102266
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6810
NIIN: 00N072355
Manufacturer's CAGE: 21076
Part No. Indicator: A
Part Number/Trade Name: HYDROCHLORIC ACID, 320331
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General Information
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Item Name:
Company's Name: SIGMA CHEMICAL CO
Company's Street:
Company's P. O. Box: 14508
Company's City: ST LOUIS
Company's State: MO
Company's Country: US
Company's Zip Code: 63178
Company's Emerg Ph #: 314-771-5765
Company's Info Ph #: 314-771-5765
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 01JAN96
Safety Data Review Date: 21AUG96
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: CBYBG
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code:
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 00N072355
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
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Ingredients/Identity Information
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Proprietary: NO
Ingredient: HYDROGEN CHLORIDE; (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA)
Ingredient Sequence Number: 01
Percent: 100
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: MW4025000
CAS Number: 7647-01-0
OSHA PEL: 5 PPM, C
ACGIH TLV: 5 PPM, C
Other Recommended Limit: N/K
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Physical/Chemical Characteristics
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Appearance And Odor: COLORLESS LIQUID.
Boiling Point: N/K
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): SUPP DATA
Vapor Density (Air=1): 1.3
Specific Gravity: 1.2
Decomposition Temperature: N/K
Evaporation Rate And Ref: N/K
Solubility In Water: N/K
Percent Volatiles By Volume: N/K
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss):
Corrosion Rate (IPY): N/K
Autoignition Temperature:
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Fire and Explosion Hazard Data
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Flash Point: NONE
Flash Point Method: N/P
Lower Explosive Limit: N/K
Upper Explosive Limit: N/K
Extinguishing Media: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Special Fire Fighting Proc: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire And Expl Hazrds: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Report for NIIN: 00N072355
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Reactivity Data
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Stability: YES
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: BASES, AMINES, ALKALI METALS, COPPER, COPPER ALLOYS,
ALUMINUM, CORRODES STEEL. DO NOT ALLOW WATER TO ENTER CNTNR(SUPDAT)
Hazardous Decomp Products: TOXIC FUMES OF HYDROGEN CHLORIDE GAS.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
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Health Hazard Data
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LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
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Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: ACUTE:MAY BE FATAL IF INHALED, SWALLOWED OR
ABSORBED THROUGH SKIN. CAUSES BURNS. MATERIAL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL (EFTS OF OVEREXP)
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: HLTH HAZ:PNEUM & PULM EDEMA. SYMPS OF EXPOS MAY
INCL BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HDCH, NAUS & VOMIT. TARGET ORGAN DATA:SENSE ORGANS & SPECIAL SENSES
(OTHER EYE EFTS). LUNGS, THORAX/RESP (RESP STIMULATION). SKIN & APPENDAGES
(AFTER SYSTEMIC EXPOS: DERMATITIS, OTHER).
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT
LST 15 MINS. ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. SKIN:
IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS WHILE REMOVING
CONTAM CLTHG & SHOES. WASH CONTAM CLTHG BEFORE REUSE. DISCARD CONTAM SHOES.
INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER PROVIDED (SUPDAT)
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: EVACUATE AREA. WEAR NIOSH APPRVD SCBA,
RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY-LIME, SAND OR SODA ASH.
PLACE IN COVERED CNTNRS USING NON-SPARKING TOOLS & TRANSPORT OUTDOORS.
VENTILATE AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE.
Neutralizing Agent: DRY-LIME, SAND OR SODA ASH.
Waste Disposal Method: FOR SM QTYS:CAUTIOUSLY ADD TO LG STIRRED EXCESS OF
WATER. ADJUST PH TO NEUT, SEPARATE ANY INSOL SOLIDS/LIQS & PACKAGE THEM FOR
HAZ-WASTE DISP. FLUSH AQ SOLN DOWN DRAIN W/PLENTY OF WATER. HYDROLYSIS &
NEUTRALIZATION RXNS MAY GENERATE HEAT & (SUPDAT)
Precautions-Handling/Storing: AVOID BRTHG VAP. DO NOT GET IN EYES, ON
SKIN, ON CLTHG. AVOID PRLNG/RPTD EXPOS. CORROSIVE. POISON. KEEP TIGHTLY
CLSD. MAY DEVELOP PRESSURE.
Report for NIIN: 00N072355
Other Precautions: REACTS VIOLENTLY W/WATER. STORE IN A COOL, DRY PLACE.
CAUSES BURNS. IRRITATING TO RESPIRATORY SYSTEM. TAKE OFF IMMEDIATELY ALL
CONTAMINATED CLOTHING. IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED
ADVICE IMMED (SHOW LBL WHERE POSSIBLE).
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Control Measures
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Respiratory Protection: NIOSH APPROVED RESPIRATOR IN NONVENTILATED AREAS
&/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation: MECHANICAL EXHAUST REQUIRED.
Protective Gloves: RUBBER GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA (FP N). WEAR SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Suppl. Safety & Health Data: VP:3.23 PSI @ 21.1C; 7.93 PSI @ 37.7C. MATLS
TO AVOID:BECAUSE OF VIOLENT REACTION. FIRST AID PROC:PERSON IS CONSCIOUS.
CALL MD IMMEDIATELY. WASTE DISP METH:FUMES WHICH CAN BE CONTROLLED BY THE
RATE OF ADDITION. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL
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REGULATIONS. EYE PROT:& FULL LENGTH FACESHIELD (FP N).
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Transportation Data
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Transportation Action Code:
Transportation Focal Point:
Trans Data Review Date:
DOT PSN Code:
DOT Symbol:
DOT Proper Shipping Name:
DOT Class:
DOT ID Number:
DOT Pack Group:
DOT Label:
DOT/DoD Exemption Number:
IMO PSN Code:
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IMO Regulations Page Number:
IMO UN Number:
IMO UN Class:
IMO Subsidiary Risk Label:
IATA PSN Code:
IATA UN ID Number:
IATA Proper Shipping Name:
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IATA Subsidiary Risk Class:
IATA Label:
AFI PSN Code:
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AFI Pack Group:
AFI Label:
Report for NIIN: 00N072355
AFI Special Prov:
AFI Basic Pac Ref:
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
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Disposal Data
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Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
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3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
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Label Data
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Label Required: YES
Technical Review Date: 21AUG96
Label Date: 20AUG96
MFR Label Number:
Label Status: G
Common Name: HYDROCHLORIC ACID, 320331
Chronic Hazard: NO
Signal Word: DANGER!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight:
Contact Hazard-Moderate:
Contact Hazard-Severe: X
Fire Hazard-None: X
Fire Hazard-Slight:
Fire Hazard-Moderate:
Fire Hazard-Severe:
Reactivity Hazard-None:
Reactivity Hazard-Slight: X
Reactivity Hazard-Moderate:
Report for NIIN: 00N072355
Reactivity Hazard-Severe:
Special Hazard Precautions: CORROSIVE. POISON. ACUTE:MAY BE FATAL IF
INHALED, SWALLOWED OR ABSORBED THROUGH SKIN. CAUSES BURNS. MATERIAL IS
EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY BE FATAL AS A RESULT OF
SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL
PNEUMONITIS AND PULMONARY EDEMA. SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA AND VOMITING. CHRONIC:NONE LISTED BY MANUFACTURER.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: SIGMA CHEMICAL CO
Label Street:
Label P.O. Box: 14508
Label City: ST LOUIS
Label State: MO
Label Zip Code: 63178
Label Country: US
Label Emergency Number: 314-771-5765
Year Procured:
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