Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 28.06.2006 Reviewed on 28.06.2006
* 1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: Manganese-03 / -3
路 Catalog number: 424383-3
路 Supplier:
Tintometer GmbH
Division AQUALYTIC庐
Schleefstr. 12
D-44287 Dortmund phone: +49(0)231 94510-755
Made in Germany e-mail: sales@aqualytic.de
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Chemical characterization
路 Description: aqueous solution
路 Dangerous components:
CAS: 5470-11-1 hydroxylammonium chloride @ Xn, @ N; R 22-36/38-43-48/22-50 10-20%
G D
EINECS: 226-798-2
EC Number: 612-123-00-2
路 Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
路 Hazard designation:
@
G Xn Harmful
路 Information pertaining to particular dangers for man and environment
R 43 May cause sensitisation by skin contact.
R 48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air; consult doctor in case of symptoms.
路 After skin contact
Instantly rinse with water.
Seek medical treatment.
(Contd. on page 2)
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Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 28.06.2006 Reviewed on 28.06.2006
Product name: Manganese-03 / -3
(Contd. of page 1)
路 After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
路 After swallowing
Rinse out mouth and then drink plenty of water.
Induce vomiting.
路 The following symptoms may occur:
after swallowing and inhalation:
irritations
after absorption:
Cyanosis
methaemoglobin formation
drop in blood pressure
路 Danger risk of skin sensitization
* 5 Fire fighting measures
路 Suitable extinguishing agents Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
nitrogen oxides (NOx)
Hydrogen chloride (HCl)
路 Protective equipment: Wear self-contained breathing apparatus.
路 Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter drains.
Ambient fire may liberate hazardous vapours.
* 6 Accidental release measures
路 Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, universal binders).
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
路 Handling
路 Information for safe handling: Prevent formation of aerosols.
路 Information about protection against explosions and fires: The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility: Not required.
路 Further information about storage conditions:
Protect from heat and direct sunlight.
Protect from humidity and keep away from water.
Protect from the effects of light.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
(Contd. on page 3)
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Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 28.06.2006 Reviewed on 28.06.2006
Product name: Manganese-03 / -3
(Contd. of page 2)
路 Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Protection of hands:
Only use chemical-protective gloves with CE-labelling of category III.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile rubber, NBR
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
Value for the permeation: Level 鈮? 6 (480 min)
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
路 Eye protection: Safety glasses
路 Body protection: Protective work clothing.
* 9 Physical and chemical properties:
Fluid
路 Form:
Colourless
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 100掳C
Not applicable
路 Flash point:
Product is not explosive.
路 Danger of explosion:
1.126 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Fully miscible
Water:
2.9
路 pH-value at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
> 80 %
Water:
< 20 %
路 Solids content:
10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: strong heating
路 Dangerous reactions No dangerous reactions known
路 Dangerous products of decomposition: see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
(Contd. on page 4)
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Page 4/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 28.06.2006 Reviewed on 28.06.2006
Product name: Manganese-03 / -3
(Contd. of page 3)
路 LD/LC50 values that are relevant for classification:
5470-11-1 hydroxylammonium chloride
Oral LD50 400 mg/kg (mouse)
600 mg/kg (rat)
141 mg/kg (MERCK) (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Irritant effect.
路 Sensitization: Sensitization possible by skin contact.
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information: Quantitative data on the ecological effect of this product are not available.
路 Ecotoxical effects:
路 Acquatic toxicity:
5470-11-1 hydroxylammonium chloride
LC50 1-10 mg/l/48h (Leuciscus idus)
路 General notes:
Water danger class 3 (German Regulation) (Self-assessment acc. VwVwS Annex 4): extremely hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into soil.
13 Disposal considerations
路 Product:
路 Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
16 05 07 discarded inorganic chemicals consisting of or containing dangerous substances
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: -
路 Maritime transport IMDG:
-
路 IMDG Class:
No
路 Marine pollutant:
路 Air transport ICAO-TI and IATA-DGR:
-
路 ICAO/IATA Class:
(Contd. on page 5)
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Page 5/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 28.06.2006 Reviewed on 28.06.2006
Product name: Manganese-03 / -3
(Contd. of page 4)
路 Transport/Additional information: Not dangerous according to the above specifications.
15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xn Harmful
路 Hazard-determining components of labelling:
hydroxylammonium chloride
路 Risk phrases:
43 May cause sensitisation by skin contact.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
路 Safety phrases:
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
路 National regulations
路 Information about limitation of use:
Employment restrictions concerning young persons must be observed.
Employment restrictions concerning pregnant and lactating women must be observed.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
22 Harmful if swallowed.
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
50 Very toxic to aquatic organisms.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
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