MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
1. PRODUCT AND COMPANY IDENTIFICATION
NAUGALUBE庐 TPP
Product name :
Triphenyl phoshite
Chemical name:
No specific information
Use of substance/preparation:
Chemtura USA Corporation
Supplier:
Chemtura Corporation (Worldwide HQ)
199 Benson Road
Middlebury, CT 06749 USA
CHEMTREC (24 hours) 800-424-9300
Emergency telephone
For additional emergency telephone numbers see section 16 of the Safety Data Sheet.
number:
866-430-2775
Environmental, Health and
Safety Department:
877-948-2660
Customer Service:
2. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT
Triphenyl phosphite > 99
CAS# 101-02-0
Phenol <1
CAS# 108-95-2
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION!
MAY CAUSE EYE AND SKIN IRRITATION.
MAY CAUSE SENSITIZATION BY SKIN CONTACT.
CAN BURN IN A FIRE CREATING DENSE TOXIC SMOKE.
EXPOSURE TO MOISTURE OR HIGH HUMIDITY CAN CAUSE HYDROLYSIS PRODUCING PHOSPHORUS ACID AND PHENOL.
EXCESSIVE OVEREXPOSURE MAY CAUSE THE FOLLOWING EFFECTS:
MAY CAUSE NERVOUS SYSTEM DAMAGE.
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
4. FIRST AID MEASURES
Swallowing
Do not induce vomiting. Obtain medical attention immediately.
Inhalation
Remove to fresh air. Obtain medical attention if symptoms develop.
Skin contact
Immediately wash with soap and water for at least 15 minutes. Immediately remove contaminated clothing and shoes. If redness or irritation occurs, seek medical
attention.
Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes. Remove contact lenses, if worn. Obtain medical attention if irritation develops.
5. FIRE-FIGHTING MEASURES
Flash point: 295 掳F 146 掳C
Flammable limits
Lower limit: Not available
Upper limit: Not available
Autoignition temperature:
No data available.
NFPA CLASSIFICATION
Health: 2 Flammability: 1 Reactivity: 1 Special provisions:
Hazardous combustion products
Carbon dioxide.
Carbon monoxide.
Oxides of phosphorous.
Phosphine.
Special fire fighting procedures
Water spray may be used to cool containers and adjacent surfaces.
Run-off water may be highly acidic and should be collected and neutralized if possible.
Special protective equipment for firefighters
Firefighters must be equipped to prevent breathing of vapors or products of combustion. Wear an approved self-contained breathing apparatus and protective
clothing.
Full protective clothing
Extinguishing media
Suitable: - CO2
- dry chemical
- foam
Unusual fire and explosion hazards
Hazardous combustion products may include intense heat, dense black smoke, carbon monoxide, carbon dioxide, hydrocarbon fragments, phosphine, fragments of
phosphite/phosphate esters and oxides of phosphorus.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Wear protective clothing when taking up spill., Avoid contact with eyes and skin.
Environmental precautions
Avoid drainage to sewers or natural waters., Since phosphites can hydrolyze, notification of governing agencies may be appropriate due to the possible release of
phenolic materials.
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
Methods for cleaning up
Avoid contact with liquid and vapors.
Dike area of spill to prevent spreading and pump liquid to salvage tank.
Absorb residue with inert absorbent, and transfer to proper containers. Remaining material may be emulsified with soap and water and absorbed on additional
sorbent. Do not flush to sewer. Since phosphites can hydrolyze, notification of RCRA may be appropriate due to the possible release of phenolic materials.
Do not flush this product to sewers or waterways.
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Avoid contact with eyes, skin and clothing., Wash thoroughly with soap and water after handling., Do not eat, drink or smoke when handling., Keep containers
tightly closed to prevent contamination., Electrically bond and ground all containers and equipment before transfer or use of material.
Other precautions
Caution - If water contamination has occurred, or if you have any reason to suspect water contamination, do not heat containers of product. Do not heat opened
containers with steam in a manner which will allow steam to condense into the container.
STORAGE
Storage requirements
Keep away from heat, sparks and flame., Store in a dry place away from excessive heat., Exposure to moisture or high humidity can cause hydrolysis producing
phosphorus acid and phenol., Keep container tightly closed., Normal precautions common to safe manufacturing practice should be followed in handling and
storage.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Component Country Type Value Remark
Triphenyl phosphite 0.1 mg/m3 Chemtura Corporation recommended exposure limit.
Phenol USA TWA, ACGIH 5ppm
Australia TWA 4 mg/m3
1 ppm
No other exposure limits have been established
PERSONAL PROTECTION
Respiratory protection
None required in normal use., NIOSH approved full face organic respiratory protection required in the absence of proper environmental control. For emergencies,
a self-contained breathing apparatus and full chemical resistant suit.
Hand protection / protective gloves
Gauntlet type gloves of nitrile rubber or butyl rubber recommended; for short time contact PVC is suitable.
Eye protection
Safety glasses with side shields., Safety goggles.
Skin protection
Chemical resistant protective clothing.
Industrial hygiene measures
Do not eat or drink at work., Remove contaminated clothing and clean it.
ENGINEERING CONTROLS
Ventilation
Use local ventilation or engineering controls as needed to maintain personnel exposure below the exposure limits.
Further information
Provide for sufficient ventilation and/or exhaust.
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Liquid
Physical state
Colorless
Color
Slight phenolic
Odor
No data available.
