172556
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6830
NIIN: 013446534
Manufacturer's CAGE: 2A580
Part No. Indicator: A
Part Number/Trade Name: REFRIGERANT 12, FREON 12, GENETRON 12, (SUP
======================================================================
=====
General Information
======================================================================
=====
Item Name: DICHLORODIFLUOROMETHANE & DIFLUOROETHANE, AZEOTROPIC MIX
Company's Name: RACON INC
Company's Street:
Company's P. O. Box: 198
Company's City: WICHITA
Company's State: KS
Company's Country: US
Company's Zip Code: 67201
Company's Emerg Ph #: 415-821-5338
Company's Info Ph #: 316-524-3245 OR 800-835-2916
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 07APR89
Safety Data Review Date: 19MAY92
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Page 1
172556
Other MSDS Number:
MSDS Serial Number: BNRMF
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code: N-
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 013446534
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
======================================================================
=====
Ingredients/Identity Information
======================================================================
=====
Proprietary: NO
Ingredient: METHANE, DICHLORODIFLUORO-; (DICHLORODIFLUOROMETHANE) (SAR
A
III). VP:79.8 PSIG @ 77F. VD:2.32 LB/FT3 @ 77F.
Ingredient Sequence Number: 01
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: PA8200000
CAS Number: 75-71-8
OSHA PEL: NOT APPLICABLE
ACGIH TLV: 1000PPM;1250STEL(MFR
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: EFTS OF OVEREXPOS:PROPERTIES (ASPHY, CARDIAC ARRHYTHMIAS)
WHEN
SNIFFED. SKIN:CONT OF LIQ WILL RESULT IN FREEZING (ING 3)
Ingredient Sequence Number: 02
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
Page 2
172556
-------------------------------------
Proprietary: NO
Ingredient: ING 2:& FROSTBITE OF CONT TISSUE. EYES:CONT OF VAP WILL RE
SULT
IN MILD INFLAMM. INGEST:NOT PROBABLE. FREEZING & (ING 4)
Ingredient Sequence Number: 03
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 3:SEV FROSTBITE OF CONT TISSUE WILL RESULT. CHRONIC:IN
HAL:
SIMILAR AS SYMP ACUTE CNS DEPRESS/SEDATION/LOSS OF(ING 5)
Ingredient Sequence Number: 04
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
Report for NIIN: 013446534
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 4:COORDINATION & MILD DEPRESSION. EFTS DISAPPEARED RAP
IDLY
AFTER CESSATION. INGEST:A SLIGHT EFT ON LIVER (ING 6)
Ingredient Sequence Number: 05
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 5:FUNCTION IN RATS. CARDIAC STUDIES: CARDIAC SENSIT
Page 3
172556
POTENTIAL IS CONSIDERED MOD. AT HIGH CONC CAPABLE OF (ING 7)
Ingredient Sequence Number: 06
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 6:SENSIT HEART TO INJECTED EPINEPHRINE, RESULTING IN
IRREGULAR HEART BEAT (CARDIAC ARRHYTHMIAS), WHICH (ING 8)
Ingredient Sequence Number: 07
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 7:SOMETIMES HAS BEEN FATAL.
Ingredient Sequence Number: 08
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
Report for NIIN: 013446534
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: FIRST AID PROC:20 MIN. LIQ:BECAUSE OF DEFATTING EFTS OF PR
OD,
SKIN & EYE IRRIT MAY OCCUR. FLUSH EXPOSED SKIN & (ING 10)
Ingredient Sequence Number: 09
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
Page 4
172556
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 9:EYES THORO (MIN OF 10-15 MIN) W/LUKE WARM WATER/BALA
NCED
SALINE SOLUTION. IF EYE IRRIT PERSIST, SEE MD. (ING 11)
Ingredient Sequence Number: 10
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 10:INGEST:LIQ:NOT PROBABLE.HOWEVER IF INGEST, KEEP PAT
IENT
CALM, IF CONSCIOUS & GET TO MD IMMED. FROSTBITE (ING 12)
Ingredient Sequence Number: 11
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 11:IS PROBABLE, INDICATED BY NECROSIS OF LIPS & TONGUE
(CONTACTED TISSUE), BLANCHING OF SKIN, PAIN & (ING 13)
Ingredient Sequence Number: 12
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
Report for NIIN: 013446534
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
Page 5
172556
-------------------------------------
Proprietary: NO
Ingredient: ING 12:TENDERNESS. WARM SKIN SLOWLY.
Ingredient Sequence Number: 13
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
======================================================================
=====
Physical/Chemical Characteristics
======================================================================
=====
Appearance And Odor: COLORLESS LIQUID & VAPOR WITH VERY SLIGHT ETHEREA
L
ODOR/ODORLESS.
