Material Safety Data Sheet U.S. Department of Labor
Occupational Safety and Health Administration
May be used to comply with OSHA鈥檚 Hazard Communication
(Non-Mandatory Form) Form Approved
Standard, 29 CFR 1910.1200. Standard must be consulted for
OMB No. 1218-0072
specific requirements.
Identity as Used on Label: CITRUS II 256:1 GERMICIDAL CONCENTRATE
Health = 3 Flammability = 1 Reactivity = 0
SECTION I
Beaumont Products, Inc. (800) 255-3924
Manufacturer Name: Emergency Telephone Number:
1560 Big Shanty Rd. (770) 514-9000
Manufacturer鈥檚 Address: Telephone Number for Info:
Kennesaw, GA 30144
USA Date Prepared: November 2, 2006
SECTION II 鈥? Ingredients
APPROXIMATE TWA/TLV
WEIGHT %
N,N-Didecyl-N,N-dimethylammonium chloride 10.14 None established
(CAS No. 7173-51-5)
N-Alkyl (C12-16)-N,N-dimethyl-N-benzylammonium chloride 6.76 None established
(CAS No. 8001-54-5)
N,N-Dimethyl-l-octylamine-N-oxide 3.2 None established
(CAS No. 2605-78-9)
Ethylenediaminetetraacetic acid 3.0 None established
(CAS No. 60-00-4)
Ethanol (CAS No. 64-17-5) 3.2 1000 ppm (OSHA-PEL)
1000 ppm (ACGIH-TWA)
Water (CAS No. 7732-18-5) 73.70 None established
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SECTION III 鈥? Physical/Chemical Characteristics
Not known 1.0
Boiling Point: Specific Gravity (H2O = 1):
Vapor Pressure (mmHg): Not known Melting Point: Not known
Vapor Density (Air = 1): Not known Evaporation Rate (Butyl Acetate = 1): Not known
SOLUBLE 7.2 - 8.2
Solubility in Water: pH:
77.9
Percent Volatile (by weight):
Clear Liquid (color depends upon optional dye added), odor varies with fragrance
Appearance and Odor:
added (if any)
SECTION IV 鈥? Fire and Explosion Hazard Data
>200藲F
Flash Point:
N/A LEL: N/A UEL: N/A
Flammable Limits:
FOAM, CO2, DRY CHEMICAL, WATER
Extinguishing Media:
Products of combustion are toxic.
Unusual Fire and Explosion Hazards:
Must wear NIOSH approved self-contained breathing
Special Fire Fighting Procedures:
apparatus and protective clothing. Cool fire-exposed
containers with water spray.
SECTION V 鈥? Reactivity Hazard Data
Stability: Stable
Conditions to avoid: None known
Incompatibility (materials to avoid): Strong oxidizing or reducing agents.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition of By-Products: Thermal decomposition may product toxic vapors/fumes
of hydrogen chloride, amines, and other organic
materials, and oxides of carbon and nitrogen.
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SECTION VI 鈥? Health Hazard Data
Skin: YES Eye: YES Inhalation: YES
Route(s) of Entry:
Effects of Overexposure: Based on information available for similar products, it is anticipated that direct
contact will produce severe eye and skin irritation and/or burns and possible
irreversible damage. Solvent vapors or mists of product can produce
irritation of the mucous membranes. Ingestion can produce immediate burning pain
in the mouth, throat, and abdomen; severe swelling of the larynx; skeletal muscle
paralysis affecting the ability to breathe; circulatory shock; and/or convulsions.
Exposure to ethyl alcohol concentrations of over 1,000 ppm may cause headache,
irritation of the eyes, nose and throat, and, if long continued, drowsiness and
lassitude, loss of appetite and inability to concentrate.
Medical Conditions Generally Aggravated by Exposure: No effects indicated.
Emergency and First Aid Procedures: Eyes 鈥? Flush eyes with large amounts of running water for at
least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of the eye and lids with water. Get
immediate medical attention. If physician not available, flush for additional 15 minutes and then transport
victim to medical care.
Skin: Wash with large amounts of running water, and soap if available, for 15 minutes. Remove
contaminated clothing and shoes. Get immediate medical attention. Wash clothing and decontaminate shoes
before reuse.
If ingested: If swallowed, immediate give 3-4 glasses of milk (if unavailable, give water). DO NOT induce
vomiting. If vomiting occurs, give fluids again. Get immediate medical attention. Have physician determine
if patient鈥檚 condition allows for induction of vomiting or evacuation of stomach. Do not give anything by
mouth to a convulsing or unconscious person.
If inhaled: Remove from area to fresh air. If not breathing, clear airway and start artificial respiration. If
victim is having trouble breathing, give supplemental oxygen, if available. Get immediate medical attention.
Note to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. Supplemental
oxygen and other measures to support breathing may be needed to combat circulatory shock. Persistent
convulsions may be controlled by the cautious intravenous injection of a short acting barbiturate drug.
SECTION VII 鈥? Precautions for Safe Handling and Use
Steps to be taken in case material is released or spilled: DANGER! Corrosive liquid. Wear appropriate
protective gear and respiratory protection where mist or vapors of unknown concentrations may be generated
(self-contained breathing apparatus preferred).
Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid and solid separately to
containers for recovery or disposal. Keep spill out of sewers and open bodies of water.
Waste Disposal Methods: Dispose of in compliance with all Federal, state and local laws and regulations.
Incineration is the preferred method.
Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and
dispose of in a sanitary landfill, or incineration, or, if allowed by state and local authorities, by burning. If
burned, stay out of smoke.
Precautions to be taken in handling and storing: Store at temperatures below 140藲F. Keep containers closed until
used. Do not contaminate drinking water, food, or feed by storage or disposal.
