Material Safety Data Sheet (MSDS)
Current Product Status: Active
MSDS Status:
Product Name: ULTRA-SHIELD TAR ROOF COATING Revision Date: 2003-12-12
5314 Version: 2003.1
Product Code:
200235
MSDS No.:
SECTION I - CHEMICAL PRODUCT/COMPANY IDENTIFICATION
MIXTURE
Chemical Name:
NOT APPLICABLE
CAS No.:
COLD APPLIED TAR ADHESIVE
Product Description:
3 2 0
Hazard Classification: HEALTH - FLAMMABILITY - REACTIVITY -
GMX, INC.
Manufacturer/Supplier:
9105 WAY AVE.
CLEVELAND, OHIO 44105
PH: (216) 641-7502 FAX: (216) 641-0633
http://www.gmxwaterproofing.com
Internet Address:
24 HR EMERGENCY ASSISTANCE: 1-800-762-8225
SECTION II - HAZARDOUS INGREDIENTS/COMPOSITION
AGCIH TLV WEIGHT
HAZARDOUS INGREDIENTS CAS NUMBER (TWA) %
0.2mg/m3**
REFINED COAL TAR PITCH 65996-93-2 <70
HYDROCARBON SOLVENT 64742-95-6 100 ppm <20
10 mg/m3*
TALC 14807-96-6 <7
5 mg/m3*
STYRENE BUTADIENE POLYMER 9003-55-8 <7
5 mg/m3*
CELLULOSE FIBER 9004-34-6 <3
** Coal Tar Pitch volatiles (benzene soluble fraction)
SECTION III - HAZARDS IDENTIFICATION
ROUTES OF ENTRY: INHALATION, DERMAL, INGESTION.
ACUTE HEALTH HAZARD:
INHALATION: Overexposure to fumes, vapors or dust can cause temporary respiratory tract
irritation and may include coughing, sneezing, and swollen or irritated nasal, mucousa, or
sinuses. Prolonged exposure in significant excess of permissible air concentrations can
result in systemic symptoms such as:
salivation; vomiting; respiratory difficulties; headache; loss of pupillary reflexes;
dizziness; weakness; possible loss of coordination and collapse; cyanosis; hypothermia; and
convulsions.
SKIN CONTACT: Direct skin contact can result in irritation, which, when accentuated by
sunlight, may result in phototoxic skin reaction. Prolonged and repeated skin contact in the
absence of recommended hygiene practices may cause acne, folliculitis and more serious skin
disorders such as changes in skin pigmentation, ulcerations, benign skin growths and skin
cancer.
EYES CONTACT: Overexposure to product fumes, vapors or dusts can result in irritation and
burning to the eyes. Eye contact with this product will result in irritation, which in the
absence of recommended first aide, can result in minor burns to the eyes.
INGESTION: Ingestion may result in irritation of the gastrointestinal tract accompanied by one
or more of the following: nausea and vomiting, abdominal discomfort, rapid pulse, etc.. In
extreme cases, cardiovascular collapse may occur.
EFFECTS OF CHRONIC EXPOSURE: Prolonged or repeated contact over many years in the absence of
recommended exposure control/personal protection measures and first aid may lead to changes in skin
pigmentation, benign skin growths, and in some cases, skin cancer. These effects appear to be
exacerbated by exposure to sun. In addition, inhalation if vapors over a period of several years
also in the absence of recommended exposure control/personal protection measures may present a lung
cancer hazard.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders may be at
increased risk from exposure. Individuals with chronic respiratory disorders may be more
susceptible to the effects of exposure to any vapor, fume, or airborne particulate matter. Persons
with a history of central nervous system (CNS) functional illness may be more susceptible to the
effects when working with this product.
