SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET BB 175
Threshold Limited Value RTECS No. EF9100000 Bromine TWA: 0.1 ppm (air), 0.66 mg/m3 (air);
ALDON 1533 W.Henrietta Rd. 3
STEL: 0.3 ppm, 2 mg/m (ACGIH 1992-93)
BB 175
Avon, New York 14414 MSDS No.
庐
CORPORATION February 16, 1996
Effective Date
(716) 226-6177
Effects of Overexposure In both liquid and vapor form it seriously burns tissue upon contact. A toxic
gas, very irritating to the eyes and respiratory tract. Lachrymation occurs at
less than 1 part per million and respiratory damage occurs at 10 ppm.
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE
Irritating effect so great that no one would voluntarily remain in its presence.
BROMINE WATER
Product INGESTION: Of solution may cause severe gastroenteritis and death.
CHEMTREC
0 Health 4
800-424-9300
Chemical
Emergency and SKIN: Flush with water for at least 15 minutes. Remove contaminated
Bromine Saturated Water 4 0
Synonyms 0
Fire clothing. Get medical attention. EYES: Flush thoroughly with water for at
Day 716-226-6177
oxy First Aid Procedures least 30 minutes, lifting upper and lower eyelids occasionally. Get
Mixture. See Section II.
Formula 3
Reactivity
NFPA immediate medical attention. INHALATION: Remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen.
HAZARD RATING HMIS *
Unit Size up to 4 Lt.
Get medical attention. INGESTION: If swallowed, do NOT induce
LEAST SLIGHT MODERATE HIGH EXTREME
vomiting. If conscious, give several glasses of water or milk to drink. Get
0 1 2 3 4
C.A.S. No. Mixture. See Section II.
immediate medical attention. Never give anything by mouth to an
SECTION II INGREDIENTS OF MIXTURES unconscious person.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Bromine: (CAS No. 7726-95-6) 3% See Section V. Excessive temperature and heat.
Stable X
Water: (CAS No. 7732-18-5) 97% None established. Incompatibility Oxidizable and reactive materials. Heat of reaction may cause ignition of
combustible materials.
(Materials to Avoid)
DANGER! CORROSIVE! POISON CAUSES SEVERE BURNS.
Hazardous
VAPOR EXTREMELY HAZARDOUS. MAY BE FATAL IF INHALED OR SWALLOWED. When heated, emits highly toxic fumes of bromine.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Freezes approx. 0掳C (32掳F) Approx. 1.01 @ 20掳C.
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 59掳C (138掳F) (Bromine). 97%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 175 mm at 21掳C (Bromine). Ether Greater than 1 (Bromine).
=1)
(
Steps to be taken in case
Vapor Density (Air=1) Cover with a reducer (hypo, a bisulfite, or a ferrous salt, but not
5.5 (Bromine).
material is released or spilled carbon, sulfur or strong reducing agents). Mix well and spray with
Solubility in Water 3.35 grams Bromine per 100 mL. water at 25掳C. water. A sulfite or a ferrous salt will require addition of some 3
molar-sulfuric acid to promote rapid reduction.
Appearance & Odor Clear, reddish-brown, liquid; strong characteristic odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Scoop slurry into a container of water, neutralize with soda ash and flush to
% by Volume
(Method Used) Non-flammable (NA). NA -------- --------
drain with excess water.
Extinguisher
Use any media suitable for extinguishing supporting fire. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
Work in ventilation hood or wear a NIOSH/MSHA-approved respirator with organic vapor
Respiration Protection
and acid gases canister or a self-contained breathing apparatus.
(Specify Type)
SPECIAL FIREFIGHTING
Yes. No.
Local Exhaust Special
This material is highly corrosive. When heated, emits highly toxic fumes.
PROCEDURES Ventilation Yes. Adequate to maintain below exposure limit.
In fire conditions, wear a NIOSH/MSHA-approved self-contained breathing Mechanical (General) Other
apparatus and full protective clothing. Use large amounts of water to cool
Protective Gloves Eye Protection
Rubber. Splash-proof goggles.
container and wash away spills. Hypo solution (Sodium Thiosulfate) or
limewater should be poured over small spills. Other Protective
Goggles and shield, lab coat and apron, ventilation hood, proper gloves, eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 59)
Store in a cool, dry area, out of direct sunlight. Separate from combustible,
Precautions to be Taken
UNUSUAL FIRE AND organic or other readily oxidizable materials. Keep above 32掳F (0掳C) to
in Handling & Storing
EXPLOSION HAZARDS prevent freezing but avoid heating above atmospheric pressure; vapor
Keep container tightly closed when not in use.
pressure breaks container.
Read label on container before using. Do not wear contact lenses when working with chemicals.
May ignite a combustible material upon contact. A very powerful Other Precautions
oxidizer. Fire or heat will liberate hazardous bromine from Avoid contact with skin, eyes and clothing. Do not breathe vapor. Use
solution. with adequate ventilation. Immediately remove and wash contaminated
clothing. Discard contaminated shoes. Wash thoroughly after handling.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 4 Michael Raszeja MR
2/16/96 Coordinator
D.O.T. BROMINE SOLUTIONS, 8, UN 1744, PG I The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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