SAFETY DATA SHEET according to EC directive 2001/58/EC
CAPITAN庐 25
Version 2.1
Revision Date 16.10.2006 Ref. 130000023529
This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory
requirements in other countries.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
CAPITAN庐 25
Product name :
Synonyms : B11995500
: DPX- H6573-462
Use of the : Fungicide
Substance/Preparation
Company Du Pont (UK) Limited
:
Wedgwood Way
Stevenage, Herts. SG1 4QN
United Kingdom
Telephone : +44-1438-734.000
Emergency telephone : +44-(0)8456-006.640
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. EC-No. Classification Concentration [%]
Flusilazole 85509-19-9 Carc.Cat.3; R40 25
Repr.Cat.2; R61
Xn; R22
N; R51 -R53
Diisobutyl ketone 108-83-8 203-620-1 R10 >= 20 - < 25
Xi; R37
Xi; R36 -R52/53
Ethoxylated Polyarylphenol 99734-09-5 >= 5 - < 10
1,2-Benzisothiazolin-3-one 2634-33-5 220-120-9 Xn; R22 <1
Xi; R38 -R41
R43
N; R50
For the full text of the R phrases mentioned in this Section, see Section 16.
3. HAZARDS IDENTIFICATION
Harmful if swallowed.
Irritating to skin.
Limited evidence of a carcinogenic effect.
May cause harm to the unborn child.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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4. FIRST AID MEASURES
General advice : Never give anything by mouth to an unconscious person. For specialist advice
physicians should contact the National Poisons Information Service, (24-hr), Tel:
0870-600-6266.
Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician.
Skin contact : Wash off immediately with soap and plenty of water. Take off contaminated
clothing and shoes immediately. In the case of skin irritation or allergic reactions
see a physician. Wash contaminated clothing before re-use.
Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide
open while rinsing. Consult a physician.
Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Call a physician immediately.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Water spray, Dry powder, Foam, Carbon dioxide (CO2),
media
Extinguishing media which : High volume water jet, (contamination risk),
must not be used for safety
reasons
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters
Further information : Prevent fire extinguishing water from contaminating surface water or the ground
water system. Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations. Collect contaminated fire
extinguishing water separately. This must not be discharged into drains.
(on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool containers
/ tanks with water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use personal protective equipment.
Environmental precautions : Prevent further leakage or spillage if safe to do so. Use appropriate container to
avoid environmental contamination. Do not flush into surface water or sanitary
sewer system. Do not allow material to contaminate ground water system. Local
authorities should be advised if significant spillages cannot be contained. If the
product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Clean-up methods - small spillage Soak up with inert absorbent material. Sweep
up or vacuum up spillage and collect in suitable container for disposal.
Clean-up methods - large spillage Prevent further leakage or spillage. Large
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SAFETY DATA SHEET according to EC directive 2001/58/EC
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Revision Date 16.10.2006 Ref. 130000023529
spills should be collected mechanically (remove by pumping) for disposal.
Collect leaking liquid in sealable (metal/plastic) containers.
Additional advice : Never return spills in original containers for re-use.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Provide adequate ventilation.
Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion
Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
areas and containers place accessible by authorized persons only. Keep out of reach of children.
Keep away from food, drink and animal feeding stuffs.
Advice on common storage : Keep away from: Oxidizing agents
Storage temperature : > -5 掳C
Other data : Stable under recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Type Control Update Basis
Form of exposure parameters
Diisobutyl ketone 108-83-8 TWA 148 mg/m3 2003 EH40 OES
25 ppm
Propylene glycol 57-55-6 TWA 10 mg/m3 2001 EH40 OES
Particulate.
TWA 474 mg/m3 2001 EH40 OES
Vapor and 150 ppm
particulates.
TWA 10 mg/m3 2005 EH40 WEL
Particulate.
TWA 474 mg/m3 2005 EH40 WEL
Vapor and 150 ppm
particulates.
Engineering measures
Ensure adequate ventilation, especially in confined areas.
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Personal protective equipment
Respiratory protection : Respirator with a vapour filter (EN 141) respirator with A2B2-P3 filter
Hand protection : Material: Nitrile rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: 480 min
Avoid neoprene and natural rubber gloves., Please observe the instructions
regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions
under which the product is used, such as the danger of cuts, abrasion, and the
contact time., The suitability for a specific workplace should be discussed with
the producers of the protective gloves.
