Page 7 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) Ultrapro(TM) MSP Seam Sealer - Gray, P.N. 08309, 08365, 08366, 08370
07/06/2005
Section 8: Exposure guidelines ingredient information was modified.
Section 15: TSCA section 12[b] information was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 8 of 8
|