SAFETY DATA SHEET according to EC directive 2001/58/EC
OPTION庐
Version 2.1
Revision Date 03.07.2006 Ref. 130000013486
This SDS adheres to the standards and regulatory requirements of the Republic of Ireland and may not meet the
regulatory requirements of other countries.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
庐
Product name : OPTION
Synonyms : B10923139
: DPX-T3217 60WG
Use of the : Fungicide
Substance/Preparation
Company Du Pont (UK) Limited
:
Wedgwood Way
Stevenage, Herts. SG1 4QN
United Kingdom
Telephone : +44-1438-734.000
Emergency telephone : +44-(0)8456-006.640
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. EC-No. Classification Concentration [%]
Cymoxanil 57966-95-7 261-043-0 Xn; R22 60
R43
N; R50 -R53
Sodiumalkylnaphthalenesulfonate, 68425-94-5 Polymer Xi; R36/38 >= 1 - < 10
formaldehyde polymer
Sodium dihydrogenphosphate 7558-80-7 231-449-2 Xi; R36/37/38 >= 1 - < 5
Fumaric Acid 110-17-8 203-743-0 Xi; R36 >= 1 - < 5
Arylalkyl Sulphonate 1322-93-6 215-343-3 Xn; R22 >= 1 - < 5
Xi; R36
For the full text of the R phrases mentioned in this Section, see Section 16.
3. HAZARDS IDENTIFICATION
Harmful if swallowed.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice : Never give anything by mouth to an unconscious person. If breathing is irregular
or stopped, administer artificial respiration. For specialist advice physicians
should contact the National Poisons Information Service, Beaumont Hospital,
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OPTION庐
Version 2.1
Revision Date 03.07.2006 Ref. 130000013486
Dublin. Tel: 01-8379964/8379966.
Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Call a physician
immediately.
Skin contact : Take off contaminated clothing and shoes immediately. Wash off immediately
with soap and plenty of water. In the case of skin irritation or allergic reactions
see a physician. Wash contaminated clothing before re-use.
Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide
open while rinsing. If eye irritation persists, consult a specialist.
Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Call a physician immediately.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Water spray, Dry chemical, Foam, Carbon dioxide (CO2),
media
Extinguishing media which : High volume water jet, (contamination risk),
must not be used for safety
reasons
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters
Further information : (on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool containers
/ tanks with water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use personal protective equipment.
Environmental precautions : Use appropriate container to avoid environmental contamination. Prevent further
leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system. Do not allow material to contaminate ground water system. Local
authorities should be advised if significant spillages cannot be contained. If the
product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Clean up promptly by scoop or vacuum. Use approved industrial vacuum
cleaner for removal. Shovel into suitable container for disposal.
Additional advice : Never return spills in original containers for re-use.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed. Wear
personal protective equipment.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
OPTION庐
Version 2.1
Revision Date 03.07.2006 Ref. 130000013486
Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion
Storage
Requirements for storage : Keep in a dry, cool and well-ventilated place. Store in a place accessible by
areas and containers authorized persons only. Keep out of reach of children.
Advice on common storage : Never allow product to get in contact with water during storage. Do not store
near acids.
Other data : No decomposition if stored and applied as directed.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Type Control Update Basis
Form of exposure parameters
Sucrose 57-50-1 TWA 10 mg/m3 2002 ELV (IE)
STEL 20 mg/m3 2002 ELV (IE)
Fumed Silica 112945-52-5 TWA 6 mg/m3 2002 ELV (IE)
Total inhalable
dust.
TWA 2,4 mg/m3 2002 ELV (IE)
Respirable dust.
Engineering measures
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Respiratory protection : Half mask with a particle filter FFP2 (EN149)
Hand protection : Material: Nitrile rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: 480 min
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used, such as the danger of
cuts, abrasion, and the contact time., The suitability for a specific workplace
should be discussed with the producers of the protective gloves.