Eye protection : Safety glasses with side-shields conforming to EN166 Face-shield
Skin and body protection : Lightweight protective clothing Long sleeved clothing
Hygiene measures : Wash hands before breaks and immediately after handling the product. When
using do not eat, drink or smoke. Keep away from food, drink and animal
feeding stuffs. For environmental protection remove and wash all contaminated
protective equipment before re-use. Dispose of rinse water in accordance with
local and national regulations.
Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid,
Colour : milky, white,
Odour : aromatic,
pH : 6,8 at 10 g/l ( 20 掳C)
Flash point : 84,6 掳C
Autoignition temperature : 475 掳C
Explosive properties : Not explosive
Density : 1,004 g/cm3
Partition coefficient (n- : POW: 5 495 log Pow: 3,74 , Active ingredient
octanol/water)
Viscosity, dynamic : 86 mPa/s at 25,1 掳C
10. STABILITY AND REACTIVITY
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Conditions to avoid : Temperature : < 5 掳C
Materials to avoid : Incompatible with oxidizing agents.
Hazardous decomposition : Carbon oxides, Sulphur oxides, Hydrogen fluoride, nitrogen oxides (NOx)
products
Hazardous reactions : Vapours may form explosive mixture with air. No decomposition if stored and
applied as directed.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50/ rat: > 300 mg/kg
Acute inhalation toxicity
鈥? Flusilazole : LC50/ 4 h/ rat : > 5,0 mg/l
Acute dermal toxicity : LD50/ rat > 5,000 mg/kg
Skin irritation : Irritating to skin.
Eye irritation : No eye irritation
Sensitization : Animal test did not cause sensitization by skin contact.
Carcinogenicity assessment
鈥? Flusilazole : Carcinogenic Category 3, Limited evidence of a carcinogenic effect.
Toxicity to reproduction assessment
鈥? Flusilazole : Toxic to Reproduction Category 2, Experiments have shown reproductive
toxicity effects in male and female laboratory animals.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish : LC50/ 96 h/ Oncorhynchus mykiss (rainbow trout) :: 3,2 mg/l
Toxicity to algae : / EC50/ 72 h/ Selenastrum capricornutum (green algae): 1,6 mg/l
Toxicity to daphnia : / EC50/ 48 h/ Daphnia: 19,5 mg/l
13. DISPOSAL CONSIDERATIONS
Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Do not contaminate ponds, waterways or ditches with chemical or
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used container.
Contaminated packaging : Do not re-use empty containers.
14. TRANSPORT INFORMATION
ADR
Class: 9
Packaging group: III
Classification Code: M6
HI No:: 90
UN-No.: 3082
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Flusilazole)
Further information : Not classified as dangerous in the meaning of sea and air transport regulations.,
Optional classification as per IMDG Special Provison 909., Optional
classification as per IATA Special Provison A97.
15. REGULATORY INFORMATION
Labelling according to EC Directives
Symbol(s) : T Toxic
N Dangerous for the environment
Hazardous components: Flusilazole
Diisobutyl ketone
Ethoxylated Polyarylphenol
1,2-Benzisothiazolin-3-one
R-phrase(s) : R22 Harmful if swallowed.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R61 May cause harm to the unborn child.
R51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
S-phrase(s) : S23 Do not breathe spray.
S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S38 In case of insufficient ventilation, wear suitable respiratory
equipment.
S46 If swallowed, seek medical advice immediately and show this
container or label.
S53 Avoid exposure - obtain special instructions before use.
S35 This material and its container must be disposed of in a safe
way.
S57 Use appropriate container to avoid environmental
contamination.
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Special labelling of certain : To avoid risks to man and the environment, comply with the instructions for use.
preparations
Sensitising components contains:
1,2-Benzisothiazolin-3-one
May produce an allergic reaction.
Further information : Restricted to professional users.
16. OTHER INFORMATION
Text of R phrases mentioned in Section 2
R10 Flammable.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R51 Toxic to aquatic organisms.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment.
R61 May cause harm to the unborn child.
Further information
Take notice of the directions of use on the label.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
above information relates only to the specific material(s) designated herein and may not be valid for such material(s)
used in combination with any other materials or in any process or if the material is altered or processed, unless
specified in the text.
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Revision Date 16.10.2006 Ref. 130000023529
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