SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET AA 380
Threshold Limited Value RTECS Ref No. CC6825000 Toxicity data: orl-human LDLo 2 mg/kg; orl-rat LD50 115
ALDON mg/kg. TLV - TWA: Antimony and compound, as Antimony 0.5 mg/m3. OSHA - AIR:
1533 W.Henrietta Rd.
TWA 500 ug (Sb)/m3.
AA 380
Avon, New York 14414 MSDS No.
庐
CORPORATION June 2, 1995
Effective Date
(716) 226-6177
Effects of Overexposure INGESTION: MAY BE FATAL IF SWALLOWED. It can cause cough,
metallic taste, salivation, nausea, diarrhea, weight loss, stomach pain,
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE vomiting, low blood pressure, breathing trouble with possible collapse,
convulsion and coma. Skin rash may also occur. Large doses can cause
Product ANTIMONY POTASSIUM TARTRATE
CHEMTREC severe damage to the liver, heart, lung and kidneys.
3
Health
800-424-9300
Chemical
Emergency and INGESTION: If swallowed, if conscious, and not in shock or convulsing, give
Potassium Antimony (III) Oxide Tartrate
Synonyms 0
Fire
Day 716-226-6177 one or two glasses of water to drink. Induce vomiting and call physician. If
First Aid Procedures vomiting should occur involuntarily, keep head lower than hips to prevent
KOOC鈥HOH鈥HOH鈥OO(SbO)鈥?1/2H O
Formula 1
Reactivity
2
NFPA aspiration. Never give anything by mouth to an unconscious person.
HAZARD RATING INHALATION: Remove victim to fresh air. Give artificial respiration if not
HMIS *
up to 2.5 Kg.
Unit Size
breathing. If breathing is difficult, give oxygen. Get medical attention.
LEAST SLIGHT MODERATE HIGH EXTREME
SKIN: Flush thoroughly with water, then wash with mild soap and water.
0 1 2 3 4
C.A.S. No. 28300-74-5
EYES: Flush thoroughly with water for at least 15 minutes, lifting lower and
SECTION II INGREDIENTS OF MIXTURES upper eyelids occasionally. Get medical attention.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Antimony Potassium Tartrate, Hemihydrate 100% See Section V. Excessive temperature and heat.
Stable X
Incompatibility Avoid conditions in which nascent hydrogen will react with antimony to form stibine
(Materials to Avoid) (SbH3 ), which is extremely toxic.
DANGER! POISON. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED.
Hazardous Thermal decomposition or burning will produce carbon dioxide and/or
DO NOT BREATH DUST. USE WITH ADEQUATE VENTILATION.
carbon monoxide and fumes of antimony metal.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) >300掳C (572掳F) 2.607
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Decomposes. 2.5% at 100掳C X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. Not applicable.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) Unknown. Using a respirator and protective clothing, secure spills at the source as
material is released or spilled soon as possible. Collect spilled material in a manner so as to avoid
Solubility in Water 8.7 grams per 100 mL. water at 25掳C.
dusting and seal it in appropriate containers for reclaiming or disposal.
Appearance & Odor White crystalline powder; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved chemical landfill or contract with a licensed waste
% by Volume
(Method Used) Not applicable. NA -------- --------
disposal agency.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use any media suitable for extinguishing supporting fire.
Media
None should be required in normal laboratory use. If dusty conditions prevail
Respiration Protection
use an approved (NIOSH) respirator or work in ventilation hood.
(Specify Type)
SPECIAL FIREFIGHTING
Local Exhaust Special
Recommended. No.
PROCEDURES Ventilation Recommended.
Mechanical (General) Other Adequate to maintain below exposure limit.
Toxic antimony fumes may be released in a fire involving this product.
Wear a NIOSH-approved self-contained breathing apparatus and full Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
protective clothing.
Other Protective
Goggles, lab coat or apron, ventilation hood, proper gloves, eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 53)
Precautions to be Taken Store and handle in a manner which avoids or controls dusting. Do
UNUSUAL FIRE AND in Handling & Storing not put in aluminum or zinc containers; See Section VI above.
EXPLOSION HAZARDS
Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
May be hazardous when heated to a melt or vapor state, as may occur
Chemical Manufacture鈥檚 label 鈥淧OISON鈥?. Do not breathe dust.
in a fire condition. Moderate fire hazard, in the form of dust or vapor,
Use with adequate ventilation. Avoid contact with skin and eyes.
when exposed to heat or flame.
Remove and wash contaminated clothing before reuse.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 3 6/2/95 Michael Raszeja MR
Coordinator
D.O.T. ANTIMONY POTASSIUM TARTRATE, 6.1, UN 1551, PG III The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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