MATERIAL SAFETY DATA SHEET (MSDS)
MATERIAL SAFETY DATA SHEET
EM SCIENCE
|1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer.............: Preparation Date.: 3/10/95
EM SCIENCE
A Division of EM Industries Information Phone Number.: 856-423-6300
P.O. Box 70 Hours: Mon. to Fri. 8:30-5
480 Democrat Road Chemtrec Emergency Number: 800-424-9300
Gibbstown, N.J. 08027 Hours: 24 hrs a day
Catalog Number(s):
BX1777 BX1780 BX1780S
Product Name:
Butyl Alcohol
Synonyms:
n-1-Butanol
Chemical Family:
Aliphatic Alcohol
Formula:
CH3CH2CH2CH2OH
Molecular Weight.:
74.12
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component CAS # Appr %
____________________________________________________________
Butyl Alcohol
71-36-3 100%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
FLAMMABLE LIQUID AND VAPOR.
CAUSES IRRITATION OF EYES, NOSE AND THROAT.
HARMFUL IF INHALED OR SWALLOWED.
Appearance:
Clear, colorless liquid with characteristic alcohol odor
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure:
Harmful if inhaled or swallowed; causes headache, nausea, gastrointestinal disturbances. Vapor irritating to eyes and
respiratory passages. Large concentrations or continued overexposure may cause hearing loss, kidney or liver injury. Irritating
on contact with eyes or skin.
Medical Cond. Aggravated by Exposure:
Kidney and liver conditions
Routes of Entry:
Inhalation, ingestion
Carcinogenicity:
The material is not listed (IARC, NTP, OSHA) as cancer causing
agent.
4. FIRST AID MEASURES
Emergency First Aid:
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
Skin: Wash thoroughly with soap and water.
Eyes: Immediately flush thoroughly with water for at least 15
minutes.
Inhalation: Remove to fresh air; give artificial respiration if
breathing has stopped.
Ingestion: If conscious, drink water and induce vomiting
immediately as directed by medical personnel. Never give anything
by mouth to an unconscious person.
Remove contaminated clothing and wash before reuse.
5. FIRE FIGHTING MEASURES
Flash Point (F): 95F (tcc)
Flammable Limits LEL (%): 1.40
Flammable Limits UEL (%): 11.20
Extinguishing Media:
Use "alcohol" foam, carbon dioxide, dry chemical.
Water spray to cool fire-exposed containers.
Fire Fighting Procedures:
Wear self-contained breathing apparatus and protective clothing.
Fire & Explosion Hazards:
Vapor can travel distances to ignition source and flash back.
6. ACCIDENTAL RELEASE MEASURES
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective equipment listed under Exposure / Personal
Protection. Eliminate any ignition sources until the area is determined to be free from explosion or fire hazards. Contain the
release and eliminate its source, if this can be done without risk. Take up and containerize for proper disposal as described
under Disposal. Comply with Federal, State, and local regulations on reporting releases. Refer to Regulatory Information for
reportable quantity and other regulatory data.
EM SCIENCE recommends Spill-X absorbent agents for various types of spills. Additional information on the Spill-X
products can be provided through the EM SCIENCE Technical Service Department (609) 423-6300. The following EM
SCIENCE Spill-X absorbent is recommended for this product:
SX0863 Solvent Spill Treatment Kit
7. HANDLING AND STORAGE
Handling & Storage:
Keep container tightly closed. Store in a cool area away from ignition sources and oxidizers. Do not breathe vapor. Do not
get in eyes, on skin, or on clothing. Electrically ground all equipment when handling this product.
|8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection:
Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), a
NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations
also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your safety equipment
supplier). Engineering and/or administrative controls should be implemented to reduce exposure. Material must be handled or
transferred in an approved fume hood or with equivalent ventilation. Protective gloves (Butyl rubber, Neoprene, PVC or
equivalent) should be worn to prevent skin contact. Safety glasses with side shields must be worn at all times.
Work/Hygenic Practices:
Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available.
EXPOSURE GUIDELINES
OSHA - PEL:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Butyl Alcohol
50 150 X
ACGIH - TLV:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Butyl Alcohol
50 152 50 152 X
If there are no exposure limit numbers listed in the Exposure Guidelines chart, this indicates that no OSHA or ACGIH
exposure limts have been established.
9. PHYSICAL AND CHEMCIAL PROPERTIES
Boiling Point (C 760 mmHg) : 117.7C
Melting Point (C) : -89C
Specific Gravity (H2 0 = 1) : 0.810
Vapor Pressure (mm Hg) : 4 20C
Percent Volatile by vol (%): 99+%
Vapor Density (Air = 1) : 2.55
Evaporation Rate (BuAc = 1): 0.46
Solubility in Water (%) : 7.7%
Appearance :
Clear, colorless liquid with characteristic alcohol odor
10. STABILITY AND REACTIVITY
Stability: Yes
Hazardous Polymerization:
Does not occur
Hazardous Decomposition:
COx
Conditions to Avoid:
Heat, contact with ignition source
Materials To Avoid:
() Water
(X) Acids
() Bases
() Corrosives
(X) Oxidizers
(X) Other: Halogens, Aluminum, Alkali metals
11. TOXICOLOGICAL INFORMATION
Toxicity Data
orl-rat LD50: 790 mg/kg ihl-hmn TCLo: 25 ppm
ihl-rat LC50: 8000 ppm/4H
Toxicological Findings:
Test on laboratory animals indicate material may produce adverse
mutagenic and reproductive effects.
Cited in Registry of Toxic Effects of Chemical Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
EPA Waste Numbers: U031 D001
Treatment:
Incineration, fuels blending or recycle. Contact your local permitted waste disposal site (TSD) for permissible treatment sites.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL
CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
13. TRANSPORT INFORMATION
DOT Proper Shipping Name:
Butanol
DOT ID Number :
UN1120
14. REGULATORY INFORMATION
TSCA Statement:
The CAS number of this product is listed on the TSCA Inventory.
SARA SARA CERCLA
Component EHS EHS TPQ RQ
(302) (lbs) (lbs)
____________________________________________________________
Butyl Alcohol
5000
OSHA SARA
DeMinimis
Component Floor List 313
for SARA 313
(%)
____________________________________________________________
Butyl Alcohol
Y Y 1.0
If there is no information listed on the regulatory information chart, this indicates that the chemical is not covered by the
specific regulation listed.
15. OTHER INFORMATION
Comments:
None
NFPA Hazard Ratings:
Health :1
Flammability :3
Reactivity :0
Special Hazards :
Revision History: 9/1/81 8/1/83 1/24/87 10/27/87
6/22/88 6/29/89 3/1/91 4/2/93
| = Revised Section
N/A = Not Available
N/E = None Establised
The statements contained herein are offered for informational purposes only and are based upon technical data that EM
Science believes to be accurate. It is intended for use only by persons having the necessary technical skill and at their own
discretion and risk. Since conditions and manner of use are outside our control, we make NO WARRANTY, EXPRESS OR
IMPLIED, OR MERCHANTABILITY, FITNESS OR OTHERWISE.
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