SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET AA 357
Threshold Limited Value
ALDON None established for this mixture. TWA Triethylamine [CAS No. 121-44-8]
1533 W.Henrietta Rd.
10 ppm; 40 mg/m3; STEL 15 ppm, 60 mg/m3 (Air).
AA 357
Avon, New York 14414 MSDS No.
庐
CORPORATION December 28, 1995
(716) 226-6177 Effective Date
Effects of Overexposure Toxicity data: None available for this solution. ACUTE: Triethylamine is a
severe irritant to eyes and mucous membranes. May cause skin irritation.
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE CHRONIC: Prolonged overexposure to Triethylamine may cause damage to
liver and/or kidneys. For Triethylamine: Mutation data cited (RTECS, 1986),
Product ANESTHEFLY KIT
CHEMTREC reproductive effects cited (RTECS No. YE0175000).
Health 2
800-424-9300
Chemical
Emergency and
Triethylamine Mixture INHALATION AS MIST: Remove to fresh air. If not breathing, give artificial
Synonyms 3
Fire
Day 716-226-6177 respiration. If breathing is difficult, give oxygen. Get medical attention.
First Aid Procedures
Formula Mixture. See Section II. EYES: Flush thoroughly with water for at least 15 minutes, lifting lower and
1
Reactivity
NFPA upper eyelids occasionally. Get immediate medical attention. SKIN: Flush
HAZARD RATING HMIS *
Unit Size up to 4 Lt. with water, then wash with mild soap and water. Should irritation develop,
LEAST SLIGHT MODERATE HIGH EXTREME
get medical attention. INGESTION: If swallowed, if conscious, give one or
0 1 2 3 4
C.A.S. No. Mixture. See Section II. two glasses of water to drink, induce vomiting and call physician. Never give
SECTION II INGREDIENTS OF MIXTURES anything by mouth to an unconscious person.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Unstable
Stability Excessive heat and open flame.
Triethylamine: (CAS No. 121-44-8); RTECS No. YE0175000 >10 10 ppm (ACGIH TWA).
Stable X
Ethyl Alcohol: (CAS No. 64-17-5); RTECS No. KQ6300000 >10 1000 ppm (ACGIH TWA). Incompatibility
Strong oxidizers, strong caustics.
(Materials to Avoid)
DANGER! FLAMMABLE! HARMFUL IF SWALLOWED,
Hazardous If heated to decomposition, this product may produce ammonia as fumes,
INHALED OR ABSORBED THROUGH SKIN.
Decomposition Products oxides of carbon and/or nitrogen.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Approx. -115掳C (-175掳F) Approx. 0.726-0.730 @ 20/20掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 85-91掳C (185-195掳F) TEA 100%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 52 @ 20掳C (68掳F) TEA Ether Greater than 1.
=1)
(
Steps to be taken in case Recover for use if not contaminated. Absorb spill in vermiculite, sand,
Vapor Density (Air=1) 3.5 (TEA)
material is released or spilled earth, paper towel and place in a suitable container. Wash spill area
Solubility in Water Complete. with soap and water. For small spills, cover with sodium bisulfate.
Spray with water and flush to sewer with copious amounts of water.
Appearance & Odor Clear, colorless solution with pleasant sweet odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator equipped with an afterburner and scrubber
% by Volume
(Method Used) Approx. 20掳F (-7掳C) As TEA 1.2% 8.0%
or contract with a licensed waste disposal system.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use water spray; alcohol 鈥渇oam鈥?; dry chemical; or carbon dioxide.
Media
None needed under normal conditions of use with adequate ventilation. If airborne
Respiration Protection
concentration is high, a NIOSH/MSHA-approved chemical cartridge respirator may be used.
(Specify Type)
SPECIAL FIREFIGHTING
Fire fighters should wear full protective equipment and NIOSH/MSHA-approved Local Exhaust Yes. Special No.
PROCEDURES Ventilation
self-contained breathing apparatus operated in pressure demand or other Yes. Adequate to maintain below exposure limit.
Mechanical (General) Other
positive pressure mode. Use water spray to keep fire-exposed containers cool.
Eye Protection
Protective Gloves Rubber. Chemical safety glasses.
Autoignition Temperature: No information available. Other Protective
Lab coat, eye wash station, proper gloves, adequate ventilation.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 68)
Precautions to be Taken
UNUSUAL FIRE AND Keep container tightly closed and store in a cool, dry well-ventilated area.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Triethylamine vapors are heavier than air and may travel along the
ground to a distant source of ignition and flash back. Avoid contact with skin, eyes and mucous membranes.
Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date 12/28/95 Michael Raszeja
No. 3 MR
Coordinator
D.O.T. FLAMMABLE LIQUID, N.O.S. , (TRIETHYLAMINE, DENATURED ETHYL ALCOHOL), 3, UN 1993 The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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