DICHLOROMETHANE http://www.jtbaker.com/msds/englishhtml/D2895.htm
MSDS Number: D2895 * * * * * Effective Date: 02/16/06 * * * * * Supercedes: 05/14/03
DICHLOROMETHANE
1. Product Identification
Synonyms: DCM; Methylene chloride (MC); Methylene dichloride; Methylene bichloride; Methane dichloride
CAS No.: 75-09-2
Molecular Weight: 84.93
Chemical Formula: CH2Cl2
Product Codes:
J.T. Baker: V653
Mallinckrodt: 3023, 4877, 4879, 4881, 4883, 4884, 4885, H077, H485
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Methylene Chloride 75-09-2 99 - 100% Yes
3. Hazards Identification
Emergency Overview
--------------------------
WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. AFFECTS
CENTRAL NERVOUS SYSTEM, LIVER, CARDIOVASCULAR SYSTEM, AND BLOOD. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. SUSPECT CANCER HAZARD. MAY
CAUSE CANCER. Risk of cancer depends on level and duration of exposure.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 3 - Severe (Cancer Causing)
Flammability Rating: 1 - Slight
Reactivity Rating: 2 - Moderate
Contact Rating: 3 - Severe
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Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: Blue (Health)
-----------------------------------------------------------------------------------------------------------
Potential Health Effects
----------------------------------
Inhalation:
Causes irritation to respiratory tract. Has a strong narcotic effect with symptoms of mental confusion,
light-headedness, fatigue, nausea, vomiting and headache. Causes formation of carbon monoxide in blood which
affects cardiovascular system and central nervous system. Continued exposure may cause increased
light-headedness, staggering, unconsciousness, and even death. Exposure may make the symptoms of angina
(chest pains) worse.
Ingestion:
May cause irritation of the gastrointestinal tract with vomiting. If vomiting results in aspiration, chemical
pneumonia could follow. Absorption through gastrointestinal tract may produce symptoms of central nervous
system depression ranging from light headedness to unconsciousness.
Skin Contact:
Causes irritation, redness and pain. Prolonged contact can cause burns. Liquid degreases the skin. May be
absorbed through skin.
Eye Contact:
Vapors can cause eye irritation. Contact can produce pain, inflammation and temporal eye damage.
Chronic Exposure:
Can cause headache, mental confusion, depression, liver effects, kidney effects, bronchitis, loss of appetite,
nausea, lack of balance, and visual disturbances. Can cause dermatitis upon prolonged skin contact. Methylene
chloride may cause cancer in humans.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular
function may be more susceptible to the effects of this substance.
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to
an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.
5. Fire Fighting Measures
Fire:
Autoignition temperature: 556C (1033F)
Flammable limits in air % by volume:
lel: 12; uel: 23
Forms flammable vapor-air mixtures above 100C (212F).
Explosion:
Concentrated can be ignited by a high intensity ignition source. Vapor may form flammable mixture in
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atmosphere that contains a high percentage of oxygen. Sealed containers may rupture when heated.
Fire Extinguishing Media:
Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with
full facepiece operated in the pressure demand or other positive pressure mode. Combustion by-products include
phosgene and hydrogen chloride gases. Structural firefighters' clothing provides only limited protection to the
combustion products of this material.
6. Accidental Release Measures
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain
and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate
container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste
container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations
(CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll
free number for the US Coast Guard National Response Center is (800) 424-8802.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from any source of heat or ignition. Outside or detached storage is recommended. Containers of this material
may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and
precautions listed for the product. To minimize decomposition, all storage containers should be galvanized or
lined with a phenolic coating. This material may corrode plastic and rubber. Wear special protective equipment
(Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face,
forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at
the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink,
or smoke in workplace. Odor Threshold: 205 - 307 ppm. The odor threshold only serves as a warning of
exposure; not smelling it does not mean you are not being exposed.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
Methylene Chloride (Dichloromethane):
- OSHA Permissible Exposure Limit (PEL) -
25 ppm (TWA), 125 ppm (STEL), 12.5 ppm (8-hour TWA - Action Level)
- ACGIH Threshold Limit Value (TLV) -
50 ppm (TWA), A3 - suspected human carcinogen.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece
self-contained breathing apparatus. The cartridges recommended for this material have a predicted service of less
than 30 minutes at concentrations of ten times (10x) the exposure limits. Actual service life will vary
considerbly, depending on concentration levels, temperature, humidity, and work rate. This substance has poor
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warning properties.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact. Neoprene is a recommended material for personal protective equipment. Natural rubber and
polyvinyl chloride ARE NOT recommended materials for personal protective equipment. Note: Breakthrough
time for neoprene is less than 5 minutes; change gloves frequently or consult with a reputable glove supplier to
select a glove with longer breakthrough times.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain
and quick-drench facilities in work area.
