MSDS Material SafetyCompanySheet
Data
Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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1 PRODUCT AND COMPANY IDENTIFICATION
110 Adhesive Solvent
Common Name
MANUFACTURER RALPH WILSON PLASTICS COMPANY
P.O. BOX 6110 - 2400 WILSON PLACE
TEMPLE, TX 76503
INFORMATION PHONE: 800-433-3222 (USA)
Trade Name 110 adhesive solvent
MATERIAL USES Cleaning solvent for laminates.
Revision # 1
IN CASE OF EMERGENCY CONTACT
CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
2 HAZARDS IDENTIFICATION
Route of Entry: Absorbed through skin. Skin contact. Eye contact. Inhalation. Ingestion.
Target Organs: None.
Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Narcotic effect; may cause
nervous system disturbances. Peripheral neuropathy (numbness in limbs). Central nervous system
depression. Severe over-exposure can result in death.
Skin Contact: May cause skin irritation. Permeator (absorbed through intact skin).
Eye Contact: May cause eye irritation.
Ingestion: Ingestion may cause severe gastric disturbances.
Emergency Overview
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF INHALED OR
SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
Use only with adequate ventilation.
Potential Chronic Health Effects: May cause irritation of respiratory tract, coughing, shortness of breath. Exposure to high
concentrations can cause dizziness, lightheadness, headache, nausea, and blurrred vision. Higher levels may cause
unconsciousness. Long term skin contact to solvents may produce defatting of the skin and dermatitis. Repeated or
prolonged inhalation of vapors may lead to chronic respiratory irritation. Severe over-exposure can produce lung damage,
choking, unconsciousness or death.
Medical Conditions Aggravated by Overexposure: Pre-existing eye and skin disorders.
Overexposure/Signs/Symptoms: Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening.
See Toxicological Information (section 11)
MSDS Material SafetyCompanySheet
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Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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HMIS (United States): NFPA (United States):
*See Section 11
WHMIS (Canada): B2, D2
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS# % by Weight
Light hydrotreated 68410-97-9 30 - 50
distillate
n-Hexane 110-54-3 1.5% max.
n-Pentane 109-66-0 23% max.
Cyclohexane 110-82-7 7.5% max.
Acetone 67-64-1 15 - 40
Toluene 108-88-3 15 - 40
4 FIRST AID MEASURES
Inhalation: Remove victim to a well ventilated area. Seek immediate medical attention.
Skin Contact: Wash contaminated skin with soap and water. If the product is absorbed into clothing, remove
clothing from the body as quickly as possible. Place the victim under a deluge shower. Wash
contaminated clothing before reusing. If irritation occurs, seek medical attention.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least
15 minutes, keeping eyelids open. Seek medical attention.
Ingestion: DO NOT induce vomiting. Aspiration into the lungs may cause chemical pneumonitis. Have
conscious person drink several glasses of water or milk. NEVER give an unconcious person
something to drink. Seek immediate medical attention.
Notes to Physician: Sudden death due to ventricular fibrillation has been reported from acute inhalation in chronic
MSDS Material SafetyCompanySheet
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Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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solvent abusers. Treat patient supportively. Life support measures should be provided because CNS depression
cardiopulmonary failure, and metabolic acidosis have been reported in massive overexposures.
5 FIRE FIGHTING MEASURES
Flash Point: -14.7掳C (5.5 掳F)
Flash Point Method: CLOSED CUP
Autoignition Temperature: The lowest known value is 225掳C (437掳F).
LEL: 2%
UEL: 13%
Flammability Classification: Flammable.
Hazardous decomposition products of combustion include carbon oxides (CO, CO2).
Highly flammable in presence of open flames and sparks, of heat. Slightly flammable in presence of oxidizing materials, of
reducing materials, of combustible materials. Non-flammable in presence of moisture.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact:
Not available. Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive to explosive
in presence of oxidizing materials.
Fire Fighting Media and Instructions: Flammable liquid.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog.
Special Remarks on Fire Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container
explosion may occur under fire conditions or when heated. All electrical equipment in the spray area must be rated for
flammable liquids. [Dispensing - Class I, Division 1 / Storage area rated Class I, Division 2] When dispensing, bond and
ground all containers.
Special Remarks on Explosion Hazards: All electrical equipment in the spray area must be rated for flammable liquids.
[Dispensing - Class I, Division 1 / Storage area rated Class I, Division 2] When dispensing, bond and ground all containers.
Protective Clothing (Fire): Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full
turnout gear.
6 ACCIDENTAL RELEASE MEASURES
Small Spill and Leak: Absorb with an inert material and place in an appropriate waste disposal container.
Large Spill and Leak: Flammable liquid. Evacuate personnel to a safe area. Eliminate all ignition sources. Stop leak
if without risk. Ventilate area. Prevent entry into sewers, basements or confined areas; dike if needed. Absorb with
an inert material and put the spilled material in an appropriate waste disposal container. Do not use metal tools or
equipment.
