Material Safety Data Sheet
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Section 1. Product Identification and Uses
Wilsonart(R) 110 Solvent
Product Name PIN: UN1993
CI#
PG (Canada) TDG: II
Lokweld(R) 110 Solvent DSL
Also known as: All ingredients are listed.
Synonym
Not applicable. Mixture.
Chemical Name CAS #
Code
Not applicable. 17018
Chemical Formula
Solvent. Not applicable.
Chemical Family Molecular Weight
WILSONART INTERNATIONAL INC. WILSONART INTERNATIONAL, INC.
Supplier Manufacturer
P.O. BOX 6110, Temple, TX 76503-6110
P.O. BOX 6110 - 2400 Wilson Place, Temple, TX 76503
Information Phone: 254-207-7000 or 800-433-3222
Telephone: 800-433-3222 (USA) or 254-207-7000
solvent for adhesives
Material Uses
Section 2. Hazardous Ingredients
Name CAS # % by LC50/LD50
Weight
Toluene 108-88-3 15-40 ORAL (LD50): Acute: 2600 mg/kg [Rat]. 5000 mg/kg [Rat].
DERMAL (LD50): Acute: 12210 mg/kg [Rabbit]. VAPOR
(LC50): Acute: 8000 ppm 4 hour(s) [Rat]. 7523.6 ppm 4
hour(s) [Mouse].
Acetone 67-64-1 15-40 ORAL (LD50): Acute: 3000 mg/kg [Mouse]. 5340 mg/kg
[Rabbit]. 5800 mg/kg [Rat]. DERMAL (LD50): Acute:
20000 mg/kg [Rabbit]. VAPOR (LC50): Acute: 29826.7
ppm 4 hour(s) [Rat]. 16000 ppm 4 hour(s) [Rat].
Hexane isomers N/A 40-60 ORAL (LD50): Acute: 32400 mg/kg [Rat]. 28710 mg/kg
[Rat].
N-hexane 110-54-3 1-5 ORAL (LD50): Acute: 32400 mg/kg [Rat]. 28710 mg/kg
[Rat].
Section 3. Physical Data
Liquid.
Physical State and Solvent-like. (Slight.)
Odor
Appearance
Not available.
Taste
Not available.
pH (1% Soln/Water)
Clear Colorless.
Color
The highest known value is 13 ppm (Acetone)
Odor Threshold
Weighted average: 8.5 ppm
V.O.C.'s: 6.1 lbs/gal; 727 g/Liter less water & exempt solvent.
Volatility
MAXIMUM VOC: 528 g/Liter (SCAQMD)
HAP CONTENT: 57.03 mm/Hg composite partial pressure
The highest known value is 7.7 (Acetone) Weighted average: 5.34compared to Butyl acetate.
Evaporation Rate
May start to solidify at -94.5掳C (-138.1掳F) based on data for: Toluene. Weighted average: -94.98掳C (-139掳F)
Melting Point
55.556掳C (132掳F)
Boiling Point
0.733 (Water = 1)
Specific Gravity
The highest known value is 3.14 (Air = 1) (Toluene). Weighted average: 2.73 (Air = 1)
Vapor Density
185 mm of Hg (@ 20掳C)
Vapor Pressure
Not available.
LogKow
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Not available.
Ionicity (Surface Active
Agent)
The lowest known value is 234.2掳C (453.6掳F) (Hexane isomers).
Critical Temperature
The lowest known value is 220掳C (428掳F) (Acetone).
Instability Temperature
Keep away from sources of ignition.
Conditions of Instability
Dispersion Properties Not available.
Insoluble in water.
Solubility
Section 4. Fire and Explosion Data
Flammable.
The Product is:
The lowest known value is 225掳C (437掳F) (Hexane isomers).
Auto-ignition
Temperature
These products are carbon oxides (CO, CO2).
Products of Combustion
CLOSED CUP: -14.444掳C (6掳F). (Pensky-Martens.)
Flash Points
LOWER: 2% UPPER: 13%
Flammable Limits
Flammable liquid, insoluble in water.
Extinguishing Media
SMALL SPILL: Use DRY chemicals, CO2, alcohol foam or water spray.
LARGE SPILL: Use DRY chemicals, CO2, water spray or foam. Cool containing vessels with water jet in order to
prevent pressure build-up, autoignition or explosion.
