CITGO Tufflo庐 Process Oil 500
Material Safety Data Sheet
CITGO Petroleum Corporation
MSDS No. 669126001
P.O. Box 3758
Hazard Rankings
Tulsa, OK 74102-3758
Revision Date 01/08/2002
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to Health Hazard 0 0
employees, customers and users of this product.
Fire Hazard 1 1
Emergency Overview Reactivity 0 0
Physical State Liquid.
* = Chronic Health Hazard
Color Odor
Light amber to amber Mild petroleum odor
Protect eyes from misting or spraying material. Protective Equipment
Protect exposed skin from repeated or prolonged exposure.
Do not store material in open or unmarked containers. Minimum Requirements
See Section 8 for Details
Spills may create a slipping hazard.
SECTION 1: IDENTIFICATION
Trade Name Technical Contact
CITGO Tufflo庐 Process Oil 500 (918) 495-5933
Product Number (918) 495-4700
669126001 Medical Emergency
CAS Number CHEMTREC Emergency
Mixture. (800) 424-9300
(United States Only)
Product Family Process Oil
Synonyms Process Oil;
CITGO SAP Product Code No.: 669126001
SECTION 2: COMPOSITION
Concentration (%)
Component Name(s) CAS Registry No.
1) Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 70 - 100
2) Distillates, petroleum, hydrotreated light naphthenic 64742-53-6 0 - 30
SECTION 3: HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Major Route(s) of Entry Skin contact.
Signs and Symptoms of Acute Exposure
Inhalation No significant adverse health effects are expected to occur upon short-term exposure.
Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays or mists.
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CITGO Tufflo庐 Process Oil 500
Skin Contact This material can cause mild skin irritation from prolonged or repeated skin contact. Injection under the
skin can cause inflammation, swelling and mild central nervous system depression. Injection of
pressurized hydrocarbons can cause severe, permanent tissue damage. Initial symptoms may be minor.
Injection of petroleum hydrocarbons requires immediate medical attention.
Ingestion If swallowed, large volumes of material can cause generalized depression, headache, drowsiness, nausea,
vomiting and diarrhea. Smaller doses can cause a laxative effect.
Chronic Health Effects Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and
Summary inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation
of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can
cause respiratory irritation or other pulmonary effects.
Conditions Aggravated Medical conditions aggravated by exposure to this material may include pre-existing skin disorders.
by Exposure
Target Organs This material may cause damage to the following organs: skin.
Carcinogenic Potential This product does not contain any components at concentrations above 0.1% which are considered
carcinogenic by OSHA, IARC or NTP.
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the
hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200).
OSHA Health Hazard Classification OSHA Physical Hazard Classification
Explosive Pyrophoric
Irritant Toxic Combustible
Oxidizer Water-reactive
Sensitizer Highly Toxic Flammable
Carcinogenic Organic Peroxide Unstable
Corrosive Compressed Gas
SECTION 4: FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific
information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Inhalation Vaporization is not expected at ambient temperatures. This material is not expected to cause
inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the
person to fresh air.
Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while
occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain
persists.
Skin Contact Remove contaminated shoes and clothing. Wipe off excess material. Wash exposed skin with mild
soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists.
Thoroughly clean contaminated clothing before reuse. Discard contaminated leather goods. If material
is injected under the skin, seek medical attention immediately.
Ingestion Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed
to by a physician. Never give anything by mouth to a person who is not fully conscious. If significant
amounts are swallowed or irritation or discomfort occurs, seek medical attention immediately.
Notes to Physician The viscosity range of the product(s) represented by this MSDS is greater than 400 SUS at 100掳F.
Accordingly, upon ingestion there is a low risk of aspiration. Careful gastric lavage or emesis may be
considered to evacuate large quantities of material. Subcutaneous or intramuscular injection requires
prompt surgical debridement.
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CITGO Tufflo庐 Process Oil 500
SECTION 5: FIRE FIGHTING MEASURES
NFPA Flammability NFPA Class-IIIB combustible material. Slightly combustible!
Classification
Flash Point Method OPEN CUP: >179掳C (>354掳F) (Cleveland.).
Lower Flammable Limit Upper Flammable Limit
No data. No data.
Autoignition Temperature Not available.
