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MSDS Material Safety Data Sheet
CAS

9003-53-6

File Name: basf_com---expandable_polystyrene_product_safety_summary.asp
Product Safety Summary

Styropor Expandable Polystyrene
This Product Safety Summary is intended to provide a general overview of the chemical
substance. The information on the Summary is basic information and is not intended to provide
emergency response information, medical information or treatment information. The summary
should not be used to provide in-depth safety and health information. In-depth safety and health
information can be found on the Material Safety Data Sheet (MSDS) for the chemical substance.


Chemical Identity
Abbreviation: EPS

CAS Number: 9003-53-6

Common Names: Expandable polystyrene
Polystyrene
Ethylbenzene, homopolymer


Product Overview
鈥? Styropor expandable polystyrene is sold as white spherical beads which are treated with
steam and molded into foams.
鈥? Foams made of polystyrene are used for making insulation panels, flotation devices and
packaging materials.
鈥? BASF does not make polystyrene for use in food contact applications.
鈥? Styropor EPS contains small amounts of pentane, which allow it to be foamed, and a
flame retardant.
鈥? The primary potential hazards associated with polystyrene occur when making foam.
Because it contains pentane, which is flammable, care must be taken to avoid ignition.
鈥? The Occupational Safety and Health Administration has established a Permissible
Exposure Limit of 1000 ppm as an 8 hour average for pentane. The American
Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV)
is 600 ppm for 8 hours.
鈥? For further safety and health information, request the current Material Safety Data Sheet
(MSDS) for this substance.
鈥? Use of hot wires cutters by processors to cut foam may result in the release of potentially
toxic smoke and vapors.


Physical/Chemical Properties
鈥? Low pentane Styropor Expandable Polystyrene is about 95% polystyrene, 3.5 鈥? 3.8%
pentane and less than 1% flame retardant.
鈥? It is sold as white spherical beads, but, consumers encounter it as white molded objects,
such as insulation block and packaging material for electronics.
鈥? The beads have a density of 1.02-1.05, close to that of water.
鈥? Styropor EPS dissolves in organic solvents, such as toluene.
鈥? The beads contain about 4% pentane, which is flammable. Therefore, it is important to
avoid sources of ignition when handling industrially. Foam made from the material does
not pose a flammability concern.




Date: November 30, 2007 Page: 1 of 3
Health Information
Acute Hazards
Styropor EPS beads and articles made from them are essentially non-toxic. Processing the
beads may cause the release of pentane, which can cause irritation and central nervous system
effects at high airborne concentrations.

Effects on Respiratory System:
Products made from EPS do not present any hazards to consumers. Industrial processing may
result in potential exposure to pentane. The effects of overexposure to very high levels of
pentane vapors include eye and respiratory irritation and central nervous system effects, such as
unconsciousness.

Effects on Eyes:
EPS and its products are not irritating to the eyes. In industrial situations, pentane vapors may
cause irritation if they are not controlled.

Effects on Skin:
EPS and its products are not irritating to the skin. In industrial situations, hot molten material may
cause thermal burns.

Effects on Ingestion:
Accidental ingestion is not expected to result in injury. To avoid choking hazards, children should
not be allowed to eat molded products.

Chronic Hazards
No chronic hazards related to EPS or its products have been reported.


Environmental Information
Spills should be swept up and discarded. EPS can be disposed of as non-hazardous waste.


Additional Hazard Information
Styropor EPS should be stored and handled away from sources of flame, sparks and electrostatic
charges.

The following safety recommendations must be observed:
鈥? Specify proper electrical equipment and adequate grounding for static electricity.
鈥? Maintain a dust-free workplace and avoid generating dusts during handling.
鈥? Maintain adequate ventilation in all work areas to control to vapors.
鈥? Provide adequate firefighting equipment, including automatic sprinklers, in work and
storage areas.


Exposure Potential
Consumer exposure to expandable polystyrene is limited to products molded from EPS beads.
As a result, exposure to dusts and pentane vapors are minimal and will not be hazardous




Date: November 30, 2007 Page: 2 of 3
Workplace exposure to pentane vapors must be limited through the use of engineering controls,
such as ventilation and hoods. In general, skin and eye exposures are prevented through the use
of protective eye and face equipment and impermeable gloves and clothing.


Risk Management
Workers handling Styropor EPS beads can safely work with this material if adequately instructed
and educated regarding proper handling procedures.

Workers should be trained to understand the potential fire hazards of working with pentane and
materials that may release dusts.

Ventilation must be available in work areas to control potential airborne pentane exposures to
acceptable levels.


Federal/Science/Other Findings
Operation Clean Sweep
http://www.opcleansweep.org/

National Institutes of Health Household Products Database
http://hpd.nlm.nih.gov/cgi-bin/household/search?queryx=9003-53-
6&tbl=TblChemicals&prodcat=all


Contact Information
http://www.basf.com

MSDS
http://worldaccount.basf.com/wa/PublicMSDS~en_US/Search

Technical Information
http://www.basf.com/businesses/plasticportal/pp_home_en.html

References

Technical Leaflet S-2BFL: Styropor庐 expandable polystyrene BF Product Series, BASF
Corporation, September 2005


IMPORTANT: While the data and information contained herein are presented in good faith
and believed to be accurate, it is provided for your guidance only. No warranties of any
kind, either express or implied, are made regarding the data or information provided.
Further, it is expressly understood that the data and information furnished by BASF
hereunder are given gratis and BASF assumes no obligation or liability for the data and
information given, all such data and information being given and accepted at your risk.




Date: November 30, 2007 Page: 3 of 3

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