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MSDS Material Safety Data Sheet
CAS

12069-69-1
14808-60-7
141-43-5

File Name: appliedbiochemists_com---Cutrinegran.asp
                     MATERIAL SAFETY DATA                                                SHEET
AB Cutrine Plus Granular
1. Product And Company Identification
Supplier Manufacturer
Applied Biochemists (WI) Advantis Technologies, Inc.
A division of Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway
W175 N11163 Stonewood Drive, Suite 234 Alpharetta, GA 30004 United States
Germantown, WI 53022
Telephone Number: (262) 255-4449 Telephone Number: (770) 521-5999
FAX Number: (262) 255-4268 FAX Number: (770) 521-5959
Web Site: www.appliedbiochemists.com Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300 CHEMTREC - DAY OR NIGHT: (800) 424-9300


Issue Date: 02/15/2007
Product Name: AB Cutrine Plus Granular
Chemical Name: Chelated Elemental Copper
CAS Number: Not Established
Chemical Family: Granular Copper Algaecide
Chemical Formula: Proprietary Mixture
MSDS Number: 377

2. Composition/Information On Ingredients

Ingredient CAS Percent Of
Name Number Total Weight

COPPERCARBONATE 12069-69-1
CRYSTALLINE SILICA 14808-60-7
MONOETHANOLAMINE 141-43-5

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).

3. Hazards Identification
Primary Routes(s) Of Entry
Eye Contact, Skin Contact
Eye Hazards
Can cause eye irritation.
Skin Hazards
May be irritating to skin.
Ingestion Hazards
May be harmful if swallowed.
Inhalation Hazards
Inhaled dust may be irritating to mucous membranes.
Chronic/Carcinogenicity Effects
This product contains clay. IARC has classified crystalline silica (a component of clay) as a probable human
carcinogen. Prolonged contact may cause liver damage, kidney damage, and/or chronic muscle damage.




Page 1 of 5
MATERIAL SAFETY DATA SHEET
AB Cutrine Plus Granular

3. Hazards Identification - Continued

Signs And Symptoms
Contact with skin and eyes may be irritating.
Conditions Aggravated By Exposure
May cause skin sensitization.

First Aid (Pictograms)




4. First Aid Measures
Eye
Call a physician or a poison control center immediately. In case of contact, hold eyelids apart and immediately flush
eyes with plenty of water for at least 15 minutes. DO NOT let the victim rub his eye(s).
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing
and shoes. Thoroughly clean shoes before reuse. Wash clothing before reuse.
Ingestion
Get medical attention immediately.
Inhalation
Get medical attention immediately. If breathing is difficult, give oxygen. If inhaled, remove to fresh air.

5. Fire Fighting Measures
Flammability Class: Not flammable
Fire And Explosion Hazards
Decomposition of wet chemical may cause auto-ignition above 150F.
Extinguishing Media
Use CO2 (Carbon Dioxide), dry chemical, water fog, or foam.
Fire Fighting Instructions
Avoid breathing vapors, gases and fumes. Firefighters should wear self-contained breathing apparatus and full
protective gear. Water can be used to cool and protect exposed material.

6. Accidental Release Measures
Clean up spill immediately. Sweep up and remove immediately. Avoid rinsing into sewer. Use appropriate containers to
avoid environmental contamination.

Handling & Storage (Pictograms)




7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Use only with adequate ventilation. Wash thoroughly after handling.
Handling Precautions
Avoid contact with eyes. Avoid contact with skin and clothing. Avoid contact with strong acids and nitrates


Page 2 of 5
MATERIAL SAFETY DATA SHEET
AB Cutrine Plus Granular

7. Handling And Storage - Continued

Storage Precautions
Keep out of reach of children. Store in a cool, dry place. Do not stack wet material.
Work/Hygienic Practices
Wash thoroughly with soap and water after handling. Use safe chemical handling procedures suitable for the
hazards presented by this material.

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust recommended.
Eye/Face Protection
Safety glasses with side shields or goggles.
Skin Protection
Chemical-resistant gloves (rubber or plastic).
Respiratory Protection
None normally required. If needed, use NIOSH approved respirator for dusts.
Ingredient(s) - Exposure Limits
COPPER CARBONATE
PEL = 1 mg/m3 (as copper dusts and mists - CAS# 7440-50-8)
TLV = 1 mg/m3 (as copper dusts and mists - CAS# 7440-50-8)
CRYSTALLINE SILICA
PEL = 0.1 mg/m3
TLV = 0.05 mg/m3
MONOETHANOLAMINE
PEL = 3ppm
TLV = 3 ppm

9. Physical And Chemical Properties
Appearance
Blue/Green granules
Odor
Amine, slight
Chemical Type: Mixture
Physical State: Solid
Melting Point: N/A 掳F
Boiling Point: Not Determined 掳F
Percent Volitales: Not Determined
Packing Density: 1.2-1.3
Vapor Pressure: Not Determined
Solubility: Granules are insoluble; Chemical soluble
Evaporation Rate: Not Determined

10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
Temperatures above 150F, especially if the material is damp.




Page 3 of 5
MATERIAL SAFETY DATA SHEET
AB Cutrine Plus Granular

10. Stability And Reactivity - Continued

Incompatible Materials
Strong acids and nitrates.
Hazardous Decomposition Products
Oxides of Nitrogen and Carbon.

11. Toxicological Information
Acute Inhalation Effects
Acute Inhalation LC50 > 2.59 mg/L (Male and female rats)

12. Ecological Information
Ecotoxicological Information



13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.

14. Transport Information
Proper Shipping Name
Not regulated
Hazard Class
Not regulated
DOT Identification Number
NONE

15. Regulatory Information
No Data Available...

NFPA HMIS
HEALTH 1
1
FLAMMABILITY 0
1 0
REACTIVITY 0
B
PERSONAL PROTECTION


16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 11/15/2006

Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).




Page 4 of 5
MATERIAL SAFETY DATA SHEET
AB Cutrine Plus Granular

Disclaimer - Continued

Applied Biochemists (WI)
Printed Using MSDS Generator鈩? 2000




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