CHEMTREC Transportation
Emergency Phone: 800-
Material 424-9300
Pittsburgh Poison Control
Safety Data Center
Health Emergency No.: 412-
681-6669
Sheet NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident
involving chemicals
Section 1 - Chemical Product / Company Information
Revision
ADDITIVE 8505 08/04/2008
Product Name:
Date:
Identification
PLMSDS 8505S1NL Supercedes : 08/02/2005
Number:
Product
FOR INDUSTRIAL USE ONLY
Use/Class:
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
350 Hanley Industrial Ct.
St. Louis, MO 63144
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWAOSHA-CEIL
TRIS-2,4,6- 90-72-2 100.0 NE N/E NE NE
(DIMETHYLAMINOMETHYL)
PHENOL
Section 3 - Hazards Identification
Emergency Overview: Corrosive Material. Harmful if swallowed. Can cause eye and skin burns. May
cause skin sensitization.
Effects Of Overexposure - Eye Contact: Can cause eye burns.
Effects Of Overexposure - Skin Contact: Can cause skin burns.
Effects Of Overexposure - Inhalation: May cause nose and throat irritation. May cause lung irritation.
May cause allergic respiratory reaction, effects may be permanent.
Effects Of Overexposure - Ingestion: Harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Prolonged contact may result in chemical burns and
permanent damage. Subchronic exposure of this material or component in test animals has caused
abnormalities in the following organ(s) : Central Nervous System.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Medical Conditions Prone to Aggravation by Exposure: If sensitized to amines, epoxies, or other
chemicals do not use. See a physician if a medical condition exists. Eye disease. Skin disorders and
allergies. Neurological disorders.
Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult
a physician.
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First Aid - Skin Contact: In case of contact, immediately wash with plenty of soap and water for at least
15 minutes. Seek medical attention. Remove contaminated clothing and shoes. Clean contaminated
clothing and shoes before re-use.
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a
physician if symptoms persist or exposure was severe.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point, F: 206F (96C) Lower Explosive Limit, %: N/A
Upper Explosive Limit, %: N/A
(Setaflash)
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: May generate ammonia gas. May generate toxic nitrogen oxide
gases. Use of water may result in the formation of very toxic aqueous solutions. Do not allow run-off from
fire-fighting to enter drains or water courses. Incomplete combustion may form carbon monoxide.
Downward personnel must be evacuated. Burning produces obnoxious and toxic fumes.
Special Firefighting Procedures: Avoid contact with the skin. A face shield should be worn. Use
personal protective equipment. Wear Self-contained breathing apperatus for fire fighting if necessary.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Use self-contained breathing apperatus and
chemically protective clothing. Wear suitable protective clothing, gloves and eye/face protection. Evacuate
personnel to safe areas.
Section 7 - Handling And Storage
Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty
containers. Use only in accordance with Carboline application instructions, container label and Product
Data Sheet.
Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store
in a cool, dry place with adequate ventilation.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).
Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in
Section 2. User should test and monitor exposure levels to ensure all personnel are below guidelines. If
not sure, or not able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current
OSHA requirements for respirator use. For silica containing coatings in a liquid state, and/or if no
exposure limits are established in Section 2 above, supplied air respirators are generally not required.
Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates
to skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.
Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.
Other protective equipment: Eye wash and safety showers should be readily available.
Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or
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using toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before
reuse. Leather shoes can absorb and allow hazardous materials to pass through. Check shoes carefully
after soaking before reuse.
Section 9 - Physical And Chemical Properties
266 F (130 C) - 320 F (160 C) Vapor Density: Heavier than Air
Boiling Range:
Amine-Like N/D
Odor: Odor Threshold:
Light Yellow Lquid Slower Than Ether
Appearance: Evaporation Rate:
N/D
Solubility in H2O:
N/D 0.98
Freeze Point: Specific Gravity:
<0.01 mmHg @ 70F (21C) Alkaline
Vapor Pressure: PH:
Liquid
Physical State:
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Heat, sparks and open flames.
Incompatibility: Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these
operations.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: N/D Product LC50: N/D
Chemical Name CAS Number LD50 LC50
TRIS-2,4,6- (DIMETHYLAMINOMETHYL) 90-72-2 2169 MG/KG ORAL NOT AVAILABLE
PHENOL
Section 12 - Ecological Information
Ecological Information: No data
Section 13 - Disposal Information
Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental
regulations. Responsibility for proper waste disposal is with the owner of the waste.
Section 14 - Transportation Information
Corrosive Liquid NOS Packing Group: III
DOT Proper Shipping
Name:
tris 2,4,6 N/A
DOT Technical Name: Hazard
(dimethylaminomethyl) Subclass:
phenol
8 154
DOT Hazard Class: Resp. Guide
Page:
UN1760
DOT UN/NA Number:
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Additional Notes: None.
Section 15 - Regulatory Information
CERCLA - SARA HAZARD CATEGORY
This product has been reviewed according to the EPA Hazard Categories promulgated under Sections
311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Section 313 Substances exist in this product
TOXIC SUBSTANCES CONTROL ACT
All components of this product are listed on the TSCA inventory.
This product contains the following chemical substances subject to the reporting requirements of TSCA
12(B) if exported from the United States:
No TSCA 12(B) Substances exist in this product
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
BIS(DIMETHYLAMINOMETHYL)PHENOL 71074-89-0
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
BIS(DIMETHYLAMINOMETHYL)PHENOL 71074-89-0
CALIFORNIA PROPOSITION 65
Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:
No California Proposition 65 Carcinogens exist
Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards:
No California Proposition 65 Reproductive Toxins exist
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of
the 16 headings.
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CANADIAN WHMIS CLASS: D2B E
Section 16 - Other Information
HMIS Ratings
Health: 3 Flammability: 1 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 0
REASON FOR REVISION: Routine Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations
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