Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
Lokweld(R) 3001 Adhesive
Common Name Mexico MSDS 17263
Code
17263
MSDS#
Ralph Wilson Plastics Company
Supplier
P.O. Box 6110 - 2400 Wilson Place Validation Date 05/30/2000
Temple, TX 76503-6110
Telephone: 254-207-7000 or 800-433-3222
05/30/2000
Print Date
Also known as: LW 3001
Synonym
Responsible Name Ralph Wilson Plastics
Lokweld(R)3001Adhesive
Trade name
Company
Spray grade adhesive for laminate.
Material Uses
In Case of CHEMTREC:
Emergency 800-424-9300 (USA)
Ralph Wilson Plastics Company
Manufacturer 703-527-3887 (International)
P.O. Box 6110 - 2400 Wilson Place
Temple, TX 76503-6110
Telephone: 254-207-7000 or 800-433-3222
Section 2. Composition and Information on Ingredients
CAS #
Name % by Weight Exposure Limits
STEL: 20 (mg/m3) ACGIH (TLV)
Residual Vinyl acetate monomer 108-05-4 <0.5
TWA: 10 (ppm) ACGIH (TLV)
TWA: 35 (mg/m3) ACGIH STEL: 70 (mg/m3) ACGIH
Plasticizer Proprietary 5 - 15 Not available.
Proprietary Polymer Proprietary 15 - 40 Not available
Vinyl acetate homopolymer 9003-20-7 5 - 15 Not available.
Section 3. Hazards Identification
Liquid.
Physical State and
Appearance
Emergency Overview
EYE CONTACT MAY PRODUCE MILD IRRITATION. INHALATION MAY IRRITATE RESPIRATORY
TRACT.
Inhalation. Eye contact. Skin contact. Ingestion.
Routes of Entry
Potential Acute Health Effects
Eyes Mildly irritating to the eyes.
Skin Non-irritating to the skin.
Inhalation May cause slight irritation of upper respiratory tract.
Ingestion Not an expected route of entry. May cause mild gastric irritation.
No additional information.
Potential Chronic Health
Effects
Repeated or prolonged exposure is not known to aggravate any medical condition.
Medical Conditions
Aggravated by Overexposure:
Inflammation of the eye is characterized by redness, watering, and itching.
Overexposure
/Signs/Symptoms
See Toxicological Information (section 11)
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Section 4. First Aid Measures
In case of contact with eyes, rinse immediately with plenty of water. If irritation occurs, seek medical
Eye Contact
attention.
Wash contaminated skin with soap and water. If irritation occurs, seek medical attention. Wash
Skin Contact
contaminated clothing before reusing.
If symptoms are present, allow the victim to rest in a well ventilated area. Oxygen may be
Inhalation
administered if breathing is difficult. If symptoms persist, seek medical attention.
Remove dentures if any. Have conscious person drink several glasses of water or milk. [NEVER give
Ingestion
an unconscious person anything to ingest.] INDUCE VOMITING by giving syrup of ipecac or by
touching back of throat with fingers. Lower the head so that the vomit will not reenter the mouth and
throat. Seek medical attention.
Notes to Physician No additional information.
Section 5. Fire Fighting Measures
Non-flammable.
Flammability of the Product
Not applicable.
Auto-ignition Temperature
Not applicable.
Flash Points
Not applicable.
Flammable Limits
carbon oxides (CO, CO2)
Products of Combustion
Not applicable.
Fire Hazards in Presence of
Various Substances
Not considered to be a product presenting risks of explosion.
Explosion Hazards in
Presence of Various
Substances
Non-flammable. Use extinguishing media suitable for surrounding materials.
Fire Fighting Media
and Instructions
Protective Clothing (Fire) Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout
gear.
Non combustible.
Special Remarks on Fire
Hazards
No additional remark.
Special Remarks on
Explosion Hazards
Section 6. Accidental Release Measures
Absorb with an inert material and place in an appropriate waste disposal container.
Small Spill and Leak
Prevent entry into sewers, basements or confined areas; dike if needed. Absorb with an inert material
Large Spill and Leak
and put the spilled material in an appropriate waste disposal.
Section 7. Handling and Storage
After handling, always wash hands thoroughly with soap and water. Avoid breathing vapors of this
Handling
product. Avoid contact with eyes.
Do not freeze. Keep out of the reach of children Keep container tightly closed in a cool, well-ventilated
Storage
place.
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Section 8. Exposure Controls/Personal Protection
Provide good general ventilation or other engineering controls to keep the airborne concentrations of
Engineering Controls
vapors below their respective threshold limit value.
Personal Protection
Eyes Safety glass with side shields or splash goggles.
Body No special precautions are necessary if used as intended.
Respiratory A respirator is not needed under normal and intended conditions of product use. In case of insufficient
ventilation, wear an approved (NIOSH) respirator with organic vapor cartridges with dust/mist pre-filter.
Hands No special precautions are necessary if used as intended.
Feet No special precautions are necessary if used as intended.
Protective Clothing
(Pictograms)
Personal Protection in Case of In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic vapor cartridges.
Splash goggles. Boots. Full suit. Neoprene or latex gloves.
a Large Spill
Exposure Limits
Product Name
STEL: 20 (mg/m3) ACGIH (TLV)
residual vinyl acetate monomer
TWA: 10 (ppm) ACGIH (TLV)
TWA: 35 (mg/m3) ACGIH STEL: 70 (mg/m3) ACGIH
Not available.
Proprietary NJTSRN 950003
Not available
Proprietary NJTSRN 950002
Not available.
Vinyl acetate homopolymer
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Liquid.
Physical State and Mild, polyvinyl acetate odor.
Odor
Appearance
Taste Not available.
