MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: COMMERCIAL CARE DIVISION
TRADE NAME:
SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
ID NUMBER/U.P.C.:
61-5000-5727-0 00-48011-13702-0 61-5000-9451-3 00-48011-16861-1
61-5001-0870-1 00-48011-17933-9 70-0705-4950-9 00-48011-19344-6
70-0705-5216-4 00-48011-19349-6 78-8095-4127-5 - - -
CN-1006-4843-1 - - - XN-1015-1365-5 - - -
ISSUED: February 06, 2001
SUPERSEDES: January 21, 1998
DOCUMENT: 11-2032-8
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1. INGREDIENT C.A.S. NO. PERCENT
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WATER................................... 7732-18-5 > 90
2-BUTOXYETHANOL......................... 111-76-2 3 - 7
ETHANOLAMINE............................ 141-43-5 1 - 5
ETHOXYLATED ALCOHOLS.................... 68439-45-2 0.5 - 1.5
ETHOXYLATED SECONDARY ALCOHOLS.......... 84133-50-6 0.5 - 1.5
POTASSIUM HYDROXIDE..................... 1310-58-3 < 1
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
2-BUTOXYETHANOL
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2. PHYSICAL DATA
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BOILING POINT:................. ca. 212 F
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. N/D
EVAPORATION RATE:.............. ca. 1 Water=1
SOLUBILITY IN WATER:........... complete
SPECIFIC GRAVITY:.............. ca. 1 Water=1
PERCENT VOLATILE:.............. ca. 95 % by wt
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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pH:............................ 12.4 - 13.8
VISCOSITY:..................... < 100 centipoise
MELTING POINT:................. N/A
APPEARANCE AND ODOR:
Liquid, clear; essentially colorless; mild solvent odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... N/A
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Not applicable
UNUSUAL FIRE AND EXPLOSION HAZARDS:
No unusual fire or explosion hazards are anticipated. See Hazardous
Decomposition section for products of combustion.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 0 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Not applicable.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Contain spill.
Evacuate unprotected personnel from hazard area. Dilute in a large
excess of water. Carefully, and with stirring, add appropriate dilute
acid such as sulfamic acid or vinegar. Confirm neutrality. Collect
spilled material. Clean up residue with water. Place in a
polyethylene-lined metal container. Do not seal for 48 hours.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: ca. 6 %.
VOC Less H2O & Exempt Solvents: ca. 6 %.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D002
(Corrosive)
TSCA: All components used in the manufacture of this material are in
compliance with the US TSCA inventory.
USDA: approved for use in inedible and nonprocessing areas (USDA
Code C1)
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact.
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Use with adequate dilution
ventilation.
RESPIRATORY PROTECTION:
Avoid breathing of vapors.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Keep container closed when not in use. Keep out of the reach of
children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
HMIS HAZARD RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
PERSONAL PROTECTION: X (See precautions, section 7.)
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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WATER................................ NONE NONE NONE NONE
2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y
2-BUTOXYETHANOL...................... 25 PPM TWA OSHAV Y
OSHA VACATED PEL
2-BUTOXYETHANOL...................... 50 PPM TWA OSHA Y
ETHANOLAMINE......................... 3 PPM TWA ACGIH
ETHANOLAMINE......................... 6 PPM STEL ACGIH
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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ETHANOLAMINE......................... 3 PPM TWA OSHA
ETHANOLAMINE......................... 6 PPM STEL OSHA
ETHANOLAMINE......................... 6 MG/M3 TWA OSHA
ETHOXYLATED ALCOHOLS................. NONE NONE NONE NONE
ETHOXYLATED SECONDARY ALCOHOLS....... NONE NONE NONE NONE
POTASSIUM HYDROXIDE.................. 2 MG/M3 CEIL ACGIH
POTASSIUM HYDROXIDE.................. 2 MG/M3 CEIL OSHA
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Moderate Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, itching, and dryness.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Lung Inflammation: Product contains surfactants which have been shown
in animal studies to cause lung inflammation resulting from prolonged
skin contact. Signs/symptoms can include coughing and shortness of
breath.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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INHALATION:
Single overexposure, above recommended guidelines, may cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include
soreness of the nose and throat, coughing and sneezing.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
Aspiration Pneumonitis: signs/symptoms can include coughing,
difficulty breathing, wheezing, coughing up blood and pneumonia,
which can be fatal.
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SECTION CHANGE DATES
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INGREDIENTS SECTION CHANGED SINCE January 21, 1998 ISSUE
PRECAUTIONARY INFO. SECTION CHANGED SINCE January 21, 1998 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SHARPSHOOTER brand EXTRA STRENGTH NO RINSE CLEANER
February 06, 2001 PAGE 7
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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