Material Safety Data Sheet
Section 1 - Manufacturer and Product Information
Manufacturer: CARBOLINE, DIVISION OF STONCOR GROUP, INC.
Mailing 350 HANLEY IND. CT.
Address: ST. LOUIS, MO 63144
Customer Information: (314) 644-1000
24 Hour Emergency CHEMTREC 1-800-424-9300
Phone: Outside US (703) 527-3887
Product Name: Plasite 9500 Part B Revision Date: 08/18/2003
Product Code: 293PB1NL Supercedes : 07/11/2003
Preparer: Schlereth, Ken
Section 2 - Composition / Information On Ingredients
CAS # OR NJ TRADE SECRET # CHEMICAL NAME WEIGHT % LESS THAN
000064-17-5 ETHYL ALCOHOL 30.0
000108-45-2 mPHENYLENEDIAMINE 30.0
000101-77-9 4,4-METHYLENE DIANALINE 20.0
000107-98-2 PROPYLENE GLYCOL 20.0
MONOMETHYL ET
025214-70-4 POLYMERIC MDA 15.0
Chemical Exposure Guidelines
CAS# OR NJ TRADE SECRET # OSHA PEL ACGIH TLV
000064-17-5 1900.0 MG/M3 1900.0 MG/M3
000108-45-2
000101-77-9 0.010 PPM 0.010 PPM
000107-98-2 100.0 PPM 100.0 PPM
025214-70-4 .1 PPM .1 PPM
Section 3 - Hazards Identification
Emergency Overview: FLAMMABLE. SUSPECT CANCER HAZARD. CONTAINS MATERIAL WHICH MAY CAUSE
CANCER. HARMFUL IF IN CONTACT WITH SKIN. HARMFUL IF SWALLOWED. MILD EYE IRRITANT. MILD SKIN
IRRITANT. MAY CAUSE SKIN SENSITIZATION.
Potential Health Effects:
Eyes: CONTACT WILL CAUSE MILD EYE IRRITATION. CAUSES REDNESS AND DISCOMFORT.
Skin: CONTACT WILL CAUSE MILD IRRITATION. REPEATED EXPOSURE MAY CAUSE CANCER, ALLERGIC
REACTION / SENSITIZATION.
Ingestion: INGESTION MAY CAUSE DEATH, UNLESS TREATED PROMPTLY.
Inhalation: INHALATION OF MISTS MAY CAUSE IRRITATION IN THE RESPIRATORY TRACT. REPEATED
EXPOSURES CAUSES DRYNESS OF NASAL PASSAGES.
Systemic: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED EXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. REPEATED AND/OR PROLONGED EXPOSURES MAY
RESULT IN LIVER DISORDERS, KIDNEY DISORDERS, AND ADVERSE SKIN EFFECTS.
* This product contains the following chemicals classified by the International Agency for Research on Cancer (IARC)
as 1, 2A, or 2B carcinogens:
CAS # OR NJ TRADE SECRET # IARC
000101-77-9 Possibly Carcinogenic
025214-70-4 Possibly Carcinogenic
Section 4 - First Aid Measures
Eyes: HOLD EYELIDS APART AND IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES.
Skin: WASH AFFECTED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
DESTROY CONTAMINATED LEATHER APPAREL. LAUNDER CONTAMINATED CLOTHING PRIOR TO REUSE.
Ingestion: IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY. REMOVE STOMACH CONTENTS BY GASTRIC
SUCTION OR INDUCE VOMITING ONLY AS DIRECTED BY MEDICAL PERSONNEL.
Inhalation: MOVE PATIENT TO FRESH AIR. IF BREATHING HAS STOPPED OR IS LABORED GIVE ASSISTED
RESPIRATION (MOUTH TO MOUTH). PREVENT ASPIRATION OF VOMIT. TURN VICTIM'S HEAD TO THE SIDE.
Section 5 - Fire Fighting Measures
Flash Point: <60F / 11C <60 F / <16 C Lower Explosive Limit, %: N.D.
