MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
1 of 7
Page
1 PRODUCT AND COMPANY IDENTIFICATION
Wilsonart庐 121 Adhesive Cleaner
Common Name
MANUFACTURER WILSONART INTERNATIONAL, INC.
P.O. BOX 6110 - 2400 WILSON PLACE
TEMPLE, TX 76503
INFORMATION PHONE: 800-433-3222 (USA)
Trade Name WA 121 adhesive cleaner
MATERIAL USES Cleaning solvent for laminates.
Revision # 17
IN CASE OF EMERGENCY CONTACT
CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
2 HAZARDS IDENTIFICATION
Route of Entry: Skin, eyes, and respiratory tract.
Target Organs: Chronic overexposure may effect the central nervous system, kidneys, and/or liver or cause
irregular heartbeat. May cause peripheral nervous system effects.
Inhalation: Inhalation vapors may cause dizziness, light-headedness, nausea, headache, loss of
consciousness and death. Can be fatal if inhaled or ingested. May cause Central nervous system
depression and peripheral neuropathy (numbness in limbs) .
Skin Contact: May cause skin irritation. Prolonged exposure may result in dermatitis with dryed or cracked skin.
Permeator (absorbed through the skin).
Eye Contact: May cause eye irritation.
Ingestion: Not an expected route of entry. Ingestion may cause nausea, vomiting, dizziness, and
gastrointestinal irritation.
DANGER!
FLAMMABLE LIQUD AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL OR FATAL IF SWALLOWED.
HARMFUL IF INHALED. USE ONLY WITH ADEQUATE VENTILATION.
HMIS (United States): NFPA (United States):
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
2 of 7
Page
*See Section 11.
WHMIS (Canada): B2, D2A.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS# % by Weight
Light Hydrotreated 68410-97-9 65 - 100
Distillate
n-Hexane 110-54-3 1.5% max.
n-Pentane 109-66-0 23% max.
Cyclohexane 110-82-7 7.5% max.
4 FIRST AID MEASURES
Inhalation: Remove patient to fresh air. If patient is having difficulty breathing seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use
bag-mask respirator). Get immediate medical attention.
Skin Contact: Wash affected areas with soap and water. Remove contaminated clothing. If irritation develops,
seek medical attention.
Eye Contact: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush. Seek medical
attention.
Ingestion: Give patient 3 - 4 glasses of water. DO NOT induce vomiting. Get immediate medical attention.
DO NOT give anything by mouth to an unconscious person.
Note to physician:
Sudden death due to ventricular fibrillation has been reported from acute inhalation in chronic solvent abusers. Treat
patient supportively. Life support measures should be provided because CNS depression, cardiopulmonary failure,
and metabolic acidosis have been reported in massive overexposures.
5 FIRE FIGHTING MEASURES
Flash Point: -16.7 掳C (2.0 掳F)
Flash Point Method: CLOSED CUP
Autoignition Temperature: Lowest known value is 225 掳C (437 掳F, for n-Hexane).
LEL: 1%
UEL: 8%
Flammability Classification: Flammable
General Hazard:
Flammable liquid, insoluble in water.
Highly flammable in presence of open flames and sparks. Flammable in the presence of heat and/or oxidizing materials.
Risks of explosion of the product in the presence of mechanical impact is not available.
Risks of explosion of the product in the presence of static discharge: Static discharge may serve as an ignition source to
closed containers of product.
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
3 of 7
Page
For small spill: use dry chemicals, CO2, or alcohol foam.
For large spill: use dry chemicals, CO2, or foam. Cool containing vessels with water jet in order to prevent pressure build-up,
autoignition or explosion.
Firefighting equipment:
Use self contained breathing apparatus with a full face piece and pressure-demand or other positive-pressure mode.
Special Remarks:
Container explosion may occur under fire conditions or when heated.
All electrical equipment in the area must be rated for flammable liquids (Dispensing - Class I, Division 1; Storage - Class 1,
Division 2). Ground all containers of this material.
Hazardous products of combustion include carbon oxides (CO, CO2).
6 ACCIDENTAL RELEASE MEASURES
Small Spill and Leak: Absorb with an inert material and place in an appropriate waste disposal container.
Large Spill and Leak: Flammable liquid insoluble in water. Eliminate all ignition sources. Stop leak if without risk.
Prevent entry into sewers, basements or confined areas; dike if needed. Absorb with an inert material and put the
spilled material in an appropriate waste diposal container. Do not use metal tools or equipment.