Extremely flammable in presence of open flames and sparks.
Flammability of the
Highly flammable in presence of heat.
Product
Slightly flammable to flammable in presence of oxidizing materials, of reducing materials, of combustible materials.
Non-flammable in presence of moisture.
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of Explosion
Risks of explosion of the product in presence of static discharge: Not available.
Slightly explosive to explosive in presence of oxidizing materials.
Section 5. Reactivity
The product is stable.
Stability
Products of Combustion include: carbon oxides (CO, CO2)
Hazardous Decomposition
Products
Not available.
Degradability
Products of Degradation Not available.
Non-corrosive in presence of glass.
Corrosivity
Reactive with oxidizing agents, reducing agents, organic materials, acids, alkalis.
Reactivity
The lowest known value is 220掳C (428掳F) (Acetone).
Instability Temperature
Keep away from sources of ignition.
Conditions of Instability
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Section 6. Toxicological Properties
Absorbed through skin. Skin contact. Eye contact. Inhalation. Ingestion.
Routes of Entry
Toluene
TLV
TWA: 100 STEL: 150 (ppm) from OSHA (PEL)
TWA: 50 (ppm) from ACGIH (TLV)
STEL: 150 (ppm) from NIOSH
Acetone
Australia: TWA: 500 STEL: 1000 (ppm) [1997]
USA: TWA: 750 STEL: 1000 CEIL: 1000 (ppm) from ACGIH (TLV) [1989]
Germany: TWA: 500 (ppm) from DFG MAK
UK: TWA: 1000 STEL: 1250 (ppm) [1989]
Hexane isomers
TWA: 1760 CEIL: 3500 (mg/m3) from ACGIH (TLV)
TWA: 500 STEL: 1000 (ppm) from ACGIH (TLV)
TWA: 200 (ppm) from DFG MAKs
N-hexane
TWA: 176 (mg/m3) from ACGIH (TLV)
TWA: 50 (ppm) from ACGIH (TLV)
TWA: 200 (ppm) from DFG MAKs
Consult local authorities for acceptable exposure limits.
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.
Toxicity to Animals
Acute oral toxicity (LD50): 2600 mg/kg [Rat]. (Toluene).
Acute dermal toxicity (LD50): 12210 mg/kg [Rabbit]. (Toluene).
Acute toxicity of the vapor (LC50): 7523.6 ppm 4 hour(s) [Mouse]. (Toluene).
This product may irritate eyes and skin upon contact. Inflammation of the eye is characterized by redness, watering,
Acute Effects on
and itching. Skin inflammation is characterized by itching, scaling, reddening. Permeator (absorbed through the
Humans
intact skin). Inhalation of the vapors may cause dizziness, nausea, or anaesthetic effects. Central nervous system
depression.
Repeated or prolonged exposure to the substance can produce target organs damage. The substance is toxic to
Chronic Effects on
blood, kidneys, liver, lungs, the nervous system, respiratory system. Long term skin contact to solvents may
Humans
produce defatting of the skin and dermatitis. Irritating to eyes and skin.
Not available.
Synergetic Products
(Toxicologically)
Very hazardous in case of eye contact (irritant).
Skin
Hazardous in case of skin contact (irritant).
Irritation/Corrosivity
No additional information.
Sensitization
CARCINOGENIC EFFECTS: None. by NTP, ACGIH, IARC
Carcinogenic Effects
Toxicity to DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Toluene].
Reproductive System
TERATOGENIC EFFECTS: Classified PROVEN for human [Toluene].
Teratogenic Effects
Mutagenic Effects NO mutagenic effect.
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Section 7. Preventive Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal container.
Small Spill and Leak
In case of insufficient ventilation, wear an approved (NIOSH) respirator
Personal Protective
with organic vapor cartridges. Splash goggles. Gloves (neoprene or
Equipment
rubber). Synthetic apron.
Flammable liquid, insoluble in water.
Large Spill and Leak
Eliminate all ignition sources. Stop leak if without risk. Absorb with an inert material and put the spilled material in
an appropriate waste disposal container. Do not use metal tools or equipment. Prevent entry into sewers, basements
or confined areas; dike if needed.
In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic vapor cartridges. Splash goggles.
Protective Clothing
Gloves (neoprene or rubber). Safety glasses. Boots. Full suit.