Boiling Point: -22F,-30C
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): SEE ING
Vapor Density (Air=1): SEE ING
Specific Gravity: 1.31 (WATER =1)
Decomposition Temperature: N/K
Evaporation Rate And Ref: NOT APPLICABLE
Solubility In Water: INSOLUBLE
Percent Volatiles By Volume: 100
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss): N/P
Corrosion Rate (IPY): N/K
Autoignition Temperature:
======================================================================
=====
Fire and Explosion Hazard Data
======================================================================
=====
Flash Point: NON FLAMMABLE
Flash Point Method: N/P
Lower Explosive Limit: N/K
Upper Explosive Limit: N/K
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N)
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND S
CBA
Page 6
172556
AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire And Expl Hazrds: THERMAL DECOMPOSITION PRODUCTS MAY INCLU
DE
CHLORIDES, FLUORIDES AND PHOSGENE (FP N).
======================================================================
=====
Reactivity Data
======================================================================
=====
Stability: YES
Cond To Avoid (Stability): AVOID CONDITIONS WHERE CFC-12 MAY CONTACT O
PEN
FLAMES OR EXTREMELY HOT METAL SURFACES.
Report for NIIN: 013446534
Materials To Avoid: CERTAIN ELASTOMERS, ALKALI/ALKALINE EARTH METALS,
POWDERED ALUMINUM, ZINC, BERYLLIUM ETC. MCA REPORTED THAT (SUPDAT)
Hazardous Decomp Products: CHLORIDES, FLUORIDES & PHOSGENE (FP N). HF,
HCL
& TRACES OF CARBONYL HALIDES.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
======================================================================
=====
Health Hazard Data
======================================================================
=====
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: NO
Health Haz Acute And Chronic: CHLOROFLUOROCARBON MATLS HAVE PRODUCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILA
R EFT
IN HUMANS. ADRENOMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXC
EPT
FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFCS
(FP
N). ACUTE:INHAL:MAY AFFECT RESP/ (EFTS OF OVEREXP)
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: HLTH HAZ:CARDIOVASCULAR SYS. MAY CAUSE TING
LING
SENSATION, HUMMING IN EARS, APPREHENSION & SLURRED SPEECH, DECREASE IN
CONSCIOUSNESS W/AMNESIA, IRREGULAR HEART BEAT, EYE IRRIT, CNS EFTS.
Page 7
172556
SNIFFING OF FLUOROCARBON PROPELLANTS FOR THEIR INTOX EFTS HAS PRODUCED
OVER
100 DEATHS. FLUOROCARBONS EXHIBIT VERY TOX (ING 2)
Med Cond Aggravated By Exp: INDIVIDUALS W/HEART OR RESPIRATORY DISORDE
RS
MAY BE ESPECIALLY SUSCEPTIBLE TO HEALTH HAZARDS.
Emergency/First Aid Proc: INHAL:REMOVE TO FRESH AIR. KEEP WARM & AT RE
ST.
IF BRTHG IS DFCLT (LABORED), GIVE O*2. IF NOT BRTHG, GIVE ARTIF RESP &
CHECK FOR PULSE. IF NO PULSE START CPR. DO NOT GIVE STIMULANTS (ADRENA
LINE,
EPINEPHRINE/HAND HELD ASTHMA AEROSOLS). CALL 911 (IF AVAILABLE) & MD.
KEEP
PATIENT AT REST FOR 24 HRS AFTER OVEREXPOS. NO LONG TERM EFTS ARE EXPE
CTED.
EYE/SKIN:VAP:FLUSH WITH WATER FOR AT LEAST (ING 9)
======================================================================
=====
Precautions for Safe Handling and Use
======================================================================
=====
Steps If Matl Released/Spill: KEEP UPWIND. VENTILATE ENCLOSED SPACES U
NTIL
GAS IS DISPERSED. DO NOT SMOKE OR OPERATE INTERNAL COMBUSTION ENGINES
IN
IMMED VICINITY.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STAT
E
AND FEDERAL REGULATIONS (FP N). EPA HAZ WASTE# UO75. WHEN REMOVED FROM
REFRIDGERATION SYSTEM, MAY BE HAZARDOUS WASTE. CONSULT 40 CFR 261, 262
.
Precautions-Handling/Storing: DO NOT BRTH VAP. AVOID CONT W/EYES, SKIN
&
CLTHG. STORE IN COOL PLACE (<120F). STORE & USE W/ADEQ VENT. LIQUIFIED
,
COMPRESSED GAS.
Other Precautions: NOT FOR FOOD/DRUG/COSMETIC USE. NO SMOKING IN AREA
OF
USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES/HOT
SURFACES. HEAT AND/OR UV RADIA MAY CAUSE FORMATION OF CHLORIDES, FLUOR
IDES
AND/OR PHOSGENE (FP N).
