Page : 1
SAFETY DATA SHEET
Revised edition no : 3
Date : 20/3/2006
Supersedes : 6/2/2006
PYRUS 400 SC
CA701576
www.lisam.com
N : Dangerous for
the environment
1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Identification of the product : Pyrimethanil 400 g/L SC.
Trade name : PYRUS 400 SC.
Horticulture
Use :
Type of product : Fungicide.
ADRIA NZ LTD.PO
Company identification :
Tel. : +64 9 4129817
Fax : +64 9 4129807
http://www.adriacp.co.nz
Emergency phone nr :0800 POISON (0800 764 766)
2 COMPOSITION / INFORMATION ON INGREDIENTS
This product is considered to be hazardous and contains hazardous components.
Substance name Contents CAS No / EC No / Index No Symbol(s) R-Phrase(s)
: 384 to 415 g/L 53112-28-0 / ----- / ----- N 51/53
Pyrimethanil
Log P octanol / water at 20掳C : 2.84
Rat oral LD50 [mg/kg] : 4150
Percutaneous (rat) LD50 [mg/kg] : > 5000
Rat inhalation LC50 [mg/l/4h] : > 1.98
LC50-96 Hour - fish [ppm] : 10.56
EC50 24-72h Algae [mg/l] : 1.2
IC50 48h Daphnia magna [mg/l] : 2.9
3 HAZARDS IDENTIFICATION
Environmental hazard : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Primary route of exposure : Skin and eyes contact. Ingestion.
Symptoms relating to use
- Skin contact : Non-sensitizer. Not expected to be an irritant.
- Eye contact : Not expected to present a significant eye contact hazard under anticipated
conditions of normal use.
- Ingestion : Health hazard if ingested in large quantities. Keep away from food, drink and animal
feeding stuffs.
4 FIRST AID MEASURES
First aid measures
- Inhalation : Assure fresh air breathing. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Seek medical advice.
- Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse. Seek medical attention if ill effect develops.
- Eye contact : Check for and remove any contact lenses. In case of eye contact, immediately rinse
with clean water for 10-15 minutes. Obtain emergency medical attention if pain,
blinking, tears or redness persist.
- Ingestion : DO NOT INDUCE VOMITING. If swallowed, rinse mouth with water (only if the
GRIPHAR S.A.
ue de Renory, 26/1 B-4102 Ougr茅e Belgique-Belgie Tel. : +32 (0)4 385 97 11
Page : 2
SAFETY DATA SHEET
Revised edition no : 3
Date : 20/3/2006
Supersedes : 6/2/2006
PYRUS 400 SC
CA701576
www.lisam.com
4 FIRST AID MEASURES (continued)
person is conscious). Seek medical advice (show the label where possible).
5 FIRE-FIGHTING MEASURES
Extinguishing media
- Suitable extinguishing media : Small fire: Dry chemical.
Large fire: Water fog. Water spray. Alcohol foam.
- Not to be used : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
Specific hazards : When heated to decomposition, emits dangerous fumes. Nitrogen oxides. Carbon
*
monoxide. Carbon dioxide.
Protection against fire : Do not enter fire area without proper protective equipment, including respiratory
protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to
enter environment.
6 ACCIDENTAL RELEASE MEASURES
General precautions : No smoking.
Personal precautions : Keep public away from danger area. Spill should be handled by trained cleaning
personnel properly equipped with respiratory and eye protection.
Environmental precautions : Notify authorities if liquid enters sewers or public waters.
Clean up methods : Clean up any spills as soon as possible, using an absorbent material to collect it.
Dilute residues and flush.
7 HANDLING AND STORAGE
General : Ventilate confined spaces before enter. No naked lights. No smoking.
*
Technical protective measures : Ground well.
*
Storage : Keep only in the original container in a cool, well ventilated place. Protect from
*
freezing.
Handling : Wash hands and other exposed areas with mild soap and water before eat, drink or
*
smoke and when leaving work. Handle in accordance with good industrial hygiene
and safety procedures. For even minor contact, immediately remove contaminated
clothing/wash skin thoroughly with mild soap / water.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
- Respiratory protection : Where exposure through inhalation may occur from use, approved respiratory
protection equipment is recommended.
- Hand protection : Wear suitable gloves resistant to chemical penetration.
- Skin protection : Skin protection appropriate to the conditions of use should be provided.
- Eye protection : Chemical goggles or face shield with safety glasses.
