SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET BB 30
Threshold Limited Value TWA: 0.5 mg/m3 as Barium (ACGIH, 1992-93). U.S. H.E.W. Toxic Substance
ALDON 1533 W.Henrietta Rd.
List (1976) gives; orl-hmn TDLo: 80 mg/Kg. ; orl-rat LDLO: 335 mg/Kg.
BB 30
Avon, New York 14414 MSDS No.
庐
CORPORATION June 16, 1995
Effective Date
(716) 226-6177 HARMFUL OR FATAL IF SWALLOWED. Oral intake may cause weakness,
Effects of Overexposure
salivation and nausea, followed by vomiting and diarrhea. Patient may
become cold and experience varying degrees of paralysis. INHALATION:
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE May be harmful, with symptoms similar to those of oral intake. Observe
allowable limits. EYES AND SKIN CONTACT: Not usually severe, but may
Product BARIUM CHLORIDE
CHEMTREC cause irritation to sensitive individuals.
0 3
Health
800-424-9300
Chemical
Emergency and
Barium Chloride; Barium Dichloride 3 1 FIRST AID: INGESTION: If swallowed, if conscious, give one or two
Synonyms Fire 0
Day 716-226-6177 glasses of water to drink and induce vomiting. Repeat until vomit fluid is
First Aid Procedures
(a) BaCI2 (b) BaCI 2鈥?2H2O
Formula clear. Call physician immediately. Never give anything by mouth to an
Reactivity 0
NFPA unconscious person. EYES: Flush thoroughly with water for at least 15
HAZARD RATING HMIS *
up to 2.5 Kg.
Unit Size minutes, lifting upper and lower eyelids occasionally. Get medical attention.
LEAST SLIGHT MODERATE HIGH EXTREME
SKIN: Flush with water, then wash with mild soap and water.
0 1 2 3 4
(a) 10361-37-2 (b) 10326-27-9
C.A.S. No. INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Call a physician.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Excessive temperature and heat.
Barium Chloride 100% See Section V.
Stable X
Incompatibility
Bromine Trifluoride and 2-Furan percarboxylic acid, violent reaction.
(Materials to Avoid)
DANGER! POISON. MAY BE FATAL IF SWALLOWED.
Hazardous Thermal decomposition or burning may produce toxic fumes of chlorine gas,
CAUSES IRRITATION. MAY BE HARMFUL IF INHALED.
Decomposition Products Hydrochloric acid and Barium oxide, Barium dust.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Transition 925掳C (1696掳F) (a) 3.856 (b) 3.1 @ 24掳C.
May Occur Will Not Occur Not Applicable.
Percent Volatile
Boiling Point (掳F) 1560掳C (2840掳F) Negligible as solid. X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. Not applicable.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 7.21 Recover for use if not contaminated. Wearing proper protective clothing
material is released or spilled and ventilation, sweep up and collect in dry state and place in a suitable
Solubility in Water 31 grams per 100 mL. water @ 32掳F (BaCI2 ). container for proper disposal. Flush spill area. Do not get into sewer or
waterways. Use U.S.B.M. approved toxic dust respirator.
Appearance & Odor Fine white crystals or powder; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Non-flammable. N/A
% by Volume
(Method Used) Dispose of in an approved chemical landfill or contract with a licensed waste disposal service.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use any media suitable for extinguishing supporting fire.
Media
None should be needed in normal laboratory handling. If dusty conditions prevail, work in
Respiration Protection
ventilation hood or wear a NIOSH/MSHA-approved dust mask or respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
A NIOSH/MSHA-approved self-contained breathing apparatus should be worn
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
for protection against barium-containing dust, mist or fumes. Wear full protective
clothing. Other Protective
Goggles, lab coat or apron, vented hood, proper gloves, eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 55)
Precautions to be Taken
UNUSUAL FIRE AND Store in a dry place, away from food products.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Do not breath dust or mist. Avoid contact with eyes, skin and
Fire or excessive heat may produce hazardous decomposition products, as dust
clothing. Use with adequate ventilation. Remove and wash
or fume.
contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 4 6/16/95 Michael Raszeja MR
Coordinator
D.O.T. Barium compounds, n.o.s., (Barium chloride), 6.1, UN 1564, PG III The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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