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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
1 Identification of the substance/preparation and of the company/undertaking
Product details
Trade name: 82M-1
Application of the substance / the preparation Coating
Manufacturer/Supplier:
Kester Tel.(847) 297-1600
515 E. Touhy Ave. Fax.(847) 390-9338
Des Plaines, IL 60018
Further information obtainable from:
MSDS Coordinator: Tel. (847) 699-5755
Information in case of emergency:
CHEMTREC 24-Hour Emergency Response Telephone Number: (800) 424-9300
CHEMTREC 24-Hour Emergency Response Telephone Number (Outside US and Canada): (703) 527-3887
2 Composition/information on ingredients
Chemical characterization
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 67-56-1 methanol T, F; R 11-23/24/25-39/23/24/25 50-100%
CF
@@
EINECS: 200-659-6
CAS: 8050-09-7 Rosin Xi; R 43 25-50%
@
G
EINECS: 232-475-7
鈮? 2.5%
CAS: 123-99-9 azelaic acid
EINECS: 204-669-1
鈮? 2.5%
CAS: 128-37-0 2,6-di-tert-butyl-p-cresol Xi; R 36/38
G
@
EINECS: 204-881-4
3 Hazards identification
Hazard description:
@@
FC
T Toxic
F Highly flammable
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R 39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
R 43 May cause sensitisation by skin contact.
GB
(Contd. on page 2)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 1)
4 First-aid measures
General information: Immediately remove any clothing soiled by the product.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: Do not induce vomiting; call for medical help immediately.
5 Fire-fighting measures
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards caused by the substance, its products of combustion or resulting gases:
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Aliphatic aldehydes
Protective equipment: Wear self-contained respiratory protective device.
6 Accidental release measures
Person-related safety precautions:
Keep away from ignition sources.
Wear protective clothing.
Measures for environmental protection: Do not allow product to reach sewage system or any water course.
Measures for cleaning/collecting:
Absorb with clay, diatomaceous earth, dry sand, or other inert material. Do not use combustible materials such as
sawdust. Place in a chemical waste container. Flush residual with water.
7 Handling and storage
Handling:
Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
(Contd. on page 3)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 2)
Ingredients with limit values that require monitoring at the workplace:
67-56-1 methanol
OES Short-term value: 333 mg/m鲁, 250 ppm
Long-term value: 266 mg/m鲁, 200 ppm
Sk, ILV
Additional information:
PEL = Permissible Exposure Limit (OSHA)
REL= Recommended Exposure Limit (NIOSH)
TLV= Threshold Limit Value (ACGIH)
OSHA= Occupational Safety and Health Administration
ACGIH= American Conference of Governmental Industrial Hygienists
NIOSH= National Institute for Occupational Safety and Health
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Respiratory protection:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-
contained breathing apparatus should be worn.
Protection of hands:
S Protective gloves
Material of gloves
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
R Tightly sealed goggles
Safety glasses
9 Physical and chemical properties
General Information
Form: Liquid
Colour: Amber coloured
Odour: Alcohol-like
(Contd. on page 4)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 3)
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 64掳C
Flash point: 18掳C
Ignition temperature: 465掳C
Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are
possible.
Explosion limits:
Lower: 6.0 Vol %
Upper: 36.5 Vol %
Vapour pressure at 20掳C: 100 mm Hg
Density at 20掳C: 0.861 g/cm鲁
Solubility in / Miscibility with
water: Partly miscible.
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous decomposition products:
When heated, the solvents are evaporated and rosin may be thermally degraded to liberate aliphatic aldehydes,
acids, and terpenes.
11 Toxicological information
Acute toxicity:
LD/LC50 values relevant for classification:
67-56-1 methanol
Oral LD50 5628 mg/kg (rat)
Dermal LD50 15800 mg/kg (rabbit)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
Methanol is a poisonous, narcotic chemical that may exert its effects through inhalation, skin absorption, or
ingestion. Body elimination of methanol is slow and the toxic effects can be compounded.
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Toxic
(Contd. on page 5)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 4)
Irritant
12 Ecological information
General notes: Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
Product:
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
European waste catalogue
14 06 03 other solvents and solvent mixtures
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID (cross-border)
ADR/RID class: 3 Flammable liquids.
Danger code (Kemler): 336
UN-Number: 1230
Packaging group: II
Hazard label 3+6.1
Description of goods: 1230 METHANOL, mixture
Maritime transport IMDG:
IMDG Class: 3
UN Number: 1230
Label 3+6.1
Packaging group: II
EMS Number: F-E,S-D
Marine pollutant: No
Proper shipping name: METHANOL, mixture
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
UN/ID Number: 1230
Label 3+6.1
Packaging group: II
Proper shipping name: METHANOL, mixture
GB
(Contd. on page 6)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 5)
15 Regulatory information
Code letter and hazard designation of product:
@@
FC
T Toxic
F Highly flammable
Hazard-determining components of labelling:
methanol
Rosin
Risk phrases:
11 Highly flammable.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
43 May cause sensitisation by skin contact.
Safety phrases:
1/2 Keep locked up and out of the reach of children.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
63 In case of accident by inhalation: remove casualty to fresh air and keep at rest.
National regulations:
Technical instructions (air):
Class Share in %
III 71.7
Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and
assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The
data on this Material Safety Data Sheet relates only to this product and does not relate to use with any other
material or in any process. All chemical products should be used only by, or under the direction of, technically
qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling.
Hazard communication regulations require that employees must be trained on how to use a Material Safety Data
Sheet as a source for hazard information.
Relevant R-phrases
11 Highly flammable.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
36/38 Irritating to eyes and skin.
(Contd. on page 7)
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Material Safety Data Sheet
According to 91/155 EC
Printing date 04.11.2003 Reviewed on 04.11.2003
Trade name: 82M-1
(Contd. of page 6)
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
43 May cause sensitisation by skin contact.
Department issuing MSDS: Product Safety
Contact: Heather Holich, MSDS Coordinator Tel. (847)699-5755
GB
DR
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