7 HANDLING AND STORAGE
Handling Precautions: To avoid fire or explosion, dissipate static electricity during transfer by bonding and
grounding containers and equipment before transferring material. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Avoid breathing vapors.
Handle in well ventilated areas. After handling always wash hands thoroughly with soap
and water. Avoid contact with skin or eyes. When using do not drink or smoke.
Storage Requirements: Flammable materials should be stored in a separate safety cabinet or room. Store and use
away from heat, sparks, open flame, or any other ignition source. Keep in a cool, well
ventilated area. Ground all equipment containing material. Keep out of reach of children.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Provide exhaust ventilation or other engineering controls to keep the airborne
Engineering Controls:
concentrations of vapors below their respective threshold limit value. Ensure that a
working eyewash and safety shower are in the work area.
Protective Equipment: Wear splash goggles or safety glasses with side shields, synthetic apron, and
neoprene or rubber gloves. In case of insufficient ventilation, wear an approved
(NIOSH) repirator with organic vapor cartridges with dust/mist pre-filter.
Exposure Guidelines/Other: Product Name Exposure Limits
Light hydrotreated ACGIH (TWA): 500 ppm, NIOSH 350 mg/m3
distillate
n-Hexane ACGIH (TWA): 50 ppm
OSHA (TWA): 500 ppm
n-Pentane ACGIH (TWA): 600 ppm,
OSHA (TWA): 1000 ppm
NIOSH (TWA): 120 ppm, 610 ppm CL
Cyclohexane ACGIH (TWA): 100 ppm
OSHA/NIOSH (TWA): 300 ppm
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
4 of 7
Page
Consult local authorities and local regulations for exposure limits.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid.
Physical State: Liquid. Boiling Point: 80 掳C (176 掳F)
Odor: Solvent-like. Freezing/Melting Pt.: May start to solidify at -95 掳C
(-139 掳F) based on
n-Hexane.
pH: Not available. Solubility: Insoluble in water.
Vapor Pressure: 150.1 mm of Hg (@20掳C) Spec Grav./Density: 5.8 lbs./gal.
Vapor Density: 2.97 (Air=1, n-Hexane).
VOC: 5.85 lbs/gal (702 g/L), VHAP Content: 0.09 lbs./gal. (10 g/L)
Molecular Weight: Not applicable
Viscosity: Not available.
Percent Volatile: 100%
Molecular Formula: Not applicable.
10 STABILITY AND REACTIVITY
Stability: This product is stable when used as intended.
Conditions to avoid: Avoid heat sources, open flames, and sparks.
Materials to avoid (incompatability): Reactive with acids, alkalis, combustable materials, oxidizing agents, reducing
agents.
Hazardous Decomposition products: Products of combustion include carbon oxides (CO, CO2).
Hazardous Polymerization: Will not occur.
11 TOXICOLOGICAL INFORMATION
Toxicity to Animals: Acute oral toxicity (LD50) 8.0 ml/kg (rat). (Cyclohexane). Anesthetic to mice at 7% concentration in 10 min. (n-
pentane), Inhalation 40% dose resulted in death of mice (n-pentane). Inhalation 15,000 ppm fatal within 70 min. (mice).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Not classifiable for human or animal.
MUTAGENIC EFFECTS: Classified none for human.
TERATOGENIC EFFECTS: Not classifiable for human or animal.
DEVELOPMENTAL TOXICITY: Causes damage to the following organs: kidneys, liver, central nervous system (CNS). N-hexane is a
neurotoxin.
Other Toxic Effects on Humans: No additional information.
Special Remarks on Toxicity to Animals: No additional remark.
Special Remarks on Chronic Effects on Humans: No additional information.
Special Remarks on Other Toxic Effects on Humans: Persons with pre-existing skin disorders may be more susceptible to the
effects of solvents.
12 ECOLOGICAL INFORMATION
Ecotoxicity Not available
BOD5 and COD Not available
Biodegradable/OECD Not available
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
5 of 7
Page
Toxicity of the Products of
Biodegradation Not available
Special Remarks on the
Products of Biodegradation No additional remark
13 DISPOSAL CONSIDERATIONS
Spilled, contaminated, or waste material should be put into a suitable container and handled according to local,
state,/provincial, and federal regulations. Contact a qualified waste management company in your area for assistance. Empty
containers should be either reconditioned by CERTIFIED firms or properly disposed of by approved firms. Disposal of
containers should be in accordance with applicable laws and regulations. "Empty" drums should not be given to individuals.