Upper Explosive Limit, %: N.D.
(TCC)
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Haz. Combustion Products: MAY GENERATE CARBON MONOXIDE GAS, NITROGEN OXIDE GASES, AND
AMMONIA GAS.
Fire Fighting Instruction: WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS EXPOSED TO FIRE.
Fire Fighting Equipment: BUTYL RUBBER BOOTS, GLOVES, AND BODY SUIT AND SELF-CONTAINED
BREATHING APPARATUS.
Other Information: VAPORS ARE HEAVIER THAN AIR AND WILL ACCUMULATE. VAPORS WILL FORM
EXPLOSIVE CONCENTRATIONS WITH AIR. VAPORS TRAVEL LONG DISTANCES AND WILL FLASHBACK.
CLASS B FIRE
Section 6 鈥? Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: USE ADEQUATE PROTECTION EQUIPMENT. USE
RESPIRATORY PROTECTION EQUIPMENT AND PROTECTIVE CLOTHING. VENT CLOSED SPACES TO
OUTSIDE ATMOSPHERE. STOP THE LEAK, VENTILATE THE SPACE INVOLVED. REDUCE VAPOR SPREADING
WITH A WATER SPRAY. SHUT OFF OR REMOVE ALL IGNITION SOURCES. CONSTRUCT A DIKE TO PREVENT
SPREADING. IF RECOVERY IS NOT FEASIBLE, ADMIX WITH DRY SOIL, SAND OR NON-REACTIVE
ABSORBANT AND PLACE IN A CONTAINER OR DUMPSTER PENDING DISPOSAL. TRANSFER TO
CONTAINERS BY SUCTION IF POSSIBLE.
Section 7 - Handling And Storage
Handling: AVOID CONTACT WITH SKIN OR EYES. WHEN HANDLING, DO NOT EAT, DRINK, OR SMOKE.
AVOID USING IN ANY SPRAY APPLICATION WITHOUT STRICT CONFORMANCE TO THE OSHA LIMIT FOR
MAXIUM ALLOWABLE AIRBORNE CONCENTRATIONS.
Storage: kEEP AWAY FROM: ACIDS, OXIDIZERS, HEAT, FLAMES, SPARKS. KEEP IN COOL, DRY,
VENTILATED STORAGE AND IN CLOSED CONTAINERS. GROUND ALL CONTAINERS DURING TRANSFER. DO
NOT STORE IN IRON OR OTHER REACTIVE METAL CONTAINERS.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: EXPLOSION PROOF AND GENERAL LOCAL EXHAUST WITH 12-30 AIR CHANGES PER
HOUR. MAINTAIN AIR CONCENTRATIONS IN ACCORD WITH EXPOSURE GUIDELINES
Respiratory Protection: USE ONLY WITH VENTILATION TO KEEP LEVELS BELOW EXPOSURE GUIDELINES
(Section II). USER SHOULD TEST AND MONITOR EXPOSURE LEVELS TO ENSURE ALL PERSONEL ARE
BELOW GUIDELINES. IF NOT SURE, OR NOT ABLE TO MONITOR, USE MSHA/NIOSH APPROVED SUPPLIED
AIR RESPIRATOR. FOLLOW ALL CURRENT OSHA REQUIREMENTS FOR RESPIRATOR USE.
Skin Protection: NEOPRENE RUBBER GLOVES. IMPERABLE GLOVES. CUFFED BUTYL RUBBER GLOVES.
WEAR IMPERVIOUS CLOTHING. LONG SLEEVED CLOTHING. SLICKER SUIT.
Eye Protection: CHEMICAL SAFETY GLASSES
Other Protective Equipment: PROVIDE READILY ACCESSIBLE EYE WASH STATIONS AND SAFETY
SHOWERS. PROMPTLY REMOVE CLOTHING THAT IS CONTAMINATED. DISCARD CONTAMINATED LEATHER.