Report for NIIN: 013446534
======================================================================
=====
Page 8
172556
Control Measures
======================================================================
=====
Respiratory Protection: RESP PROT IS NOT NEEDED IF CONC ARE CONTROLLED
. IF
CON EXCEED TLV (1000 PPM) USE A NIOSH/MSHA APPRVD RESP FOR ORGANIC VAP
. IN
VERY HIGH CONC, SCBA SHOULD BE USED.
Ventilation: LOCAL EXHAUST MAY BE NECESSARY TO REDUCE CONC BELOW TLV (
1000
PPM).
Protective Gloves: CLOTH-LINED RUBBER GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: PROTECTIVE CLOTHING SHOULD MIN EXPOSED SKI
N&
INCLUDE FULL FACE SHIELD IF SPLASHING IS POSSIBLE.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Suppl. Safety & Health Data: MFR'S TRADE NAME/PART NO:FLUOROCARBON 12,
CFC-12, R-12. MATL TO AVOID:ALKALI & ALKALINE EARTH METALS (I E SODIUM
,
POTASSIUM & BARIUM) IN THEIR FREE METALLIC FORM MAY REACT VIOLENTLY W/
FLUOROCARBONS. MATLS BECOME MORE REACTIVE WHEN FINELY GROUND. METALS S
UCH
AS MN & AL IN POWDER FORM MAY ALSO REACT, ESP AT HIGH TEMP.
======================================================================
=====
Transportation Data
======================================================================
=====
Transportation Action Code:
Transportation Focal Point: N
Trans Data Review Date: 93068
DOT PSN Code: MPU
DOT Symbol:
DOT Proper Shipping Name: REFRIGERANT GASES, N.O.S.
DOT Class: 2.2
DOT ID Number: UN1078
DOT Pack Group:
DOT Label: NONFLAMMABLE GAS
DOT/DoD Exemption Number:
IMO PSN Code: NAP
IMO Proper Shipping Name: REFRIGERANT GAS, N.O.S. o
IMO Regulations Page Number: 2176
IMO UN Number: 1078
IMO UN Class: 2(2.2)
IMO Subsidiary Risk Label: -
IATA PSN Code: VQM
IATA UN ID Number: 1078
Page 9
172556
IATA Proper Shipping Name: REFRIGERANT GAS, N.O.S. *
IATA UN Class: 2.2
IATA Subsidiary Risk Class:
IATA Label: NON-FLAMMABLE GAS
AFI PSN Code: VQM
AFI Symbols:
AFI Prop. Shipping Name: REFRIGERANT GASES, N.O.S.
AFI Class: 2.2
AFI ID Number: UN1078
AFI Pack Group:
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref: 6-6,6-8
Report for NIIN: 013446534
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
======================================================================
=====
Disposal Data
======================================================================
=====
Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
======================================================================
=====
Label Data
======================================================================
=====
Page 10
172556
Label Required: YES
Technical Review Date: 15MAY92
Label Date: 12MAY92
MFR Label Number:
Label Status: G
Common Name: REFRIGERANT 12, FREON 12, GENETRON 12, (SUPDAT)
Chronic Hazard: YES
Signal Word: WARNING!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight:
Contact Hazard-Moderate: X
Contact Hazard-Severe:
Fire Hazard-None: X
Fire Hazard-Slight:
Fire Hazard-Moderate:
Fire Hazard-Severe:
Reactivity Hazard-None:
Reactivity Hazard-Slight: X
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: AVOID CERTAIN ELASTOMERS, ALKALI/ALKALINE
Report for NIIN: 013446534
EARTH METALS, POWDERED ALUMINUM, ZINC, BERYLLIUM, ETC. ACUTE:INHAL MAY
CAUSE RESPIRATORY/CARDIOVASCULAR EFFECTS, TINGLING SENSATION, HUMMING
IN
EARS, SLURRED SPEECH, DECREASED CONSCIOUSNESS, AMNESIA, IRREGULAR
HEARTBEAT, ASPHYXIATION/DEATH. CONTACT W/LIQUID WILL CAUSE FROSTBITE/
FREEZING, NECROSIS, BLANCHING, PAIN, TENDERNESS TO TISSUE. CHRONIC:MAY
CAUSE SENSITIZATION TO INJECTED EPINEPHRINE CAUSING CARDIAC ARRHYTHMIA
S.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: RACON INC
Label Street:
Label P.O. Box: 198
Label City: WICHITA
Label State: KS
Label Zip Code: 67201
Label Country: US
Label Emergency Number: 415-821-5338
Year Procured:
Page 11
172556
Page 12
|