- Ingestion : When using, do not eat, drink or smoke.
Industrial hygiene : Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Local exhaust and general ventilation must be adequate to meet exposure
standards.
AGRIPHAR S.A.
Rue de Renory, 26/1 B-4102 Ougr茅e Belgique-Belgie Tel. : +32 (0)4 385 97 11
Page : 3
SAFETY DATA SHEET
Revised edition no : 3
Date : 20/3/2006
Supersedes : 6/2/2006
PYRUS 400 SC
CA701576
www.lisam.com
9 PHYSICAL AND CHEMICAL PROPERTIES
Physical state at 20 掳C : Liquid.
Colour : White.
Odour : Negligible.
pH value : 5.8
Density : 1.08
Viscosity : 799 cPs, 25掳C.
Solubility in water : In water, the material disperses.
Others : Particles size (mean): < 3.0 碌m.
Residue (sieve of 315 碌m): Negligible.
Residue (sieve of 150 碌m): < 0.01%
Residue (sieve of 40 碌m): < 0.1%
10 STABILITY AND REACTIVITY
Stability and reactivity : Stable under normal conditions.
Hazardous decomposition products : Nitrogen oxides. Carbon monoxide. Carbon dioxide.
*
Hazardous Polymerization : Will not occur.
Materials to avoid : Oxidizing agent.
11 TOXICOLOGICAL INFORMATION
Acute toxicity
- Dermal : Normally considered as not dangerous for the skin. Non-sensitizer.
- Ocular : Not expected to present a significant eye contact hazard under anticipated
conditions of normal use.
Rat oral LD50 [mg/kg] : >2000
Rabbit dermal LD50 [mg/kg] : >2000
Rat inhalation LC50 [mg/l/4h] : >5
12 ECOLOGICAL INFORMATION
Ecological effects information : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
LC50-96 Hour - fish [mg/l] : 61.7
EC50 24-72h Algae [mg/l] : 14.8
IC50 48h Daphnia magna [mg/l] : 8.22
13 DISPOSAL CONSIDERATIONS
General : Avoid release to the environment. Dispose of this material and its container at
hazardous or special waste collection point. Dispose in a safe manner in
accordance with local/national regulations.
14 TRANSPORT INFORMATION
General information : Ensure vehicle driver is aware of the potential hazards of the load and knows what
to do in the event of an accident or an emergency.
Land transport
- Proper shipping name : UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (
Pyrimethanil, 40% solution), 9, III
- UN No. : 3082
- H.I. nr : 90
- ADR/RID : Class : 9
AGRIPHAR S.A.
Rue de Renory, 26/1 B-4102 Ougr茅e Belgique-Belgie Tel. : +32 (0)4 385 97 11
Page : 4
SAFETY DATA SHEET
Revised edition no : 3
Date : 20/3/2006
Supersedes : 6/2/2006
PYRUS 400 SC
CA701576
www.lisam.com
14 TRANSPORT INFORMATION (continued)
- ADR/RID Packing group : Group : III
- Hazard Label(s)
Sea transport
- Proper shipping name : UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (
Pyrimethanil, 40% solution), 9, III
- IMO-IMDG code : Class : 9
- IMO Packing group : Group : III
- IMDG-Marine pollution : No.
- Hazard Label(s)
Air transport
- Proper shipping name : UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (
Pyrimethanil, 40% solution), 9, III
- IATA - Class or division : Class : 9
- IATA Packing group : Group : III
- Packing instruction : 914/NO LIMIT - 914 NO LIMIT
- Hazard Label(s)
15 REGULATORY INFORMATION
- Symbol(s) : N : Dangerous for the environment
- R Phrase(s) : R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
- S Phrase(s) : S2 : Keep out of the reach of children.
S13 : Keep away from food, drink and animal feedingstuffs.
S20/21 : When using, do not eat, drink or smoke.
S23 : Do not breathe spray.
S35 : This material and its container must be disposed of in a safe way.
S61 : Avoid release to the environment. Refer to special instructions/Safety data
sheets.
16 OTHER INFORMATION
Further information : Revision - See : *
The contents and format of this SDS are in accordance with EEC Commission Directive 2001/58EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected
with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be applicable.
End of document
AGRIPHAR S.A.
Rue de Renory, 26/1 B-4102 Ougr茅e Belgique-Belgie Tel. : +32 (0)4 385 97 11
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