7 HANDLING AND STORAGE
Handling Precautions: To avoid fire or explosion, dissipate static electricity during transfer by using proper
bonding and grounding of containers and equipment before transferring material. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. After
handling, always wash hands thoroughly with soap and water.
Storage Requirements: Flammable materials should be stored in a separate safety storage cabinet or room. Keep
away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in
a cool, well-ventilated place. Ground all equipment containing material. Keep out of reach
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Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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of children.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Provide exhaust ventilation or other engineering controls to keep the airborne
Engineering Controls:
concentrations of vapors below their respective threshold limit value. Ensure that
working eyewash station and safety shower are proximal to the work-station location.
Protective Equipment: Wear splash goggles or safety glasses with side shields. Wear synthetic apron. In
case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridges with dust/mist pre-filter. Wear appropriate gloves (Viton, nitrile, or
neoprene). No special foot wear are necessary if the product is used as intended.
Personal Protection in Case of a Large Spill: A self contained breathing apparatus
should be used to avoid inhalation of the product. Boots. Full suit. Splash goggles.
Gloves (Viton, nitrile, or neoprene).
Exposure Guidelines/Other: Product Name Exposure Limits
Light hydrotreated ACGIH (TWA): 500 ppm, NIOSH 350
mg/m3
distillate
n-Hexane ACGIH (TWA): 50 ppm
OSHA (TWA): 500 ppm
n-Pentane ACGIH (TWA): 600 ppm,
OSHA (TWA): 1000 ppm
NIOSH (TWA): 120 ppm, 610 ppm CL
Cyclohexane ACGIH (TWA): 100 ppm
OSHA/NIOSH (TWA): 300 ppm
Acetone ACGIH (TWA): 500 ppm, 750 ppm
STEL
OSHA (TWA): 1000 ppm
Toluene ACGIH (TWA): 50 ppm
OSHA (TWA): 200 ppm, 300 ppm CL
Consult local authorities and local regulations for exposure limits.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear Colorless Liquid.
Physical State: Liquid. Boiling Point: 55.556掳C (132掳F)
Odor: Strong Solvent Odor. Freezing/Melting Pt.: May start to solidify at
-94.5掳C (-138.1掳F) based on
data for: Toluene. Weighted
average: -95.02掳C (-139掳F)
pH: Not Available. Solubility: Insoluble in water.
Vapor Pressure: 185 mm of Hg (@ 20掳C) Spec Grav./Density: 6.26 lbs./gal.
Vapor Density: The highest known value is
3.14 (Air = 1) (Toluene).
Weighted average: 2.73 (Air =
1)
VOC: 6.13 lbs./gal. (735 g/Liter). VHAP: 1.52 lbs./gal. (182 g/L).
Evap. Rate: The highest known value is 7.7 (Acetone) Weighted average: 6.11compared to Butyl acetate.
MSDS Material SafetyCompanySheet
Data
Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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Molecular Weight: Not Applicable.
Viscosity: Not Available.
Percent Volatile: 100%
Molecular Formula: Not Applicable.
Composite Partial Pressure: 109 mm Hg (@ 20掳C).
10 STABILITY AND REACTIVITY
Stability: The product is stable.
Conditions to avoid: Keep away from sources of ignition.
Materials to avoid (incompatability): Reactive with oxidizing agents, reducing agents, acids, and alkalis.
Hazardous Decomposition products: Products of Combustion include carbon oxides (CO, CO2)
Hazardous Polymerization: Will not polymerize.
11 TOXICOLOGICAL INFORMATION
Toxicity to Animals: Acute oral toxicity (LD50): 2600 mg/kg [Rat]. (Toluene).
Acute dermal toxicity (LD50): 12210 mg/kg [Rabbit]. (Toluene). Acute oral toxicity (LD50) 8.0 ml/kg (rat). (Cyclohexane). Anesthetic to
mice at 7% concentration in 10 min. (n-pentane), Inhalation 40% dose resulted in death of mice (n-pentane). Inhalation 15,000 ppm fatal
within 70 min. (mice).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Not classifiable for human or animal.
MUTAGENIC EFFECTS: Classified none for human.
TERATOGENIC EFFECTS: Classified PROVEN for human [Toluene].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Toluene].
Causes damage to the following organs: kidneys, liver, central nervous system (CNS).
N-hexane is a neurotoxin. Toluene has been reported to have caused spontaneous abortion in women that intentionally concentrated and
inhaled its vapors. Toluene, cyclohexane, and n-pentane can cause CNS depression. Peripheral neuropathy (numbness in limbs).
Other Toxic Effects on Humans: No additional information.
Special Remarks on Toxicity to Animals: No additional remark.
Special Remarks on Chronic Effects on Humans: No additional information.
Special Remarks on Other Toxic Effects on Humans: Persons with pre-existing skin disorders may be more susceptible to the
effects of solvents.
12 ECOLOGICAL INFORMATION
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Biodegradable/OECD: Not available.
Mobility: Not available.
Toxicity of the Products of Biodegradation: Not available.
Special Remarks on the Products of Biodegradation: No additional remark.