Not applicable.
Molecular Weight
Green.
Color
Not applicable.
Molecular Formula
5 [Acidic.]
pH (1% Soln/Water)
The lowest known value is 100掳C (212掳F) (Water). Weighted average: 129.05掳C (264.3掳F)
Boiling/Condensation Point
May start to solidify at 4.1掳C (39.4掳F) based on data for: Plasticizer.
Melting/Freezing Point
Not available.
Critical Temperature
1.1 (Water = 1)
Specific Gravity
Vapor Pressure The highest known value is 17.535 mm of Hg (@ 20掳C) (Water).
7.52 (Air = 1) based on data for: plasticizer
Vapor Density
42%
Volatility
Not available.
Odor Threshold
Not available.
Evaporation Rate
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< 20 g/L
VOC
2850 cps (Brookfield Viscometer)
Viscosity
The product is more soluble in water.
LogKow
Not available.
Ionicity (in Water)
Dispersion Properties Not available.
Soluble in water.
Solubility
Physical Chemical Comments No additional information.
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Not available.
Conditions of Instability
Incompatibility with Various Avoid contact with oxidizing agents, acids and alkalies.
Substances
Products of combustion include: carbon oxides (CO, CO2)
Hazardous Decomposition
Products
Will not occur.
Hazardous Polymerization
Section 11. Toxicological Information
Mildly irritating to the eyes. May cause slight irritation of upper respiratory tract.
Toxicity to Animals
No additional information.
Chronic Effects on Humans
No additional information.
Other Toxic Effects on
Humans
Special Remarks on Toxicity No additional remark.
to Animals
Special Remarks on Chronic This product may contain small amounts of vinyl acetate, vapors of which have been shown to cause
Effects on Humans tumors in the respiratory tract of laboratory animals. There is no evidence that is has caused cancer in
humans.
Vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans)
classification, it has also been listed in Category 2B.
No additional information.
Special Remarks on Other
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Not available.
Biodegradable/OECD
Not available.
Mobility
Not available.
Toxicity of the Products of
Biodegradation
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No additional remark.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Spilled, contaminated, or waste material should be put into a suitable container and handled according
Waste Information
to local, state/provincial, and federal regulations.
Not available.
Waste Stream
Consult your local or regional authorities.
Section 14. Transport Information
Not a DOT controlled material (United States).
DOT Classification
Not a marine pollutant.
Marine Pollutant
No additional remark.
Special Provisions for
Transport
Not controlled under ADR (Europe).
ADR/RID Classification
Not controlled under IMDG.
IMO/IMDG Classification
Not controlled under IATA.
ICAO/IATA Classification
Section 15. Regulatory Information
May cause mild eye irritation. May cause slight irritation of upper respiratory tract.
HCS Classification
TSCA 8(b) Inventory: All ingredients are listed.
U.S. Federal Regulations
SARA 302/304/311/312 Extremely Hazardous Substances: No products were found.
SARA 302/304 Emergency Planning and Notification: No products were found.
SARA 302/304/311/312 Hazardous Chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean water act (CWA) 307: No products were found.
Clean water act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
International Regulations
Not available.
EINECS
R36/38- Irritating to eyes and skin.
DSCL (EEC)
No products were found.
International Lists
State Regulations No products were found.
California Prop. 65: This product contains the following ingredients known to the State of California to
cause cancer: Formaldehyde (50-00-0) in trace amounts, Acetaldehyde (75-07-0).
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Section 16. Other Information
EYE CONTACT MAY PRODUCE MILD IRRITATION. INHALATION MAY IRRITATE RESPIRATORY
Label Requirements
TRACT.
Hazardous Material * 1 National Fire
Health
Fire Hazard
0
Information System 0 Protection
Fire Hazard
1 0
(U.S.A.) Association (U.S.A.) Health Reactivity
0
Reactivity
Specific Hazard
B
Personal Protection
-SAX, N.I. Dangerous Properties of Industrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984.
References
-Patty's Industrial Hygiene and Toxicology
-Manufacturer's Material Safety Data Sheet.
GLOSSARY:
ACGIH - American Conference of Governmental Industrial Hygienists
ASTM - American Society for Testing and Materials
ADR - Agreement on Dangerous Goods by Road (Europe)
BOD5 - Biological Oxygen Demand in 5 days
CAS - Chemical Abstract Services
CEPA - Canadian Environmental Protection Act
CERCLA - Comprehensive Environmental Response, Compensation and Liability Act
CFR - Code of Federal Regulations
DOT - Department of Transportation
DSCL - Dangerous Substances Classification and Labeling (Europe)
DSL - Domestic Substance List (Canada)
EEC/EU - European Economic Community/European Union
EINECS - European Inventory of Existing Commercial Chemical Substances
HCS - Hazard Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
LD50/LC50 - Lethal Dose/Concentration kill 50%
LDLo/LCLo - Lowest Published Lethal Dose/Concentration
NFPA - National Fire Prevention Association
NIOSH - National Institute for Occupational Safety & Health
NTP - National Toxicology Program
OSHA - Occupational Safety & Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation and Recovery Act
SARA - Superfund Amendments and Reorganization Act
STEL - Short Term Exposure Limit (15 minutes)
TDG - Transportation of Dangerous Goods (Canada)
TLV-TWA - Threshold Limit Value-Time Weighted Average
TSCA - Toxic Substances Control Act
WHMIS - Workplace Hazardous Material Information System
Other Special No additional remark.
Considerations
Validated by Ralph Wilson Plastics Company on 05/30/2000. Verified by Ralph Wilson Plastics Company.
Printed 05/30/2000.
CHEMTREC:
800-424-9300 (USA)
703-527-3887 (International)
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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