SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET CC 105
Threshold Limited Value
ALDON None established by (ACGIH), 1983-84. RTECS No. NH3485000
1533 W.Henrietta Rd. LD50 Orl-rat: 850 mg/kg.
CC 105
Avon, New York 14414 MSDS No.
庐
CORPORATION Effective Date February 7, 1995
(716) 226-6177
Effects of Overexposure Avoid breathing dust. Irritating to skin, eyes and respiratory tract. May be
fatal if swallowed. Causes severe burns to respiratory gastrointestinal tract.
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE Corrosive to eyes and skin on contact. Exercise appropriate procedures to
minimize potential hazards.
CALCIUM HYPOCHLORITE
Product CHEMTREC
0 2
Health
800-424-9300
Chemical
Emergency and
Calcium Hypochlorite, Hydrated mixture * 2 2 EYES: Flush thoroughly with water for at least 15 minutes, lifting upper and
Synonyms 0
Fire
Day 716-226-6177 lower eyelids occasionally. Get immediate medical attention. SKIN: Flush
oxy First Aid Procedures
Ca(OCl)
Formula thoroughly with water, then wash with mild soap and water. INGESTION:
2
Reactivity
2
NFPA If swallowed, do NOT induce vomiting. If conscious, give several glasses of
HAZARD RATING HMIS *
up to 2.5 Kg.
Unit Size water to drink. Call physician immediately. Never give anything by mouth
LEAST SLIGHT MODERATE HIGH EXTREME
to an unconscious person. INHALATION: Remove to fresh air. If not
0 1 2 3 4
7778-54-3
C.A.S. No. breathing give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Heat, sparks or flame. Any form of contamination.
Conditions to Avoid
Stability Unstable
Calcium Hypochlorite, equivalent to available chlorine 65% minimum 65-70% None established. Acids will cause release of chlorine gas. Evolves
Stable X chlorine gas at ordinary temperature.
Incompatibility Acids, flammables, organics, reducing agents. Example: Oil, kerosene, gasoline,
paint products and most other organic material.
(Materials to Avoid)
DANGER! STRONG OXIDIZER! HARMFUL IF SWALLOWED
Hazardous Acids or ammonia contamination or excessive heat will release chlorine gas.
OR INHALED. HARMFUL IF EXPOSED TO SKIN OR EYES.
Decomposition Products Chlorine and chlorides.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Decomposes. 2.01 @ 20掳C. Approx 0.98 (variable).
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Decomposes 177掳C (350掳F) Not applicable. X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Not applicable. Not applicable.
=1)
(
Steps to be taken in case Carefully sweep up and dissolve in water immediately. Neutralize
Vapor Density (Air=1) Not applicable. dissolved material by adding Hydrogen peroxide 35% solution. Then
material is released or spilled dilute neutralized material with plenty of water and flush to sewer.
Solubility in Water Approx. 18% @ 25掳C.
(One pint of 35% Hydrogen peroxide solution per pound of Calcium
hypochlorite.)
White powder, granules or pellets; strong chlorine-like odor.
Appearance & Odor
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Flush neutralized solution to sewer. Dilution at least 100 gallons of water per
% by Volume
Non-flammable (NA). NA -------- --------
(Method Used)
pound of Calcium hypochlorite.
Extinguisher Use water, preferably in form of spray; carbon dioxide (CO2 ); dry chemical (ABC). SECTION VIII SPECIAL PROTECTION INFORMATION
Media
In case of rapid decomposition, use approved gas mask in area where vapors are present.
Respiration Protection
Work in a ventilation hood. NIOSH/MSHA approved respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. Storage area should be well-ventilated.
Local Exhaust Special
PROCEDURES Ventilation Recommended. Adequate to maintain below exposure limit.
Mechanical (General) Other
Use only water in the event of contamination resulting in fire or
*Contains: rapid decomposition. Wear a NIOSH-approved, self-contained
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
breathing apparatus and full protective clothing; wear goggles if
Sodium Chloride: (CAS No. 7647-14-5)...10-20%
Calcium Chlorate: (CAS No. 10137-74-3)...0-5% Other Protective
eye protection is not provided. Lab coat, vented hood, proper gloves, eye wash station, fire extinguisher.
Calcium Chloride: (CAS No. 10043-52-4)...0-5% Equipment
Calcium Hydroxide: (CAS No. 1305-62-0)...0-4%
SECTION IX SPECIAL PRECAUTIONS
Calcium Carbonate: (CAS No. 471-34-1)...0-4%
Do not get in eyes, on skin, or on clothing. Store in original container.
Precautions to be Taken
UNUSUAL FIRE AND Avoid any form of contamination. Store in a cool, dry well-ventilated
in Handling & Storing
EXPLOSION HAZARDS area, away from combustible materials. Add material only to water.
Prevent any form of contamination since a violent reaction may result.
Keep container tightly closed when not in use.
Wash thoroughly after handling.
Spontaneous decomposition @ 350掳F liberating chlorine gas. Powerful
oxidizing material. With acids evolves chlorine at ordinary tempera- Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
tures. Not combustible but evolves oxygen at higher temperature. May cause fire or explosion when mixed with other chemicals.
Readily ignites combustible or organic materials when in contact. May Fire may result from contact of dry material with cloth or flammables.
undergo accelerated decomposition with evolution of heat. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 45) Approved
Revision Date Michael Raszeja
No. 3 2/7/95 MR
Coordinator
D.O.T. CALCIUM HYPOCHLORITE, HYDRATED MIXTURES, 5.1, UN 2880, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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