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MSDS Material Safety Data Sheet
CAS

12069-69-1
5989-27-5
141-43-5
1300-72-7
61790-12-3
102-71-6

File Name: appliedbiochemists_com---Clearigate.asp
                   MATERIAL SAFETY DATA                                                  SHEET
AB Clearigate
1. Product And Company Identification
Supplier Manufacturer
Applied Biochemists (WI) Advantis Technologies, Inc.
A division of Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway
W175 N11163 Stonewood Drive, Suite 234 Alpharetta, GA 30004 United States
Germantown, WI 53022
Telephone Number: (262) 255-4449 Telephone Number: (770) 521-5999
FAX Number: (262) 255-4268 FAX Number: (770) 521-5959
Web Site: www.appliedbiochemists.com Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300 CHEMTREC - DAY OR NIGHT: (800) 424-9300


Issue Date: 01/29/2007
Product Name: AB Clearigate
CAS Number: Not Established
Chemical Family: Copper Algaecide, Herbicide
Chemical Formula: Proprietary
MSDS Number: 372

2. Composition/Information On Ingredients

Ingredient CAS Percent Of
Name Number Total Weight
COPPERCARBONATE 12069-69-1
D-LIMONENE 5989-27-5
MONOETHANOLAMINE 141-43-5

SODIUM XYLENE SULFONATE 1300-72-7
TALL OIL FATTY ACID 61790-12-3
TRIETHANOLAMINE 102-71-6

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).

Hazards Identification (Pictograms)




3. Hazards Identification
Eye Hazards
Corrosive to eyes.
Skin Hazards
Corrosive to skin.
Ingestion Hazards
Not expected to be a primary route of exposure.




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MATERIAL SAFETY DATA SHEET
AB Clearigate

3. Hazards Identification - Continued

Inhalation Hazards
Vapors or mists may cause irritation with pain, coughing and discomfort to nose, throat, and chest.
Chronic/Carcinogenicity Effects
None known.
Conditions Aggravated By Exposure
May aggravate existing dermatitis and kidney disease.

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately.
Skin
Rinse the affected area with tepid water for at least 15 minutes. Wash clothing before reuse.
Ingestion
Call a physician or a poison control center immediately. DO NOT INDUCE VOMITING, unless directed to by
medical personnel. Give two glasses of water. Never give anything by mouth to an unconscious victim.
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen.

Fire Fighting (Pictograms)




5. Fire Fighting Measures
Flash Point: 115 掳F 46.1 掳C
Flash Point Method: Tag closed cup
Fire And Explosion Hazards
None known.
Extinguishing Media
Water fog, carbon dioxide, or polymer foam for large fires.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.

6. Accidental Release Measures
Use appropriate personal protective equipment (PPE). Contain spill. Soak up with ground corn cob. Avoid rinsing into
sewer. Place in a suitable container for disposal.

Handling & Storage (Pictograms)




7. Handling And Storage
No Data Available...




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MATERIAL SAFETY DATA SHEET
AB Clearigate

7. Handling And Storage - Continued

Handling And Storage Precautions
Store at temperatures between 55F and 100F.
Handling Precautions
Do not contaminate water, food, or feed by storage, disposal, or cleaning of equipment. Keep out of reach of
children.
Storage Precautions
Store at temperatures between 55F and 100F. Do not store in direct sunlight. NFPA Class II combustible liquid.
Store in a cool, dry place.

Protective Clothing (Pictograms)




8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required.
Eye/Face Protection
Face shield or splash goggles.
Skin Protection
Rubber gloves.
Respiratory Protection
None normally required. In case of inadequate ventilation, use NIOSH-approved respirator for organic vapors and
mists.
Other/General Protection
Use safe chemical handling procedures suitable for the hazards presented by this material.
Ingredient(s) - Exposure Limits
COPPER CARBONATE
PEL = 1 mg/m3*
TLV = 1 mg/m3*
*as copper dusts and mists (CAS# 7440-50-8)
MONOETHANOLAMINE
PEL = 3ppm
TLV = 3 ppm

9. Physical And Chemical Properties
Appearance
Blue, viscous liquid.
Odor
orange, citrus
Chemical Type: Mixture
Physical State: Liquid
Melting Point: NA 掳F
Specific Gravity: 1.04-1.05
Vapor Density: >1
pH Factor: 9.7-10.0


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MATERIAL SAFETY DATA SHEET
AB Clearigate

9. Physical And Chemical Properties - Continued

Odor - Continued
Solubility: Miscible in water
Evaporation Rate: ND

10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
Avoid contact with strong acids and nitrates.
Incompatible Materials
Strong acids and nitrates.
Hazardous Decomposition Products
Oxides of nitrogen.

11. Toxicological Information
Acute Studies
LD50 Rat = 1.75 g/kg (oral)
LD50 Rat = 650 mg/kg (dermal)

12. Ecological Information
Ecotoxicological Information
Not available.

13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.



14. Transport Information
Proper Shipping Name
Pesticides, Liquid, Toxic, Flammable, N.O.S. (Copper Triethanolamine Comoplex)
Hazard Class
6.1, PGIII (<=5L Consumer Commodity ORM-D)
DOT Identification Number
UN2903
Additional Shipping Paper Description
Subsidary CORROSIVE label required per 49CFR 172.402(a)(2). NFPA Class II COMBUSTIBLE LIQUID

15. Regulatory Information
No Data Available...




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MATERIAL SAFETY DATA SHEET
AB Clearigate

NFPA HMIS
HEALTH 2
2
FLAMMABILITY 2
2 1
REACTIVITY 1
B
PERSONAL PROTECTION


16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW

Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
Applied Biochemists (WI)
Printed Using MSDS Generator鈩? 2000




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