MATERIAL SAFETY DATA SHEET
S00206
02 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER DATE OF PREPARATION HMIS CODES
Health 2*
S00206 06-SEP-07 Flammability 4
Reactivity 0
PRODUCT NAME
SPRAYON庐 All-Purpose Silicone Lube
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
Consumer Group - Industrial
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 251-2486
Regulatory Information
(216) 566-2902 www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency for Chemical Emergency ONLY (spill, leak,
(800) 424-9300 fire, exposure, or accident)
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
15 74-98-6 Propane
ACGIH TLV 2500 ppm 760 mm
OSHA PEL 1000 ppm
41 110-54-3 Hexane
ACGIH TLV 50 ppm 127 mm
OSHA PEL 50 ppm
19 107-83-5 Isohexane Isomers
ACGIH TLV Not Available 211 mm
OSHA PEL Not Available
7 96-14-0 3-Methylpentane
ACGIH TLV 500 ppm 211 mm
OSHA PEL Not Available
6 79-29-8 2,3-Dimethylbutane
ACGIH TLV Not Available 230 mm
OSHA PEL Not Available
2 75-83-2 2,2-Dimethylbutane
ACGIH TLV Not Available 317 mm
OSHA PEL Not Available
2 110-82-7 Cyclohexane
ACGIH TLV 100 ppm 100 mm
OSHA PEL 300 ppm
Continued on page 2
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Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT LEL UEL
Propellant < 0 F 1.0 9.5
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Continued on page 3
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Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Continued on page 4
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Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 5.43 lb/gal 650 g/l
SPECIFIC GRAVITY 0.65
BOILING POINT <0 - 179 F <-18 - 81 C
MELTING POINT Not Available
VOLATILE VOLUME 95 %
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 94.00% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged and repeated exposure to Hexane may cause damage to nerve
tissue of the arms and legs (peripheral neuropathy), resulting in muscular
weakness and loss of sensation. This effect may be increased by the
presence of Methyl Ethyl Ketone.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
TOXICOLOGY DATA
Continued on page 5
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CAS No. Ingredient Name
74-98-6 Propane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
110-54-3 Hexane
LC50 RAT 4HR Not Available
LD50 RAT 28700 mg/kg
107-83-5 Isohexane Isomers
LC50 RAT 4HR Not Available
LD50 RAT Not Available
96-14-0 3-Methylpentane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
79-29-8 2,3-Dimethylbutane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
75-83-2 2,2-Dimethylbutane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
110-82-7 Cyclohexane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Continued on page 6
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Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
110-54-3 Hexane 41
110-82-7 Cyclohexane 2
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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