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MSDS Material Safety Data Sheet
CAS

16874-33-2

File Name: pschem_com---tetrahydrofuroicAcidPENN.asp
Material Safety Data Sheet                                                   Tetrahydrofuroic Acid
Quick Identifier
QO脪 Tetrahydrofuroic Acid
May be used to comply with OSHA鈥檚 Hazard Communication Standard, Common Name (used on label and list):
29CFR 1910.1200. Standard must be consulted for specific requirements



Section I
Manufacturer鈥檚 Name and Address Emergency Telephone Number
Penn Specialty Chemicals, Inc. 901-320-4092
3324 Chelsea Avenue Hazard Information Services: 800-228-5635
(For Emergency Medical Information)
Memphis, TN 38108
For Product Information and Other Calls:
Penn Specialty Chemicals, Inc.: 877-895-7366

Effective: July 15, 2003
Supersedes: November 2, 1999

Section II - Hazardous Ingredients/Identity Information
OSHA PEL ACGIH TLV CAS NO. %
Hazardous Component(s) Chemical & Common Name(s)
2-Tetrahydrofuroic acid Not established Not established 16874-33-2


Note: This material is not listed in the EPA鈥檚 Toxic Substances Control Act inventory. It should be used for experimental purposes
by qualified personnel only.
Section III - Physical/Chemical Characteristics
Boiling Point Vapor Density (Air=1) Specific Gravity (H20 = 1) Vapor Pressure (mm Hg)
470掳F, 243掳C 4.0 1.214 10 @ 255掳F, 124掳C
@ 736 mmHg

Solubility in Water Reactivity in Water
Complete Solution becomes acidic

Appearance and Color Melting Point/Freezing Point
Colorless mobile liquid 70掳F, 21掳C
Distinctive odor

Section IV - Fire and Explosion Hazard Data
Flash Point Method Used Flammable Limits in Air, % Volume LEL Lower UEL Upper
>283掳F, >139掳C Setaflash Not available Not available

Auto-Ignition temperature Extinguisher Media
Not Available Water spray, dry chemical, carbon dioxide, foam

Special Fire Fighting Procedures
Firefighters should have eye protection and wear self-contained breathing apparatus.

Unusual Fire and Explosion Hazards
See section V below.
Tetrahydrofuroic Acid
Page 2 of 3
July 15, 2003
Section V - Physical Hazards/Reactivity Data
Stability Conditions to Avoid
Unstable Normally stable
Stable X

Incompatibility (Materials to Avoid)
Bases. Oxidizers.

Hazardous Decomposition Products
Combustion produces carbon dioxide and carbon monoxide

Hazardous Polymerization Conditions to Avoid
May Occur
Will Not Occur X

Section VI - Health Hazards
Chemical Listed as Carcinogen or Potential Carcinogen

National Toxicology IARC Monographs OSHA Regulated
Yes Yes Yes
No X No X No X


Signs and Symptoms
Exposure
Detectable odor

Acute Overexposure
Irritation of skin, eyes and respiratory tract.

Chronic Overexposure
No data available.

Emergency and First Aid Procedures for Overexposure - Obtain prompt medical attention.
Inhalation
Move to fresh air. Get medical attention.

Eyes
Immediately flush with water for 15 minutes while lifting eyelids and rolling eyes.
Get immediate medical attention.

Skin
Wash promptly with soap and water.

Ingestion
Get medical help. Do Not induce vomiting. If conscious and medical help not readily available, give water.
Tetrahydrofuroic Acid
Page 3 of 3
July 15, 2003
Section VII - Special Precautions and Spill/Leak Procedures
Precautions to be taken in Handling and Storage
Store in a cool, dry, well ventilated location. Outside or detached storage is preferred. Separate from oxidizers
and bases.

Other Precautions
Avoid skin contact. Keep containers tightly closed. No smoking or eating in handling area.

Steps to be taken in case Material is Released or Spilled
Pick up spill on sand, earth or other non-combustible, absorbent material and place in acid-resistant, covered
container for disposal. Flush area with water to remove last traces.

Waste Disposal Methods (Consult Federal, State and Local Regulations)
Dispose of in accord with regulations.

Section VIII - Special Protection and Control Measures
Respiratory Protection (Specify Type)
NIOSH approved organic vapor air purifying respirator.
Ventilation and local exhaust required.

Eye Protection Protective Gloves Other Protective Clothing or Equipment
Chemical goggles and face shield Impervious chemical gloves Eye fountain and safety shower

Work Hygiene Practices
Avoid direct contact with 2-Tetrahydrofuroic acid. Wash thoroughly after handling.

Transport Information
DOT: Corrosive liquid, Acidic, Organic, N.O.S. (2-Tetrahydrofuroic Acid), 8, UN3265, III
Label: Corrosive

11/99 鈥? Changed Company Name
Revision:
07-03 - Update

The data contained herein is based on information currently available to Penn Specialty Chemicals, Inc., and believed to be factual and the opinions expressed to be
those of qualified experts; however, this data is not be taken as a warranty or representation for which Penn Specialty Chemicals, Inc. assumes legal responsibility.

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