MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 1 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
1 PRODUCT AND COMPANY IDENTIFICATION
Common Name WILSONART庐 3301 Adhesive
MANUFACTURER WILSONART INTERNATIONAL
P.O. BOX 6110 - 2400 WILSON PLACE
TEMPLE, TX 76503
INFORMATION PHONE: 800-433-3222 (USA)
Trade Name WA 3301 Adhesive or Lokweld 3301 Adhesive
MATERIAL USES Adhesive for laminate
Revision # 19
In Case of Emergency Contact:
CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
2 COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS# % by Weight
Ethylene glycol 107-21-1 1-5
Toluene 108-88-3 0.5 - 1.5
Vinyl acetate polymers N/A 40 - 70
Aromatic diester NJTSRN 950001 5 - 10
RN#4457*
*See Section 15 for Canadian HMIRC Registry Number exemptions.
3 HAZARDS IDENTIFICATION
Route of Entry: Skin, eyes, and respiratory tract.
Target Organs: None.
Inhalation: Breathing vapors may cause irritation to the respiratory tract. Breathing large amounts of vapor may
cause dizziness, irregular heartbeat, narxosis, nausea, or asphyxiation (toluene).
Skin Contact: May cause skin irritation.
Eye Contact: May cause eye irritation
Ingestion: Not an expected route of entry. If ingested it may cause irritation to gastro-intestinal tract.
MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 2 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
HMIS (United States): NFPA (United States):
WHMIS (Canada): D2A, D2B
4 FIRST AID MEASURES
Inhalation: Remove patient to fresh air. If patient is having difficulty breathing seek immediate medical attention. If
victim is not breathing, trained personnel should clear airway and start mouth-to-mouth artificial respiration
(or use bag-mask respirator). If victim's heart has stopped, trained personnel should be begin
cardiopulmonary resuscitation (CPR) immediately. Get immediate medical attention.
Skin Contact: Wash affected areas with soap and water. If irritation develops seek medical attention.
Eye Contact: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush. Seek medical attention.
Ingestion: DO NOT induce vomiting. Get immediate medical attention. DO NOT give anything by mouth to an
unconscious person. If vomiting occurs naturally, have victim lean forward to reduce aspiration risk.
5 FIRE FIGHTING MEASURES
Flash Point: Not Available for product. 240 F (116 C) for ingredients.
Flash Point Method: Closed Cup.
Autoignition Temperature: 775 F (413 C) for ingredients.
LEL: 3.2% for ingredients.
UEL: 15.3% for ingredients.
Material is not flammable. Dry adhesive will burn.
In case of fire use dry chemical or CO2 extinguishing media.
Use extinguishing media appropriate for surrounding materials.
Wear self contained breathing apparatus and protective gear.
Hazardous decomposition products include carbon oxides (CO, CO2) and acetic acid.
6 ACCIDENTAL RELEASE MEASURES
Personal precautions:
MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 3 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
Wear appropriate PPE. Make sure work area is well ventilated. Spilled adhesive may be slippery.
Environmental precautions:
Keep out of sewers or drains.
Clean-up methods
Dike and contain spill. Absorb spilled product with vermiculite, dry sand, or earth. Dispose in a suitable container.
7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Handle in well ventilated areas. Wash hands after handling with soap
and water.
Storage Requirements: Avoid freezing temperatures. Minimize contact with atmospheric air to prevent inoculation with
microorganisms.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Use in a well ventilated area.
Protective Equipment: Wear approved safety glasses with side shields. Wear latex gloves.
Wear normal work clothing. Ensure a functioning eye wash is either in or near the work area.
Exposure Guidelines/Other: Product Name Exposure Limits
Toluene Inhalation LC50 = 5100 ppm (female rat, 4 hour, vapor)
OSHA PEL: 200 ppm; ACGIH TWA: 50 ppm (skin)
300 ppm CL; 500 ppm 10 min. max.
Vinyl acetate monomer OSHA PEL:10 ppm; ACGIH TWA:10 ppm
STEL 20 ppm STEL 15 ppm
ACGIH TLV: 100 mg/m3 Ceiling (aerosol)
Ethylene glycol
OSHA PEL: 5 mg/m3; ACGIH TLV: 5 mg/m3
Aromatic diester
NJTSRN 950001 (RN#4457*)
*See Section 15 for Canadian HMIRC Registry Number exemptions.
Consult local authorities and local regulations for exposure limits.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White mobile liquid.
Physical State: Liquid. Boiling Point: 212 F (100 C)
Odor: Mild sweet. Freezing/Melting Pt.: 7.7 F (-13.5 C)
pH: 5-6 Solubility: Soluble.
Vapor Pressure: Equivalent to water. Spec Grav./Density: 1.058
Vapor Density: Equivalent to water.
VOC: < 20g/L
Viscosity: Not Available.
10 STABILITY AND REACTIVITY
Stability: Stable as supplied. Coagulation may occur following freezing/thaw cycle or boiling.
MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 4 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
Conditions to avoid: Extreme temperatures.
Materials to avoid (incompatability): Copper and copper alloys, strong acids, and alkalies.
Hazardous Decomposition products: Carbon oxides (CO2, CO) and acetic acid.
Hazardous Polymerization: Will not polymerize.