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SECTION VIII 鈥? Control Measures
In processes where mists or vapors may be generated, a
Respiratory Protection:
NIOSH/MSHA jointly approved respirator is advised in
the absence of proper environmental controls.
In processed where mists or vapors may be generated,
Ventilation:
proper ventilation must be provided in accordance with
good ventilation practices.
Rubber or neoprene, to prevent skin contact.
Protective Gloves:
Wear chemical splash goggles where there is a potential
Eye Protection:
for eye contact. Use safety glasses with side shields where
there is no potential for eye contact.
Eye wash; safety shower; protective clothing (long sleeves,
Other Protective Clothing or Equipment:
coveralls or other, as appropriate), to prevent skin contact.
SECTION IX 鈥? Toxicology Information
No toxicity information is available for this product. The information provided below is for a closely related alkaline
formulation containing 10.8% active quat:
ACUTE
- oral LD (rat): 1650 mg/kg
- dermal LD (rabbit): 1870 mg/kg
- eye irritation (rabbit): Severe irritant
- skin irritation (rabbit): Severe irritant
- skin corrosivity (DOT method): Corrosive
SECTION X 鈥? Miscellaneous and Regulatory Information
FEDERAL LEVEL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS:
All components in this product are listed on the US EPA TSCA 8(b) inventory
TSCA Section 12(b) Export Notification
Components present in this product which, if exported, could require either annual or one-time
reporting under this regulation are as follows:
Chemical Name CAS Number Typical Maximum
Concentration
None known
US EPA Regulation on Pesticides:
This is an EPA registered pesticide (EPA Registration No. 47371-129-68939). This material can only
be used commercially in the EPA registered application(s) noted on the product label.
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Miscellaneous and Regulatory Information -Continued
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of 1980) requires
notification of the National Response Center (Telephone 800-424-8802) in the event of a release of quantities of the
following hazardous materials contained in this product, if the release is equal to or greater than the Reportable
Quantities (RQs) listed in 40 CFR 302.4:
Chemical Name CAS Number Typical Maximum
Concentration
None known
SARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of 1986) 鈥? This act requires
emergency planning, including agency notification, for possible release of the following components of this material,
based upon the Threshold Planning Quantities (TPQs) and release Reportable Quantities (RQs) listed for the
Components in 40 CFR 355:
Chemical Name CAS Number Typical Maximum
Concentration
None known
SARA Title III Sections 311/312 鈥? This act requires reporting under the Community Right-to-Know provisions due
to the inclusion of the following components of this material in on e of more of the five hazard categories listed in 40
CFR 370:
Chemical Name CAS Number Hazard*)
Categories
N,N-Didecyl-N,N-dimethylammonium chloride 7173-51-5 A
N-Alkyl (C12-16)-N,N-dimethyl-N-benzylammonium chloride 8001-54-5 A
N,N-Dimethyl-l-octylamine-N-oxide 2605-78-9 A
Ethanol 64-17-5 F
*) The five hazard categories are as follows: F=FIRE HAZARD; S=SUDDEN RELEASE OF PRESSURE;
R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC) HEALTH
HAZARD
SARA Title III Section 313 鈥? This act requires submission of annual reports off the releases of the following
components of this material if the threshold reporting quantities as listed in 40 CFR 372, are met or exceeded:
Chemical Name CAS Number Typical Maximum
Concentration
None known
STATE RIGHT-TO-KNOW REGULATIONS:
CALIFORNIA PROPOSITION 65 鈥? Components present in this material which the State of California has found to
cause cancer, birth defects, or other reproductive harm are as follows:
Typical Maximum
AS A CANCER HAZARD
Chemical Name CAS Number Concentration
Acetaldehyde 75-07-0 300 ppb
Benzene 71-43-2 15 ppm
Benzyl chloride 100-44-7 30 ppm
N-Nitrosodimethylamine 62-75-9 160 ppb
Propylene oxide 75-56-9 3 ppm
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Miscellaneous and Regulatory Information -Continued
CALIFORNIA PROPOSITION 65 鈥? Components present in this material which the State of California has found to
cause cancer, birth defects, or other reproductive harm are as follows:
AS A REPRODUCTIVE HAZARD
Typical Maximum
Chemical Name CAS Number Concentration
Benzene 71-43-2 15 ppm
Toluene 108-88-3 15 ppm
MASSACHUSETTS Right-to-Know - The following components of this material are included in the Massachusetts
Substance List and are present at or above reportable levels:
Typical Maximum
Chemical Name CAS Number Concentration
Acetaldehyde 75-07-0 300 ppb
Benzene 71-43-2 15 ppm
Benzyl chloride 100-44-7 30 ppm
Ethanol 64-17-5 3.1%
Hydrogen peroxide 7722-84-1 30 ppm
Propylene oxide 75-56-9 3 ppm
MICHIGAN Critical Materials - The following components of this material are included in the Michigan Critical
Materials List:
Chemical Name CAS Number
None known
NEW JERSEY Right-to-Know - The following components of this material are included in the New Jersey
Hazardous Substance List and are present at or above reportable levels:
Typical Maximum
Chemical Name CAS Number Concentration
N,N-Didecyl-N,N-dimethylammonium chloride 7173-51-5 10.56%
N-Alkyl (C12-16)-N,N-dimethyl-N-benzylammonium chloride 8001-54-5 6.33%
Ethanol 64-17-5 3.2%
PENNSYLVANIA Right-to-Know - The following components of this material are included in the Pennsylvania
Hazardous Substance List and are present at or above reportable levels:
Typical Maximum
Chemical Name CAS Number Concentration
Ethanol 64-17-5 3.2%
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