CARCINOGENICITY: NTP - X; IARC - X; OSHA - X; ACGIH 鈥? X
** THERE HAS BEEN NO CONCLUSIVE EVIDENCE OF SEVERE OR PROLONGED DISORDERS INCLUDING LUNG CANCER
FROM THE NORMAL SAFE RECOMMENDED USE OF COAL TAR ALONE. Long-term overexposure to Coal Tar Pitch
Volatiles in excess of the Permissible Exposure Limit may cause cancer. A laboratory study has
shown that extreme overexposure to Coal Tar Pitch Particulate resulted in lung cancer in
experimental animals. The route of administration and the doses used in the animal study were
extreme; human exposure of this magnitude is not expected to occur with any use of this product.
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SECTION IV - FIRST AID PROCEDURES
INHALATION: Remove victim from exposure area immediately to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical attention
immediately. Keep person warm and quiet.
SKIN CONTACT: If contact occurs, remove contaminated clothing/shoes and wash exposed area with
non-abrasive soap and water. Do not use solvents on skin as they promote absorption of this
material. If irritation persists, get medical attention. Do not re-use work clothing until
they have been thoroughly cleaned.
EYE CONTACT: If eye contact occurs, flush eyes immediately with large amounts of water,
occasionally lifting eyelids and get medical attention.
INGESTION: Give 3-4 glasses of water, but DO NOT induce vomiting. If vomiting occurs, give fluids
again. Get medical attention to determine whether vomiting or evacuation of the stomach is
necessary. Do not give anything by mouth to an unconscious or convulsing person. Consult local
Poison Control Center , IMMEDIATELY!
DECONTAMINATION PROCEDURES: Use emergency shower if available. Remove all contaminated clothing
to prevent further absorption. Wash all clothing and exposed areas of the body twice with soap
and water. Leather shoes that have been saturated should be discarded.
SECTION V - FIRE AND EXPLOSION HAZARD DATA
Minimum 1120F (440C) TCC (hydrocarbon solvent)
FLASH POINT:
9100F (4880C)
AUTOIGNITION TEMPERATURE:
LEL (LOWER EXPLOSION LIMIT): 0.5% (hydrocarbon solvent)
UEL (UPPER EXPLOSION LIMIT): 6.0% (hydrocarbon solvent)
EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemicals, or water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Self-contained (full face MSHA/NIOSH) breathing apparatus and
full protective clothing should be worn when fumes and/or smoke are present.
Water or foam can be used to contain unconfined tar fires, however, water may cause frothing or
eruption in confined fires (tanks, etc.) which may endanger the life of the fire fighter.
Normal fire fighting procedures may be used. Use water or water spray to cool fire exposed
containers and structures and to protect personnel.
UNUSUAL FIRE AND EXPLOSION HAZARD: Burning may emit hazardous fumes/vapors which may be in
concentrations greater that PEL/TLVs. Coal tar pitch at elevated temperatures may generate
vapors that can form flammable/explosive mixtures in the presence of air and a source of
ignition. Airborne pitch dust can form explosive mixtures with air. Closed containers may
explode when exposed to extreme heat. Liquid molten pitch at elevated temperatures will sustain
combustion. Water/fog can control unconfined tar fires, but water may cause frothing or
eruption in closed tanks. When heated to decomposition, it emits carbon monoxide and dioxide,
oxides of nitrogen and sulfur, and hydrocarbons from combustion.
SECTION VI - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF RELEASED OR SPILLED: Avoid breathing vapors and contact with the skin and
eyes. For large spills eliminate all ignition sources (flares, flames, pilot lights, electrical
sparks). Attempt to eliminate the spill at the source (close valves, upright drums, etc.), if
possible without hazard. Ventilate the spill area if it occurs indoors. Contain the spill or
leak with sand, clay, earth, floor absorbent, or other material. Collect in proper containers
for disposal.
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Keep spills and cleaning run-off out of municipal sewers and open bodies of water. Spills or
releases to the environment may require notifications to appropriate Federal, State, and Local
authorities.
EPA Hazardous Waste Number: D001 (Ignitable per 40 CFR 260.21)
SECTION VII - SAFE HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: Avoid prolonged and repeated contact with skin or breathing of
vapors, dusts, or fumes. Ensure work area is well ventilated. Wear appropriate protective
equipment (see section VIII).