Serious accidents have resulted from the misuse of "emptied" containers. Residual vapors in the containers may be
explosive. Do not cut, weld, or braze these containers.
Dispose of in accordance with Federal, State, and local regulations.
14 TRANSPORT INFORMATION
DOT Classification: Class 3: Flammable liquid. Flammable liquid, n.o.s. (contains pentane, cyclohexane), 3, UN1993, II,
Limited Quantity: 1 L
ADR/RID Classification -- Class 3: Flammable liquid A.
IMO/IMDG Classification -- Class 3: Flammable liquid.
ICAO/IATA Classification -- Class 3: Flammable liquid.
15 REGULATORY INFORMATION
U.S. Federal Regulations
OSHA (29 CFR 1910.1200) - Hazardous.
CERCLA Reportable quantity (Rq) values:
n-Hexane 5000 lbs.
Cyclohexane 1000 lbs.
TSCA inventory: cyclohexane, n-pentane, n-hexane, light hydrotreated distillate.
SARA 302/304/311/312 extremely hazardous substances: none.
SARA 302/304 emergency planning and notification: none.
SARA 302/304/311/312 hazardous chemicals: none.
SARA 311/312 MSDS distribution, chemical inventory: none.
SARA 313 toxic chemical notification and release reporting: cyclohexane, n-pentane, n-hexane.
CWA 307: None.
CWA 311: None.
CAA 112 accidental release prevention: n-pentane.
CAA 112 regulated flammable substances: n-pentane.
CAA 112 regulated toxic substances: n-pentane.
International Regulations
EINECS - The chemicals in this product are listed.
DSL - cyclohexane, n-pentane, n-hexane, light hydrotreated distillate.
WHIMS - B2, D2A
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
6 of 7
Page
State Regulations
Pennsylvania RTK: cyclohexane, n-pentane, n-hexane.
New Jersey RTK: cyclohexane, n-pentane, n-hexane.
Massachusetts RTK: cyclohexane, n-pentane, n-hexane.
California Prop. 65: None.
16 OTHER INFORMATION
References
Lewis, R. J., Rapid Guide to Hazardous Chemicals in the Workplace, 4th ed., Wiley-Interscience, New York, 2000.
NIOSH Pocket Guide to Chemical Hazards, Department of Health and Human Services, National Institute for
Occupational Safety and Health, 2004.
Patty's Toxicology, John Wiley & Sons, Inc., New York, 2001
TLVs and BEIs, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure
Agents, ACGI Worldwide, Cincinnati, 2003.
Glossary
ACGIH - American Conference of Governmental Industrial Hygienists
ASTM - American Society for Testing and Materials
ADR - Agreement on Dangerous Goods by Road (Europe)
BOD5 - Biological Oxygen Demand in 5 days
CAA - Clean Air Act
CAS - Chemical Abstracts Services
CEPA - Canadian Environmental Protection Act
CERCLA - Comprehensive Environmental Response, Compensations and Liability Act
CFR - Code of Federal Regulations
CWA - Clean Water Act
DOT - Department of Transportation
DSCL - Dangerous Substances Classification and Labeling (Europe)
DSL - Domestic Substance List (Canada)
EEC/EU - European Economic Community/European Union
EINECS - European Inventory of Existing Commercial Chemical Substances
HCS - Hazard Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
LD50/LC50 - Lethal Dose/Concentration kill 50%
LDLo/LCLo - Lowest Published Lethal Dose/Concentration
NFPA - National Fire Prevention Association
NIOSH - National Institute for Occupational Safety & Health
NTP - National Toxicology Program
OSHA - Occupational Safety & Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation and Recovery Act
SARA - Superfund Amendments and Reorganization Act
STEL - Short Term Exposure Limit (15 minutes)
TDG - Transportation of Dangerous Goods (Canada)
TLV-TWA - Threshold Limit Value-Time Weighted Average
TSCA - Toxic Substances Control Act
WHMIS - Workplace Hazardous Material Information System
MSDS Material Safety Data Sheet
Wilsonart International
Wilsonart庐 121 Adhesive Cleaner
MSDS Number: 16376 Revision Date: 1/3/2008
7 of 7
Page
CHEMTREC:
800-424-9300 (USA)
703-527-3887 (International)
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
END OF MSDS DOCUMENT
|