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
Engineering Controls
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.
Keep away from incompatibles such as alkalis, acids, oxidizing agents, reducing agents. Keep away from sources of
Precautions
ignition. Use only in well-ventilated areas. Avoid contact with skin and eyes. Avoid breathing vapors or spray mists.
Keep out of the reach of children
Store in a dry, cool and well ventilated area. Flammable materials should be stored in a separate safety storage
Storage
cabinet or room. A refrigerated room would be preferable for materials with a flash point lower than 37.8掳C (100掳F).
Ground all equipment containing material. Keep out of the reach of children.
Avoid breathing vapors or spray mists. Avoid contact with skin and eyes. After handling, always wash hands
Handling
thoroughly with soap and water. Keep away from sources of ignition. Ground all equipment containing material. Do
not use in presence of electrostatic discharges. Store and use away from heat, sparks, open flame, or any other
ignition source.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to local,
Waste Disposal
state/provincial, and federal regulations. Contact a qualified waste management company in your area for assistance.
EMPTY CONTAINERS: Empty containers should be either reconditioned by CERTIFIED firms or properly disposed of
by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations.
"Empty" drums should not be given to individuals. Serious accidents have resulted from the misuse of "emptied"
containers.
No additional information.
Special Shipping
Information
Section 8. First Aid Measures
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping
Eye Contact
eyelids open. Seek medical attention.
Wash contaminated skin with soap and water. If the product got onto the clothed portion of the body, remove the
Skin Contact
contaminated clothes as quickly as possible. Place the victim under a deluge shower. If irritation occurs, seek
medical attention. Wash contaminated clothing before reusing.
Allow the victim to rest in a well ventilated area. Oxygen may be administered if breathing is difficult. If irritation
Slight Inhalation
persists, seek medical attention.
Do not induce vomiting. Have conscious person drink several glasses of water or milk. NEVER give an unconscious
Slight Ingestion
person anything to ingest. Seek medical attention.
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Section 9. MSDS Preparation
-SAX, N.I. Dangerous Properties of Industrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984.
References
GLOSSARY:
ACGIH - American Conference of Governmental Industrial Hygienists
ASTM - American Society for Testing and Materials
ADR - Agreement on Dangerous Goods by Road (Europe)
BOD5 - Biological Oxygen Demand in 5 days
CAS - Chemical Abstract Services
CEPA - Canadian Environmental Protection Act
CERCLA - Comprehensive Environmental Response, Compensation and Liability Act
CFR - Code of Federal Regulations
DOT - Department of Transportation
DSCL - Dangerous Substances Classification and Labeling (Europe)
DSL - Domestic Substance List (Canada)
EEC/EU - European Economic Community/European Union
EINECS - European Inventory of Existing Commercial Chemical Substances
HCS - Hazard Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
LD50/LC50 - Lethal Dose/Concentration kill 50%
LDLo/LCLo - Lowest Published Lethal Dose/Concentration
NFPA - National Fire Prevention Association
NIOSH - National Institute for Occupational Safety & Health
NTP - National Toxicology Program
OSHA - Occupational Safety & Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation and Recovery Act
SARA - Superfund Amendments and Reorganization Act
STEL - Short Term Exposure Limit (15 minutes)
TDG - Transportation of Dangerous Goods (Canada)
TLV-TWA - Threshold Limit Value-Time Weighted Average
TSCA - Toxic Substances Control Act
WHMIS - Workplace Hazardous Material Information System
TSCA (Toxic Substance Control Act): All components of this product are listed on the TSCA Inventory.
EINECS: All components of this product are on the European Inventory of Existing Commercial Chemical Substances.
Validated by Wilsonart International Inc. on 01/06/2000. Verified by Wilsonart International Inc..
Printed 01/06/2000.
CHEMTREC:
800-424-9300 (USA)
703-527-3887 (International)
Contact Person: Emil Studinka
Responsible
Regulatory Services
Name /
Telephone No.: 254-207-7000
Classification
Class 3: Flammable liquid.
TDG Road /
Rail
Shipping name: Flammable liquids n.o.s. UNNA: UN1993 PG: II
WHMIS WHMIS Class B-2: Flammable liquid with a flash point lower than 37.8掳C (100掳F). WHMIS Class D-2B: Material causing
other toxic effects (TOXIC).
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To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards
that exist.
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