MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 1998, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: COMMERCIAL CARE DIVISION
TRADE NAME:
3M Brand TROUBLE SHOOTER CLEANER
ID NUMBER/U.P.C.:
61-5000-0313-4 00-48011-08109-0 61-5000-6131-4 00-48011-14001-8
96-0000-0066-9 - - - FZ-0100-0465-8 - - -
FZ-0100-0466-6 - - -
ISSUED: February 27, 1998
SUPERSEDES: December 18, 1996
DOCUMENT: 10-2818-2
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1. INGREDIENT C.A.S. NO. PERCENT
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WATER................................... 7732-18-5 60 - 90
2-BUTOXYETHANOL......................... 111-76-2 10 - 30
ISOBUTANE............................... 75-28-5 5 - 10
ETHANOLAMINE............................ 141-43-5 1 - 5
PROPANE................................. 74-98-6 1 - 5
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
2-BUTOXYETHANOL
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2. PHYSICAL DATA
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BOILING POINT:................. ca. 212 F
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. N/D
EVAPORATION RATE:.............. N/D
SOLUBILITY IN WATER:........... complete
SPECIFIC GRAVITY:.............. 0.999 Water=1
PERCENT VOLATILE:.............. ca. 98 %
pH:............................ ca. 11.8
VISCOSITY:..................... N/D
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Brand TROUBLE SHOOTER CLEANER
February 27, 1998 PAGE 2
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2. PHYSICAL DATA (continued)
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MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Aerosol, liquid, foamy, viscous, white, bland odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... 196 F TCC
Above for liquid; propellant < 0 F
FLAMMABLE LIMITS - LEL:........ N/D
FLAMMABLE LIMITS - UEL:........ N/D
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Water may not effectively extinguish fire; however, it should be used
to keep fire-exposed containers and surfaces cool and prevent
explosive rupture.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 2 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Brand TROUBLE SHOOTER CLEANER
February 27, 1998 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Collect spilled material. Clean up residue with
water. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Flush spent solutions and small quantities (less than 5 gal.(19 L))
to a wastewater treatment system. Reduce discharge rate if foaming
occurs. Incinerate in a permitted hazardous waste incinerator in the
presence of a combustible material. Do not puncture or burn cans in
a household incinerator. Facility must be capable of handling
aerosol cans. Dispose of empty cans in a sanitary landfill.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: ca. 275 gms/liter South Coast Air Quality Mgmt
Dist Method Rule 443.1, calculated.
VOC Less H2O & Exempt Solvents: N/D.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
All chemicals used in the manufacture of this material are listed on
the following chemical inventories: TSCA
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Brand TROUBLE SHOOTER CLEANER
February 27, 1998 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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IF SWALLOWED:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact.
When direct skin contact is likely, wear a pair of gloves. Gloves
made from the following materials are recommended: butyl rubber,
nitrile rubber.
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep out
of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Keep away
from heat, sparks, open flame, and other sources of ignition. Do not
pierce or burn container, even after use.
HMIS HAZARD RATINGS: HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: 0
PERSONAL PROTECTION: X (See precautions, section 7.)
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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WATER................................ NONE NONE NONE NONE
2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y
2-BUTOXYETHANOL...................... 25 PPM TWA OSHA Y
ISOBUTANE............................ NONE NONE NONE NONE
ETHANOLAMINE......................... 3 PPM TWA ACGIH
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Brand TROUBLE SHOOTER CLEANER
February 27, 1998 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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ETHANOLAMINE......................... 6 PPM STEL ACGIH
ETHANOLAMINE......................... 3 PPM TWA OSHA
ETHANOLAMINE......................... 6 PPM STEL OSHA
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. NONE NONE NONE ACGIH
Simple asphyxiant
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation: signs/symptoms can include redness, swelling,
and itching.
Prolonged or repeated exposure may cause:
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
Single overexposure, above recommended guidelines, may cause:
Irritation (upper respiratory): signs/symptoms can include
soreness of the nose and throat, coughing and sneezing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Single overexposure, above recommended guidelines, may cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Brand TROUBLE SHOOTER CLEANER
February 27, 1998 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
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SECTION CHANGE DATES
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HEADING SECTION CHANGED SINCE December 18, 1996 ISSUE
INGREDIENTS SECTION CHANGED SINCE December 18, 1996 ISSUE
FIRE AND EXPL. SECTION CHANGED SINCE December 18, 1996 ISSUE
ENVIRONMENTAL INFO. SECTION CHANGED SINCE December 18, 1996 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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