Odor threshold
OTHER PROPERTIES
> 250 掳C
Boiling point
at 1,013 hPa
22 - 25 掳C
Melting point
72 - 77 掳F
Not available
Solidification
Not available
pH
Not available
Specific gravity (H2O=1)
1.182 g/cm3 at 25 掳C
Density
7 hPa at 205 掳C
Vapor pressure
Insoluble, Hydrolyzes slowly
Solubility in water
Soluble
Solubility in organic solvents
No data available.
Partitioning coefficient
295 掳F
Flash point
146 掳C
>= 220 掳C
Thermal decomposition
No data available.
Autoignition temperature
Not available
Upper explosion limits
Not available
Lower explosion limits
Not available
Percent volatiles
10. STABILITY AND REACTIVITY
Stability: Stable.
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
Stability - Conditions to avoid:
Moisture.
Water.
Incompatible materials:
Water.
Strong oxidizing agents.
Hazardous reactions: Will react in the presence of water. Reaction rate will increase with increasing temperatures and pressures.
Hydrolyzed by moisture to phosphorus acid and alcohol(s).
Hazardous combustion products:
Carbon dioxide.
Carbon monoxide.
Oxides of phosphorous.
Phosphine.
11. TOXICOLOGICAL INFORMATION
SWALLOWING
Test results
Acute toxicity: LD50 Rat
Result: 1,600 mg/kg
INHALATION
Test results
Acute toxicity: LC50 - Rat
Result: > 2 mg/l
SKIN CONTACT
Test results
Skin irritation: Species: rabbit:
Result: Irritant
EYE CONTACT
Test results
Eye irritation: Species: rabbit:
Result: Irritant
SENSITIZATION
Test results: Species: - Guinea pigs
Classification: not sensitizing
Remark: This material was a weak skin sensitizer in human patch tests.
MUTAGENICITY
Assessment: This material was not mutagenic in an Ames bacterial assay.
SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH
In animal testing neurotoxic effects were observed on oral and dermal administration at high doses.
12. ECOLOGICAL INFORMATION
Acute toxicity to aquatic - EC50 - Water flea (Daphnia magna)
invertebrates: Result: 0.94 mg/l
Exposure time: 48 h
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
Additional information
No results from ecotoxicological tests are available.
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with appropriate Federal, State, and local regulations., Incinerate in a furnace where permitted
General:
under appropriate Federal, State, and local regulations.
14. TRANSPORT INFORMATION
DOT Classification
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triphenyl phosphite)
Proper shipping name:
9
Class:
UN3082
UN ID #:
III
Packing group:
MARINE POLLUTANT
marine pollutant:
Not regulated by ground or rail if shipped or transported in containers less than 450 liters.
Triphenyl phosphite
Technical description
IMDG Classification
Environmentally hazardous substance, liquid, n.o.s.
Proper shipping name:
9
Class:
marine pollutant
Subsidiary risk:
UN 3082
UN ID #:
III
Packing group:
(Triphenyl phosphite)
Technical description
ICAO Classification
Environmentally hazardous substance, liquid, n.o.s.
Proper shipping name:
9
Class:
UN 3082
UN ID #:
III
Packing group:
(Triphenyl phosphite)
Technical description
Only regulated by air Into, Out of or Within the United States in containers 881.8 lbs (400 kg) or greater.
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities
(TPQ's) and release reporting based on Reportable Quantities (RQ's) in 40CFR355 (used for SARA 302 and 304).
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phenol 108-95-2 < 1.00
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that
appear in 40CFR372 (for SARA 313). This information must be included in MSDS's that are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phenol 108-95-2 < 1.00
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MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
Massachusetts Right-To-Know Substance List (MSL)--Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified
when present in products.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phenol 108-95-2 <= 1.00
Pennsylvania Right-To-Know Hazardous Substance List--Hazardous Substances and Special Hazardous Substances on the list must be identified when
present in products.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phenol 108-95-2 <= 1.00
New Jersey Worker and Community Right-To-Know Act (Labeling Requirements)
Chemical name CAS# New Jersey TS Number
Triphenyl phosphite 101-02-0
Phenol 108-95-2
California Proposition 65
**** NONE ****
CHEMICAL INVENTORY
Canada: The ingredients of this product are on the DSL.
Europe: The ingredients of this product are on the EINECS inventory.
United States: The ingredients of this product are on the TSCA inventory.
Australia: The ingredients of this product are on the AICS inventory.
China: This product is on the IECSC Inventory.
Japan: The ingredients of this product are on the ENCS inventory.
Korea: The ingredients of this product are on the ECL.
Philippines: This product is on the PICCS.
EPA
16. OTHER INFORMATION
FURTHER INFORMATION
MAY BE ON THE INVENTORY LIST BUT NOT NECESSARILY REGISTERED, (Korea, China, New Zealand) CONSULT REGULATORY SPECIALIST.
HMIS RATING
Health: 2 Flammability: 1 Reactivity: 0 PPI:
STP Standard temperature and pressure
W/W 0 (HMIS)
1 (HMIS) Slight hazard
2 (HMIS) Moderate hazard
Copyright
3 (HMIS) Serious hazard
2006
Chemtura
4 (HMIS) Severe hazard
Corporation
X (HMIS) Personal protection rating to be supplied by user depending on use conditions
(M)SDS# 000000021695 Page: 7 of 8
MATERIAL SAFETY DATA SHEET
Version: 1.5
NAUGALUBE庐 TPP Date of Issue: 12/20/2006
Date printed: 12/30/2006
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN CHEMTURA CORPORATION. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS
CURRENT AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE OF THIS PRODUCT
ARE NOT WITHIN THE CONTROL OF CHEMTURA CORPORATION, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS.
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