DO NOT LET AIR INTAKES DRAW ODOR INDOORS.
KEEP OUT OF REACH OF CHILDREN.
CONTAMINATED EQUIPMENT REPAIR/MAINTENANCE PRECAUTIONS: Wear protective equipment when performing
maintenance on contaminated equipment.
SECTION VIII - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: Use in areas with adequate natural ventilation or provide sufficient local/general
exhaust ventilation in pattern/volume to maintain concentrations below the PEL/TLV and to
maintain areas below flammable or explosive level concentrations.
GLOVES: Use chemical resistant, if needed, to avoid prolonged or repeated skin contact.
EYE PROTECTION: Use safety glasses, splash goggles or face shield when eye contact may occur.
RESPIRATOR: If under normal conditions of use, irritation occurs, or if the TLV is exceeded, use a
NIOSH/MSHA approved air purifying respirator with organic vapor cartridges or canisters and a
dust/mist pre-filter. In situations where the H2S exceeds the PEL or TLV, supplied air
respirators or SCBA's are required.
SKIN PROTECTION: For exposed skin, use protective barrier creams. Also protect skin from direct
sunlight. For outdoor work use approved waterproof sunscreen with an SPF of 25 or greater.
Re-apply every 90 minutes while in direct sun.
CLOTHING: Full long-sleeved clothing closed at the neck and non-porous gloves are recommended. In
addition, aprons, jackets, caps, and shoes are recommended to prevent skin contact with coal
tar. To further reduce skin exposure, apply approved creams to form an un-penetrable barrier on
the skin. A complete change of work clothing should be used each day. Launder separately from
other household clothing.
HYGIENIC PRACTICES: Wash hands thoroughly before eating, drinking, smoking or using the restroom.
A complete soap/water shower and/or steam bath should be taken at the end of every work day.
Provide readily available eye wash and wash stations.
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SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS
3130F (1560C) (hydrocarbon solvent)
BOILING POINT:
SPECIFIC GRAVITY: Greater than 1.00 (water = 1)
VAPOR PRESSURE: 2.7mm Hg for solvent
VAPOR DENSITY: 4.2 for solvent (air = 1)
EVAPORATION RATE: 0.37 for solvent (Ethyl Ether = 1)
SOLUBILITY IN WATER: NEGLIGIBLE
pH: NOT APPLICABLE
% VOLATILE by VOLUME: <30
SECTION X - STABILITY AND REACTIVITY DATA
STABILITY: Stable under normal conditions. Avoid handling near open flame.
CONDITIONS TO AVOID: Open flames and intense heat.
MATERIALS TO AVOID: Strong oxidizers. Also avoid contact with water when confined and in a
molten state.
HAZARDOUS DECOMPOSITION: Carbon monoxide and dioxide, oxides of nitrogen and sulfur, hydrocarbons
from combustion.
WILL POLYMERIZATION OCCUR: No
SECTION XI - TOXICOLOGICAL INFORMATION
DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS: Long term exposure to Coal Tar Pitch Volatiles (CTPV),
above the recommended exposure limit, has been associated with the development of skin, kidney,
and lung cancer.
OTHER DATA: IARC Group 1 - Sufficient evidence of carcinogenicity in humans. No scientific study
supports an association between coal tar pitch exposure and human reproductive hazards.
Available data characterizes coal tar pitch as a mutagen.
SECTION XII - ECOLOGICAL INFORMATION
EPA Hazardous Waste Number: D001 (Ignitable per 40 CFR 260.21)
Reportable Quantity (RQ), EPA Regulation 40 CFR 302: (CERCLA Section 102):
Substance Weight % RQ (lbs)
Anthracene 0.23 5,000
Naphthalene 0.08 100
Benzo (a) Pyrene 0.20 1
Pyrene 0.17 5,000
Chrysene 0.21 100
Acenaphthene 0.13 100
Benzo (a) Anthracene 0.22 1
Benzo (b&k) Flouranthene 0.42 1
Benzo (g,h,i) Perylene 0.12 5,000
Benzo (a,h) Anthracene 0.06 1
Dibenzofuran 0.09 1
Flourene 0.15 5,000
Flouranthene 0.21 1
Indeno (1,2,3,c,d) Pyrene 0.11 1
Phenanthrene 0.57 5,000
Note: THIS INFORMATION REQUIRED FOR EMERGENCY RESPONCE REPORTING.