Eye protection : Safety glasses with side-shields conforming to EN166
Skin and body protection : Lightweight protective clothing
Hygiene measures : Wash hands before breaks and immediately after handling the product. When
using do not eat, drink or smoke. Keep away from food, drink and animal
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Version 2.1
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feeding stuffs. For environmental protection remove and wash all contaminated
protective equipment before re-use. Dispose of rinse water in accordance with
local and national regulations.
Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : solid, dry, free flowing, water dispersible granules,
Colour : light brown,
Odour : sweet,
pH : 4,2 at 10 g/l ( 20 掳 Method: CIPAC MT 75
C),
Flash point : not applicable
Thermal decomposition : Decomposition under influence of moisture is highly accelerated by heating.,
Explosive properties : Not explosive
Solubility/qualitative : dispersible
10. STABILITY AND REACTIVITY
Conditions to avoid : Decomposes slowly on exposure to water.
Materials to avoid : Water, Incompatible with acids.
Hazardous decomposition : Carbon dioxide (CO2), nitrogen oxides (NOx), Hydrogen cyanide (hydrocyanic
products acid)
Hazardous reactions : Decomposes slowly on exposure to water. No decomposition if stored and
applied as directed.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50/ rat: 433 mg/kg
Acute inhalation toxicity : LC50/ 4 h / rat : > 5,0 mg/l
Acute dermal toxicity : LD50/ rat > 5 000 mg/kg
Skin irritation : rabbit
No skin irritation
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Eye irritation : rabbit
No eye irritation
Sensitization : Buehler Test guinea pig Animal test did not cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
Toxicity to fish
鈥? Cymoxanil : LC50 / 96 h/ Oncorhynchus mykiss (rainbow trout) : 61 mg/l
Toxicity to algae
鈥? Cymoxanil : / EC50/ 72 h/ Algae: 0,35 mg/l
Aquatic toxicity
鈥? Cymoxanil : / EC50/ 48 h/ Daphnia: 27 mg/l
Further information on ecology
Additional ecological : No data is available on the product itself.
information
13. DISPOSAL CONSIDERATIONS
Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Do not contaminate ponds, waterways or ditches with chemical or
used container.
Contaminated packaging : Do not re-use empty containers.
14. TRANSPORT INFORMATION
ADR
Class: 9
Packaging group: III
Classification Code: M7
HI No:: 90
UN-No.: 3077
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Cymoxanil)
IATA_C
Class: 9
Packaging group: III
UN-No.: 3077
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SAFETY DATA SHEET according to EC directive 2001/58/EC
OPTION庐
Version 2.1
Revision Date 03.07.2006 Ref. 130000013486
Labelling No.: 9MI
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Cymoxanil)
IMDG
Class: 9
Packaging group: III
UN-No.: 3077
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Cymoxanil)
Further information : Not classified as dangerous in the meaning of sea and air transport regulations.,
Optional classification as per IMDG Special Provison 909., Optional
classification as per IATA Special Provison A97.
15. REGULATORY INFORMATION
Labelling according to EC Directives
Symbol(s) : Xn Harmful
N Dangerous for the environment
Hazardous components: Cymoxanil
R-phrase(s) : R22 Harmful if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrase(s) : S2 Keep out of reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S35 This material and its container must be disposed of in a safe
way.
S46 If swallowed, seek medical advice immediately and show this
container or label.
S57 Use appropriate container to avoid environmental
contamination.
SP 1 Do not contaminate water with the product or its container
(Do not clean application equipment near surface
water/Avoid contamination via drains from farmyards and
roads).
Special labelling of certain : To avoid risks to man and the environment, comply with the instructions for use.
preparations
Sensitising components contains:
Cymoxanil
May produce an allergic reaction.
16. OTHER INFORMATION
Text of R phrases mentioned in Section 2
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OPTION庐
Version 2.1
Revision Date 03.07.2006 Ref. 130000013486
R22 Harmful if swallowed.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
Further information
Take notice of the directions of use on the label.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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