Other Control Measures:
Do not use closed circuit rebreathing system employing soda lime or other carbon dioxide absorber because of
formation of toxic compounds capable of producing cranial nerve paralysis. See OSHA Standard for medical
surveillance, record keeping, and reporting requirements for methylene chloride (29 CFR 1910.1052).
9. Physical and Chemical Properties
Appearance:
Clear, colorless liquid.
Odor:
Chloroform-like odor.
Solubility:
1.32 gm/100 gm water @ 20C.
Specific Gravity:
1.318 @ 25C
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
39.8C (104F)
Melting Point:
-97C (-143F)
Vapor Density (Air=1):
2.9
Vapor Pressure (mm Hg):
400 @ 24C (75F)
Evaporation Rate (BuAc=1):
27.5
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Emits highly toxic fumes of phosgene when heated to decomposition. Decomposes in a flame or hot surface to
form toxic gas phosgene and corrosive mists of hydrochloric acid. Carbon dioxide and carbon monoxide may
form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers, strong caustics, plastics, rubber, nitric acid, water + heat, and chemically active metals, such as
aluminum and magnesium powder, sodium, potassium, and lithium. Avoid contact with open flames and
electrical arcs. Liquid methylene chloride will attack some forms of plastics, rubber, and coatings.
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Conditions to Avoid:
Moisture, heat, flames, ignition sources and incompatibles.
11. Toxicological Information
Toxicological Data:
Dichloromethane: Oral rat LD50: 1600 mg/kg; inhalation rat LC50: 52 gm/m3; investigated as a tumorigen,
mutagen, reproductive effector.
Reproductive Toxicity:
Dichloromethane has been linked to spontaneous abortions in humans.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Methylene Chloride (75-09-2) No Yes 2B
12. Ecological Information
Environmental Fate:
When released into the soil, this material may leach into groundwater. When released into the soil, this material
is expected to quickly evaporate. When released into water, this material may biodegrade to a moderate extent.
When released to water, this material is expected to quickly evaporate. This material has a log octanol-water
partition coefficient of less than 3.0. This material is not expected to significantly bioaccumulate. When released
into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl
radicals. When released into the air, this material is expected to have a half-life of greater than 30 days. When
released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition.
Environmental Toxicity:
The LC50/96-hour values for fish are over 100 mg/l. This material is not expected to be toxic to aquatic life.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA
approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this
product may change the waste management options. State and local disposal regulations may differ from federal
disposal regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements.
14. Transport Information
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: DICHLOROMETHANE
Hazard Class: 6.1
UN/NA: UN1593
Packing Group: III
Information reported for product/size: 20L
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: DICHLOROMETHANE
Hazard Class: 6.1
UN/NA: UN1593
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Packing Group: III
Information reported for product/size: 20L
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Methylene Chloride (75-09-2) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Methylene Chloride (75-09-2) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Methylene Chloride (75-09-2) No No Yes No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Methylene Chloride (75-09-2) 1000 U080 No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Pure / Liquid)
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
Australian Hazchem Code: 2Z
Poison Schedule: S5
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR)
and the MSDS contains all of the information required by the CPR.
16. Other Information
NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. AFFECTS
CENTRAL NERVOUS SYSTEM, LIVER, CARDIOVASCULAR SYSTEM, AND BLOOD. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. SUSPECT CANCER HAZARD. MAY
CAUSE CANCER. Risk of cancer depends on level and duration of exposure.
Label Precautions:
Do not breathe vapor.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Do not get in eyes, on skin, or on clothing.
Keep away from heat and flame.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to
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an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical
attention.
Product Use:
Industrial chemical.
Revision Information:
No Changes.
Disclaimer:
************************************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person using this product.
Individuals receiving the information must exercise their independent judgment in determining its
appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING
WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR
THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT
BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR
RELIANCE UPON THIS INFORMATION.
************************************************************************************************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)
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