Hazardous Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur
Combustion Products and/or nitrogen.
Special Properties This material can burn but will not readily ignite. This material will release vapors when heated above
the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces,
heated vapor can ignite with explosive force. Mists or sprays may burn at temperatures below the flash
point.
Use dry chemical, foam, Carbon Dioxide or water fog.
Extinguishing Media
Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
breathing apparatus to protect against potential hazardous combustion or decomposition products and
oxygen deficiencies.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific
information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal
Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective equipment.
Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small
spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place
into waste containers for later disposal. Contain large spills to maximize product recovery or disposal.
Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural
environments, seek cleanup advice from specialists to minimize physical habitat damage. This material
will float on water. Absorbent pads and similar materials can be used. Comply with all laws and
regulations.
SECTION 7: HANDLING AND STORAGE
Handling Avoid water contamination and extreme temperatures to minimize product degradation. Empty
containers may contain product residues that can ignite with explosive force. Do not pressurize, cut,
weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition
sources. Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing of empty containers and/or waste residues of this product.
Storage Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above
120掳 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local
authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or
waste residues of this product.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists
and/or vapors below the recommended exposure limits (see below). An eye wash station and safety
shower should be located near the work-station.
Personal Protective
Equipment
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CITGO Tufflo庐 Process Oil 500
Personal protective equipment should be selected based upon the conditions under which this material
is used. A hazard assessment of the work area for PPE requirements should be conducted by a
qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum
requirements for personal protective equipment. For certain operations, additional PPE may be
required.
Safety glasses equipped with side shields should be adequate protection under most conditions of use.
Eye Protection
Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if
material is heated above 125掳F (51掳C). Have suitable eye wash water available.
Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if
Hand Protection
frequent or prolonged contact is expected. Use heat-protective gloves when handling product at
elevated temperatures.
Use clean and impervious protective clothing (e.g., neoprene or Tyvek庐) if splashing or spraying
Body Protection
conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat.
If significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly
shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective
clothing when handling material at elevated temperatures.
Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is
Respiratory Protection
not anticipated under normal use conditions and with adequate ventilation. If elevated airborne
concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic
vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending
upon the type of respirator used. Respirators should be used in accordance with OSHA requirements
(29 CFR 1910.134).
General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild
soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use
gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure
standards/control limits have not been established for this product, the "Oil Mist, Mineral" exposure
limits shown below are suggested as minimum control guidelines.
Occupational Exposure Guidelines
Substance Applicable Workplace Exposure Levels
ACGIH (United States).
1) Oil Mist, Mineral
TWA: 5 mg/m3
STEL: 10 mg/m3
OSHA (United States).
TWA: 5 mg/m3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Color Light amber to Odor Mild petroleum odor
Physical State Liquid.
amber
Vapor >1 (Air = 1)
0.92 (Water = 1)
Specific Gravity pH Not Applicable.
Density
Melting/Freezing Not available.
Not available.
Boiling Point/Range
Point
Vapor Pressure Viscosity (cSt @ 40掳C) 110
<0.001 kPa (<0.01 mmHg) (at 20掳C)
Solubility in Water Volatile
Not available. Negligible volatility
Characteristics
Additional Properties Gravity, 潞API (ASTM D287) = 21.5 @ 60潞 F
Density = 7.71 Lbs/gal.
Viscosity (ASTM D2161) = 500 - 530 SUS @ 100潞 F
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CITGO Tufflo庐 Process Oil 500
SECTION 10: STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Chemical Stability Stable.
Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions.
Materials Incompatibility Strong oxidizers.
Hazardous No additional hazardous decomposition products were identified other than the combustion products
Decomposition Products identified in Section 5 of this MSDS.
SECTION 11: TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this
MSDS.
Toxicity Data Distillates, petroleum, hydrotreated light naphthenic:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].
Distillates, petroleum, hydrotreated heavy naphthenic:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].
Distillates, petroleum, hydrotreated light naphthenic:
INHALATION (LC50) Acute: 9.6 mg/L (Female Rat).
INHALATION (LC50) Acute: 10.5 mg/L (Male Rat).
ORAL (LD50) Acute: > 5,000 mg/kg (Rat screen level).
DERMAL (LD50) Acute: > 2,000 mg/kg (Rabbit screen level).
