049551
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6850
NIIN: 00N014271
Manufacturer's CAGE: 60928
Part No. Indicator: A
Part Number/Trade Name: COPPER (II) NITRATE HYDRATE (SEE SUPP DATA)
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General Information
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Item Name:
Company's Name: ALDRICH CHEMICAL CO
Company's Street:
Company's P. O. Box: 355
Company's City: MILWAUKEE
Company's State: WI
Company's Country: US
Company's Zip Code: 53201
Company's Emerg Ph #:
Company's Info Ph #: 414-273-3850
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 15MAR90
Safety Data Review Date: 06JUL95
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: BKKXL
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code: D1
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 00N014271
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
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Ingredients/Identity Information
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049551
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Proprietary: NO
Ingredient: COPPER (II) NITRATE, TRIHYDRATE (1:2:3) (COPPER (II) NITRATE
HYDRATE, 99.999%)
Ingredient Sequence Number: 01
Percent: 99.9
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: GL7875000
CAS Number: 10031-43-3
OSHA PEL: 1.0 MG/M3 (CU) DUST
ACGIH TLV: 1.0 MG/M3 (CU) DUST
Other Recommended Limit: N/K
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Physical/Chemical Characteristics
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Appearance And Odor: BLUE CRYSTALS.
Boiling Point: N/K
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): N/K
Vapor Density (Air=1): N/K
Specific Gravity: N/K
Decomposition Temperature: N/K
Evaporation Rate And Ref: N/K
Solubility In Water: N/K
Percent Volatiles By Volume: N/K
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss): N/P
Corrosion Rate (IPY): N/K
Autoignition Temperature:
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Fire and Explosion Hazard Data
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Flash Point: NONCOMBUSTIBLE
Flash Point Method: N/P
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS.
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire And Expl Hazrds: OXIDIZER. CONTACT WITH OTHER MATERIAL MAY
CAUSE FIRE. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Report for NIIN: 00N014271
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Reactivity Data
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Stability: YES
Cond To Avoid (Stability): HEAT, MOISTURE.
Materials To Avoid: REDUCING AGENTS, ORGANIC MATERIALS.
Hazardous Decomp Products: TOXIC FUMES OF:NO*X.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
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Health Hazard Data
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049551
LD50-LC50 Mixture: LD50:(ORAL, RAT)940 MG/KG.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: NO
Health Haz Acute And Chronic: ACUTE:HARMFUL IF INGESTED OR INHALED.
MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES & UPPER
RESP TRACT, EYES & SKIN. INHALATION MAY BE FATAL AS RESULT OF SPASM,
INFLAMMATION & EDEMA OF LARYNX & BRONCHI, CHEM PNEUMONITIS & PULMONARY
EDEMA.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER
FOR AT LEAST 15 MINUTES. ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/
FINGERS. SKIN:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR 15 MINUTES
WHILE REMOVING CONTAM CLTHG/SHOES. REMOVE AND WASH CONTAM CLTHG PROMPTLY.
INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP), CALL MD.
INGEST:CALL MD IMMEDIATELY (FP N).
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: EVACUATE AREA. WEAR NIOSH/MSHA APPROVED
SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. USE NONSPARKING TOOLS. SWEEP UP,
PLACE IN BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA
& WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: MATL SHOULD BE DISSOLVED IN 1)WATER, 2)ACID SOLN OR
3)OXIDIZED TO WATER-SOLUBLE STATE. PRECIPITATE MATL AS SULFIDE, ADJUSTING
PH OF SOLN TO 7 TO COMPLETE PRECIPITATION. FILTER INSOLUBLES & DISPOSE OF
IN HAZ WASTE SITE. DESTROY ANY (SEE SUPP DATA)
Precautions-Handling/Storing: REFRIGERATE. DO NOT STORE NEAR, NOR ALLOW
CNTCT W/CLTHG & OTHER COMBUST MATL. KEEP TIGHTLY CLOSED. DO NOT BREATHE
DUST.
Other Precautions: HYGROSCOPIC. HARMFUL SOLID. CORROSIVE. DO NOT GET IN
EYES, ON SKIN OR CLOTHING.
Report for NIIN: 00N014271
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Control Measures
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Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER USE AND BEFORE
EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES (FP N).
Suppl. Safety & Health Data: MFR PART NO/TRADE NAME:99.999% 22963-6. WASTE
DISP METH:EXCESS SULFIDE W/SODIUM HYPOCHLORITE. NEUTRALIZE SOLN BEFORE
FLUSHING DOWN DRAIN. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
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Transportation Data
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Transportation Action Code:
Transportation Focal Point: N
Trans Data Review Date: 91225
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049551
DOT PSN Code: LDR
DOT Symbol:
DOT Proper Shipping Name: OXIDIZING SOLID, N.O.S.
DOT Class: 5.1
DOT ID Number: UN1479
DOT Pack Group: III
DOT Label: OXIDIZER
DOT/DoD Exemption Number:
IMO PSN Code: LBH
IMO Proper Shipping Name: OXIDIZING SOLID, N.O.S. o
IMO Regulations Page Number: 5163
IMO UN Number: 1479
IMO UN Class: 5.1
IMO Subsidiary Risk Label: -
IATA PSN Code: SVW
IATA UN ID Number: 1479
IATA Proper Shipping Name: OXIDIZING SOLID, N.O.S. *
IATA UN Class: 5.1
IATA Subsidiary Risk Class:
IATA Label: OXIDIZER
AFI PSN Code: SVW
AFI Symbols:
AFI Prop. Shipping Name: OXIDIZING SOLID, N.O.S.
AFI Class: 5.1
AFI ID Number: UN1479
AFI Pack Group: III
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref: 9-10
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
Report for NIIN: 00N014271
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Disposal Data
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Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
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Label Data
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Label Required: YES
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049551
Technical Review Date: 04JUN91
Label Date: 04JUN91
MFR Label Number:
Label Status: G
Common Name: COPPER (II) NITRATE HYDRATE
Chronic Hazard: N/P
Signal Word: DANGER!
Acute Health Hazard-None:
Acute Health Hazard-Slight: X
Acute Health Hazard-Moderate:
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight:
Contact Hazard-Moderate:
Contact Hazard-Severe: X
Fire Hazard-None:
Fire Hazard-Slight:
Fire Hazard-Moderate:
Fire Hazard-Severe: X
Reactivity Hazard-None:
Reactivity Hazard-Slight: X
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL
MAY CAUSE FIRE. KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE
MATERIALS. DO NOT STORE NEAR COMBUSTIBLE MATERIALS. STORE IN TIGHTLY CLOSED
CONTAINER. ACUTE:MAY BE FATAL IF INHALED. DO NOT BREATHE VAPOR. KEEP
Report for NIIN: 00N014271
CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. HARMFUL IF SWALLOWED,
INHALED OR ABSORBED THROUGH SKIN. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. WASH THOROUGHLY AFTER HANDLING. CAUSES MUCOUS MEMBRANE, UPPER
RESPIRATORY TRACT, EYE AND SKIN IRRITATION. REACTIVITY HAZARD NOT
DETERMINED.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: ALDRICH CHEMICAL CO
Label Street:
Label P.O. Box: 355
Label City: MILWAUKEE
Label State: WI
Label Zip Code: 53201
Label Country: US
Label Emergency Number:
Year Procured:
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