13 DISPOSAL CONSIDERATIONS
Waste Information Spilled, contaminated, or waste material should be put into a suitable container and handled according to
local, state/provincial, and federal regulations. Contact a qualified waste management company in your area for assistance.
EMPTY CONTAINERS: Empty containers should be either reconditioned by CERTIFIED firms or properly disposed of by
APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. "Empty" drums
MSDS Material SafetyCompanySheet
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Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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should not be given to individuals. Serious accidents have resulted from the misuse of "emptied" containers. Residual vapors
in the container(s) may be explosive. Do not cut, weld, or braze these containers.
Waste Stream Not available.
Dispose of according to Federal, state, and local regulations.
14 TRANSPORT INFORMATION
DOT Classification: Class 3: Flammable liquid. Flammable liquids n.o.s. (contains toluene, acetone), 3, UN1993, II, Limited Quantity:
1L
Marine Pollutant: Not a marine pollutant.
Special Provisions for Transport: 1 Liter or less may use Limited Quantity exceptions (49CFR 173.150)
ADR/RID Classification: Class 3: Flammable liquid.
IMO/IMDG Classification: Class 3: Flammable liquid.
ICAO/IATA Classification: Class 3: Flammable liquid.
15 REGULATORY INFORMATION
U.S. Federal Regulations
OSHA (29 CFR 1910.1200) - Hazardous.
CERCLA Reportable quantity (Rq) values:
Acetone 5000 lbs.
n-Hexane 5000 lbs.
Cyclohexane 1000 lbs.
Toluene 1000 lbs.
TSCA inventory: acetone, toluene, cyclohexane, n-pentane, n-hexane, light hydrotreated distillate.
SARA 302/304/311/312 extremely hazardous substances: none.
SARA 302/304 emergency planning and notification: none.
SARA 302/304/311/312 hazardous chemicals: none.
SARA 311/312 MSDS distribution, chemical inventory: none.
SARA 313 toxic chemical notification and release reporting: acetone, toluene, cyclohexane, n-pentane, n-hexane.
CWA 307: None.
CWA 311: None.
CAA 112 accidental release prevention: n-pentane.
CAA 112 regulated flammable substances: n-pentane.
CAA 112 regulated toxic substances: n-pentane.
International Regulations
EINECS - The chemicals in this product are listed.
DSL - acetone, toluene, cyclohexane, n-pentane, n-hexane, light hydrotreated distillate.
WHIMS - B5, D2B
State Regulations
Pennsylvania RTK: acetone, toluene, cyclohexane, n-pentane, n-hexane.
New Jersey RTK: acetone, toluene, cyclohexane, n-pentane, n-hexane.
Massachusetts RTK: acetone, toluene, cyclohexane, n-pentane, n-hexane.
California Prop. 65: Warning. This product contains toluene that is known to the stae of California to cause
MSDS Material SafetyCompanySheet
Data
Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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reproductive toxicity.
16 OTHER INFORMATION
References
Lewis, R. J., Rapid Guide to Hazardous Chemicals in the Workplace, 4th ed., Wiley-Interscience, New York, 2000.
NIOSH Pocket Guide to Chemical Hazards, Department of Health and Human Services, National Institute for
Occupational Safety and Health, 2004.
TLVs and BEIs, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure
Agents, ACGI Worldwide, Cincinnati, 2003.
Glossary
ACGIH - American Conference of Governmental Industrial Hygienists
ASTM - American Society for Testing and Materials
ADR - Agreement on Dangerous Goods by Road (Europe)
BOD5 - Biological Oxygen Demand in 5 days
CAA - Clean Air Act
CAS - Chemical Abstracts Services
CEPA - Canadian Environmental Protection Act
CERCLA - Comprehensive Environmental Response, Compensations and Liability Act
CFR - Code of Federal Regulations
CWA - Clean Water Act
DOT - Department of Transportation
DSCL - Dangerous Substances Classification and Labeling (Europe)
DSL - Domestic Substance List (Canada)
EEC/EU - European Economic Community/European Union
EINECS - European Inventory of Existing Commercial Chemical Substances
HCS - Hazard Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
LD50/LC50 - Lethal Dose/Concentration kill 50%
LDLo/LCLo - Lowest Published Lethal Dose/Concentration
NFPA - National Fire Prevention Association
NIOSH - National Institute for Occupational Safety & Health
NTP - National Toxicology Program
OSHA - Occupational Safety & Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation and Recovery Act
SARA - Superfund Amendments and Reorganization Act
STEL - Short Term Exposure Limit (15 minutes)
TDG - Transportation of Dangerous Goods (Canada)
TLV-TWA - Threshold Limit Value-Time Weighted Average
TSCA - Toxic Substances Control Act
WHMIS - Workplace Hazardous Material Information System
CHEMTREC:
800-424-9300 (USA)
703-527-3887 (International)
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
MSDS Material SafetyCompanySheet
Data
Ralph Wilson Plastics
110 Adhesive Solvent
MSDS Number: 17249 Revision Date: 2/14/2008
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manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
END OF MSDS DOCUMENT
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