DRAIZE EYE Acute: Non-irritating (Rabbit).
DRAIZE DERMAL Acute: Mild skin irritant (Rabbit).
BUEHLER DERMAL Acute: Non-sensitizing (Guinea Pig).
28-Day DERMAL Sub-Chronic: Mild to moderate skin irritant (Rabbit & Rat).
A life-time dermal application of severely hydrotreated light naphthenic oils produced skin masses on
mice which correlated with the skin irritation response levels of the test animals. Additional studies
attribute these masses to a weak promotional activity. These studies indicate that light naphthenic oils
are not mutagenic, tumor initiators nor complete chemical carcinogens. These materials have not been
determined to be carcinogenic by IARC, NTP or OSHA.
Distillates, petroleum, hydrotreated heavy naphthenic:
Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities
in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil
mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid
granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to
lower concentrations of mineral oil mists at or near current work place exposure levels produced no
significant toxicological effects.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity Analysis for ecological effects has not been conducted on this product. However, if spilled, this product
and any contaminated soil or water may be harmful to human, animal, and aquatic life. Also, the
coating action associated with petroleum and petroleum products can be harmful or fatal to aquatic life
and waterfowl.
Environmental Fate An environmental fate analysis has not been conducted on this specific product. Plants and animals
may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based
(mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can
cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen
transport into the water. With time, if not removed, oxygen depletion in the waterway might be enough
to cause a fish kill or create an anaerobic environment.
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CITGO Tufflo庐 Process Oil 500
SECTION 13: DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility
of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and
residues at the time of disposition.
Conditions of use may cause this material to become a "hazardous waste", as defined by federal or
state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous
waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must
be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State
and/or local regulations may be more restrictive. Contact the RCRA/Superfund Hotline at (800)
424-9346 or your regional US EPA office for guidance concerning case specfic disposal issues.
SECTION 14: TRANSPORT INFORMATION
DOT Status Not a U.S. Department of Transportation regulated material.
Proper Shipping Name Not regulated.
Hazard Class Not regulated. Packing Group(s) Not applicable.
UN/NA ID Not regulated.
Reportable Quantity A Reportable Quantity (RQ) has not been established for this material.
Emergency Response Guide Not applicable.
Placards No.
HAZMAT STCC No. Not assigned.
MARPOL III Status Not a DOT "Marine Pollutant"
per 49 CFR 171.8.
SECTION 15: REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory.
SARA 302/304 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject
to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold
Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances"
listed in 40 CFR 302.4 and 40 CFR 355. No components were identified.
SARA 311/312 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject
to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40
CFR 370.2. This material would be classified under the following hazard categories:
No SARA 311/312 hazard categories identified.
SARA 313 This product contains the following components in concentrations above de minimis levels that are
listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No
components were identified.
CERCLA The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
requires notification of the National Response Center concerning release of quantities of "hazardous
substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined
by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any
fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. This product or refinery
stream is not known to contain chemical substances subject to this statute. However, it is
recommended that you contact state and local authorities to determine if there are any other reporting
requirements in the event of a spill.
CWA This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil
Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United
States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the
EPA's National Response Center at (800) 424-8802.
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CITGO Tufflo庐 Process Oil 500
California This product is not known to contain the any components for which the State of California has found to
Proposition 65 cause cancer, birth defects or other reproductive harm.
New Jersey Petroleum Oil
Right-to-Know Label
Additional Regulatory No additional regulatory remarks.
Remarks
SECTION 16: OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
Version Number 2.0
Revision Date 01/08/2002
Print Date Printed on 01/08/2002.
ABBREVIATIONS
AP = Approximately EQ = Equal > = Greater Than < = Less Than NA = Not Applicable ND = No Data NE = Not
Established
ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association
IARC = International Agency for Research on Cancer NTP = National Toxicology Program
NIOSH = National Institute of Occupational Safety and Health OSHA = Occupational Safety and Health Administration
NPCA = National Paint and Coating Manufacturers Association HMIS = Hazardous Materials Information System
NFPA = National Fire Protection Association EPA = Environmental Protection Agency
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME
INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE
SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS
A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR
OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR
PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL
AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND
EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH
HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
***** END OF MSDS *****
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