11 TOXICOLOGICAL INFORMATION
Toluene
Chronic ingestion of toluene has been shown to cause altered immune functions in laboratory animals. Chronic inhalation of
toluene has been shown to cause hearing loss in laboratory animals. Toluene has been shown to be a moderate skin irritant
in laboratory animals. Acute inhalation of toluene has been shown to cause CNS and neurobehavioral effects in humans.
Chronic inhalation of toluene has been shown to cause neurotoxic effects and color vision loss in humans. Toluene is
potentiated by acetylsalicylic acid and n-hexane to produce irreversible auditory damage in laboratory animals.
Ethylene glycol
Chronic ingestion of ethylene glycol has been shown to cause adverse effects on the kidney, bone marrow, and sperm in
laboratory animals. Ethylene glycol has been shown to be teratogen in laboratory animals.
Aromatic diester (NJTSRN 950001, RN#4457*)
Chronic ingestion of an ingredient in this product has been shown to cause tumors in laboratory animals. An ingredient in this
product has been shown to be a reproductive toxin in laboratory animals.
*See Section 15 for Canadian HMIRC Registry Number exemptions.
12 ECOLOGICAL INFORMATION
Ecotoxicity Not available.
BOD5 and COD Not available.
Biodegradable/OECD Not available.
Mobility Not available.
Toxicity of the Not available.
Products of
Biodegradation
Special Remarks on the No additional remark.
Products of Biodegradation
13 DISPOSAL CONSIDERATIONS
Dispose of in accordance with Federal, State, and local regulations.
14 TRANSPORT INFORMATION
DOT Classification - Resin Compound - Not DOT Regulated//Keep from freezing
Proper Shipping Name - Adhesive Resin Compound
Markings - None
Packaging instructions - Keep from freezing
Marine Pollutant - NO
MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 5 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
TDG hazard class - None
15 REGULATORY INFORMATION
U.S. Federal Regulations
CERCLA Rq
Toluene 1000 lbs.
Ethylene Glycol 5000 lbs.
TSCA inventory: The chemicals in this product are listed.
SARA 302/304/311/312 extremely hazardous substances: None.
SARA 302/304 emergency planning and notification: None.
SARA 302/304/311/312 hazardous chemicals: Toluene.
SARA 311/312 MSDS distribution, chemical inventory, hazard identification: None.
SARA 313 toxic chemical notification and release reporting: Toluene, ethylene glycol.
CWA 307: Toluene.
CWA 311: Toluene.
CAA 112 accidental release prevention: None.
CAA 112 regulated flammable substances: None.
CAA 112 regulated toxic substances: None.
International Regulations
EINECS - Chemicals are listed.
DSL - R36/37 - irritating to eyes and respiratory system.
WHIMS - D2A, D2B.
HMIRC Registry Number 4457 was granted an exemption dated January 26, 2005 by the Canadian Hazardous
Materials Information Review Commission.
State Regulations
Pennsylvania RTK: Toluene, NJTSRN 950001.
Minnesota RTK: Toluene.
Massachusetts RTK: NJTSRN 950001.
New Jersey RTK: Toluene, NJTSRN 950001.
Rhode Island RTK: Toluene.
California Prop. 65:
Warning. This product may contain trace amounts of vinyl acetate monomer, acetaldehyde and formaldehyde,
chemicals known to the State of California to cause cancer or reproductive toxicity.
Warning. This product contains toluene known to the State of California to cause reproductive toxicity.
16 OTHER INFORMATION
References
Lewis, R. J., Rapid Guide to Hazardous Chemicals in the Workplace, 4th ed., Wiley-Interscience, New York, 2000.
NIOSH Pocket Guide to Chemical Hazards, Department of Health and Human Services, National Institute for
Occupational Safety and Health, 2004.
TLVs and BEIs, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure
Agents, ACGI Worldwide, Cincinnati, 2003.
Glossary
MSDS Material Safety Data Sheet
Wilsonart International
WILSONART庐 3301 Adhesive 6 6
Page of
MSDS Number: 16392 Revision Date: 7/6/2005
ACGIH - American Conference of Governmental Industrial Hygienists
ASTM - American Society for Testing and Materials
ADR - Agreement on Dangerous Goods by Road (Europe)
BOD5 - Biological Oxygen Demand in 5 days
CAA - Clean Air Act
CAS - Chemical Abstracts Services
CEPA - Canadian Environmental Protection Act
CERCLA - Comprehensive Environmental Response, Compensations and Liability Act
CFR - Code of Federal Regulations
CWA - Clean Water Act
DOT - Department of Transportation
DSCL - Dangerous Substances Classification and Labeling (Europe)
DSL - Domestic Substance List (Canada)
EEC/EU - European Economic Community/European Union
EINECS - European Inventory of Existing Commercial Chemical Substances
HCS - Hazard Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
LD50/LC50 - Lethal Dose/Concentration kill 50%
LDLo/LCLo - Lowest Published Lethal Dose/Concentration
NFPA - National Fire Prevention Association
NIOSH - National Institute for Occupational Safety & Health
NTP - National Toxicology Program
OSHA - Occupational Safety & Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation and Recovery Act
SARA - Superfund Amendments and Reorganization Act
STEL - Short Term Exposure Limit (15 minutes)
TDG - Transportation of Dangerous Goods (Canada)
TLV-TWA - Threshold Limit Value-Time Weighted Average
TSCA - Toxic Substances Control Act
WHMIS - Workplace Hazardous Material Information System
CHEMTREC:
800-424-9300 (USA)
703-527-3887 (International)
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
END OF MSDS DOCUMENT
|