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MSDS Material Safety Data Sheet
CAS

100-46-9

File Name: cityu_edu_hk---msds277.asp
                                                                                               M.S.D.S. 0277

Material Safety Data Sheet

City University of Hong Kong

MSDS BENZYLAMINE 0277
========================================================================
PRODUCT INFORMATION
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Product Name: Benzylamine
Chinese Name: 脫i
Common Synonyms: Aminotoluene; Phenylmethylamine; Benzenemethanamine
Chemical Family: Amines
Formula: C6H5CH2NH2
Formula Wt.: 107.16
CAS No.: 100-46-9
Product Use: Laboratory Reagent

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RISK SYMBOL
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City University of Hong Kong 1
The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
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Boiling Point: 185 deg. C (365 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -46 deg. C (-50 deg. F) Vapor Density (Air=1): 3.7
(@ 760 mmHg)
Specific Gravity: 0.98 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Liquid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless to yellow liquid. Ammonia odor.

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FIRE AND EXPLOSION DATA
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Flash Point (Closed Cup): 66 deg. C (151 deg. F)
Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear self-contained breathing apparatus with full facepiece operated in positive
pressure mode.

Unusual Fire & Explosion Hazards: None identified.
Toxic Gases Produced: Oxides of nitrogen, ammonia, carbon monoxide, carbon dioxide

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REACTIVITY DATA
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Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Strong acids, strong oxidizing agents
Decomposition Products: Oxides of nitrogen, ammonia, carbon monoxide, carbon dioxide




The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
M.S.D.S. 0277
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.
Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation:
Irritation of mucous membranes, headache, nausea, vomiting, dizziness, drowsiness, irritation of
upper respiratory tract, unconsciousness

Skin Contact: Irritation, burns
Eye Contact: Irritation, burns, permanent eye damage
Skin Absorption: None identified
Ingestion: Nausea, vomiting, gastrointestinal irritation, burns to mouth and throat
Chronic Effects: None identified

Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation, eye contact, skin contact

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FIRST AID MEASURES
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Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Prompt action is essential.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.




City University of Hong Kong 3
The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a
chemical cartridge respirator with ammonia/amine cartridge is recommended. If concentration exceeds
capacity of cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection:
Safety goggles and face shield, uniform,protective suit, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in corrosion-proof area. Store in a cool, well-ventilated area away
from sources of heat, flame, or ignition. isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:
Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.




The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.

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