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Extremely Hazardous Substance(s) Threshold Planing Quantity (TPQ),
EPA Regulation 40 CFR 355: (SARA Section 302):
Substance Weight % TPQ (lbs) RQ (lbs)
Pyrene 1.3 max 10,000 5,000
Toxic Chemical Release Reporting, EPA regulation 40 CFR 372: (SARA 313):
Substance Weight % CAS No.
Anthracene 0.3 max 120-12-7
Phenanthrene 0.7 max 85-01-8
Naphthalene 0.1 max 91-20-3
EPA Hazard Classification Code:
Acute Cronic Fire Pressure Reactive Not
Hazard Hazard Hazard Hazard Hazard Applicable
XXX XXX XXX
SECTION XIII - DISPOSAL CONSIDERATIONS
Dispose of according to applicable Federal, State, County, and Local requirements.
EPA Hazardous Waste Number: D001 (Ignitable per 40 CFR 260.21)
SECTION XIV - TRANSPORTATION INFORMATION
NON-BULK < 119 gallon container size
DOT-U.S./MOT-CANADA/INTL.(TRUCK/RAIL)
PROPER SHIPPING NAME: NONREGULATED MATERIAL
HAZARD CLASS: NOT APPLICABLE
IDENTIFICATION NO: NOT APPLICABLE
PACKAGING GROUP: NOT APPLICABLE
Reclassed under 49CFR 173.120(b)(2). Not regulated under 49CFR 173.150(f)(2).
BULK > 119 gallon container size
DOT-U.S./MOT-CANADA/INTL.(TRUCK/RAIL)
PROPER SHIPPING NAME: COAL TAR DISTILLATES
HAZARD CLASS: 3
IDENTIFICATION NO: UN1136
PACKAGING GROUP: III
INTL.(VESSEL/AIR) - NON-BULK < 119 gallon container size
PROPER SHIPPING NAME: COAL TAR DISTILLATES
HAZARD CLASS: 3
IDENTIFICATION NO: UN1136
PACKAGING GROUP: III
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SECTION XV - REGULATORY INFORMATION
SARA 313: This product contains the following material(s) subject to the reporting requirements
under Section 313 of Title III of the Superfund Amendments and Reauthorization Act and 40 CFR
372, all at a concentration of above 0.1%:
Anthracene 0.3% max CAS No. 120-12-7
Phenanthrene 0.7% max CAS No. 85-01-8
Naphthalene 0.1% max Cas No. 91-20-3
VOC STATUS: Less than 270 g/l. This product complies with the VOC codes of all State and Federal
regulations.
CA PROP 65: This products contains a chemical known to the State of California to cause cancer.
SECTION XVI - ADDITIONAL INFORMATION
CHANGES: Update format
Disclaimer
The information contained in this Material Safety Data Sheet has been prepared in accordance with
the OSHA Hazard communication Standard CFR 1910.1200. This information relates specifically to
the product designated and may not be valid for the product when used in combination with any
other materials or products or in a particular process. The information is, to the best of our
knowledge and belief, accurate and reliable as of the date compiled. However, no representation,
warranty or guarantee is made as to its accuracy, reliability or completeness, whether originating
within the company or not. The user should review this information, satisfy itself as to its
suitability and completeness, and pass on the information to its employees or customers in
accordance with applicable federal, state or local hazard communications requirements. We do not
accept responsibility for any loss or damage which may occur from the use of this information.
John Wenneman 04/09/2003
Prepared By: Date:
John Wenneman
Modified By:
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