Section 9 - Physical And Chemical Properties
Physical State: LIQUID
Appearance: N/A
Odor: AMMONICAL/SOLVENT
Vapor Pressure: 97 MMHG @ 68DF
Vapor Density: HEAVIER THAN AIR
Boiling Range: None - None
Solubility in H2O: N/A
Specific Gravity: 0.937
Viscosity: N/A
pH: N/A
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Stability: STABLE
Conditions To Avoid: HEAT, SPARKS, OPEN FLAME
Incompatibility: MINERAL ACIDS, ORGANIC ACIDS, OXIDIZING AGENTS, REACTIVE METALS, SODIUM OR
CALCIUM HYPOCHLORITE. PRODUCT SLOWLY CORRODES COPPER, ALUMINUM & ZINC.
Hazardous Decomposition Products: FIRE: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES,
NITRIC ACID, NITROSAMINES, ALDEHYDES. WHEN HEATED: AMMONIA, IRRITATING AND TOXIC FUMES.
Hazardous Polymerization: WILL NOT OCCUR.
Section 11 - Toxicological Information
Skin/Dermal: LD50 RABBIT: >1000 MG/KG
Oral/Ingestion: LD50 RAT: >735 MG/KG
Inhalation: >20000 PPM/10HR
Section 12 - Ecological Information
Movement & Partitioning: NOT DETERMINED
Degradation & Transformation: NOT DETERMINED
Ecotoxicology: NOT DETERMINED
Section 13 - Disposal Information
Disposal Information: COMPLY WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Section 14 - Transportation Information
DOT Proper Shipping Name: PAINT
DOT Technical Name: None
DOT Hazard Class: 3
Hazard Subclass: NONE
DOT UN/NA Number: UN1263
Packing Group: II
Resp. Guide Page: 127
Section 15 - Regulatory Information
CERCLA 鈥? SARA Hazard Category
This product has been reviewed according to the EPA 鈥楬azard Categories鈥? promulgated under Sections 311and 312
of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
CAS # OR NJ TRADE SECRET # CHEMICAL NAME
000101-77-9 4,4-METHYLENE DIANALINE
025214-70-4 POLYMERIC MDA
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
CAS # OR NJ TRADE SECRET # CHEMICAL NAME
000108-45-2 mPHENYLENEDIAMINE
Clean Air Act:
Coating Category: INDUSTRIAL MAINTENANCE COATINGS
VOC Content Limit (g/l)*: 450
Product VOC Content (g/l)*: 239
Thinning Recommendations: 10%
Application Recommendations: FOR INDUSTRIAL USE ONLY
* Grams of VOC per liter of coating product as applied (mixture of Part A and Part B) per EPA Method 24.
U.S. State Regulations: As follows 鈥?
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
None
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
None
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
CAS # OR NJ TRADE SECRET # CHEMICAL NAME
000101-77-9 4,4-METHYLENE DIANALINE
Warning: The following ingredients present in the product are known to the state of California to cause birth defects,
or other reproductive hazards.
None
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
* CANADIAN DSL:
All chemical ingredients included on inventory
* European Economic Community (EEC) EINECS Master Inventory:
All chemical ingredients included on inventory
Section 16 - Other Information
US STATE REGULATIONS CALIFORNIA: THE FOLLOWING INFORMATION IS REQUIRED BY THE STATE OF
CALIFORNIA FOR THIS PRODUCT (PROPOSITION 65) *THIS PRODUCT CONTAINS CHEMICALS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER.
HMIS Ratings:
Health: 3 Flammability: 3 Reactivity: 0 Personal Protection: X
REASON FOR REVISION: Changed company name from Plasite to Carboline
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Information presented herein has been compiled from sources considered to be dependable and is accurate and
reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as
recommending any practice or any product in violation of any patent or in violation of any law or regulation. It is the
user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such
safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material
and, since conditions of use are not under our control, we must necessarily disclaim all liability with the respect to the
use of any material supplied by us.
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