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Procter & Gamble
Fabric & Home Care Division
Ivorydale Technical Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: FH/H/2004/TNTE-632GZN-TIDE Issue Date: 9/01/04
FH/H/2004/TNTE-63BQUV-TIDE
Supersedes: FH/H/2002/TATJ-52VQNT Issue Date: 5/13/02
SECTION I - PRODUCT IDENTIFICATION
Identity: Granular Laundry Detergent
Brands: TIDE (All Ultra Variations except High Efficiency, Touch of Downy and Coldwater)
Hazard Rating: Health: 1 4= EXTREME
Flammability: 0 3= HIGH
Reactivity: 0 2= MODERATE
1= SLIGHT
Emergency Telephone Number: 1-800-879-8433 or call Local Poison Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Tide: Biodegradable surfactants and enzymes.
Tide with Bleach: Biodegradable surfactants, enzymes and a color-safe oxygen bleach.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200., and/or WHMIS under the HPA:
Chemical Name Common Name CAS No. Recommended Limits Composition LD50 and/or LC50
Range
Sodium Carbonate Soda ash 497-19-8 N/K 15 鈥? 40% 1.9 g/kg (Rats,
Oral)
Subtilisin* Proteolytic 9014-01-1 NIOSH/ACGIH STEL < 0.1% > 5 g/kg (Rats,
Enzyme Oral)
0.00006 mg/m鲁
Alkyl Sulfate, Sodium Alkyl 68081-98-1 N/K 10 鈥? 30% 1.3 - 2.1 g/kg
Sodium Salt Sulfate & (Rats, Oral)
Proprietary
Under normal consumer use, this product would not constitute a hazardous product under US OSHA Hazard
Communication. With increased exposure (compared with consumer use) this mixture, when tested as a whole, is
considered an inhalation hazard (enzymes) and an eye irritant within the meaning of the OSHA Hazard
Communication Standard.
*Subtilisin is listed on Table Z-1-A (1989 Air Contaminants Rule - 29 CFR 1910.1000). Though Table Z-1-A was
revoked on 6/30/93, the following U.S. states continue to enforce Table Z-1-A limits: Alaska, Connecticut,
Minnesota, Michigan, New York, Tennessee, Vermont, and Washington. The OSHA STEL (as listed on Table Z-
1-A) is 0.00006 mg/m3.
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SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation.
Eye Contact: Contact may cause mild, transient irritation.
Skin: None.
Inhalation: Heavy exposure to dust may cause transient respiratory tract irritation. Prolonged
heavy exposure to dust may cause respiratory sensitization.
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Eye contact with the product or its aqueous solution may produce transient superficial irritation.
Skin: None.
Inhalation: Heavy exposure to dust may cause transient respiratory tract irritation.
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Give milk or water.
Eye Contact: Flush eyes with water for 15 minutes.
Skin: Rinse exposed area with water.
Inhalation: Leave dusty area. In rare cases a respiratory reaction can occur which may include tightness of chest
and difficulty breathing. If this occurs, seek medical attention immediately.
Other: Consumer product packages have a caution statement:
US: 鈥淐AUTION: EYE IRRITANT. MAY BE HARMFUL IF SWALLOWED. In case of eye contact, flush
with water. If swallowed, give a glassful of water or milk. Call a physician. KEEP OUT OF REACH OF
CHILDREN.鈥?
CANADA: "CAUTION: MAY IRRITATE EYES. Do not get in eyes. KEEP OUT OF REACH OF
CHILDREN. MAY BE HARMFUL IF SWALLOWED. FIRST AID TREATMENT: Contains biodegradable
anionic surfactants and enzymes. If swallowed, give a glassful of water or milk and call a Poison Control
Centre or doctor immediately. Do not induce vomitting. If in eyes, rinse them well with water for 15
minutes.鈥?
SECTION V - FIRE FIGHTING INFORMATION
Flash Point: N/A Explosive Limits: LEL: N/A
UEL: N/A
Method Used: N/A
Extinguishing Media: CO2, water, or dry chemical may be used. Firefighters should be equipped with self-contained
breathing apparatus to protect against potentially irritating or sensitizing fumes.
Special Fire Fighting Procedures: None.
Unusual Fire Hazards: None known.
Conditions to Avoid: Open flame.
Stability Unstable:
Stable:
Incompatibility (Materials to Avoid): None known.
Hazardous Decomposition/By Products: None known.
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Conditions to Avoid: Open flame.
Hazardous Polymerization: May Occur:
Will Not Occur:
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SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: Minimize dust levels while collecting product (see "Inhalation" health effects). Prevent
exposure to dust with NIOSH approved respirators with HEPA filters. Use gloves to minimize skin contact.
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Small (household) solutions may be disposed of in sewer.
Dry product may be landfilled if permitted by local regulations. Discard empty container in trash. Waste water
containing product may be sewered in compliance with all federal and state/provincial regulations, and local
ordinances.
Steps To Be Taken in Case Material is Released or Spilled: Review Personal Precautions, FIRE FIGHTING
MEASURES, HANDLING AND STORAGE, and EXPOSURE CONTROL, PERSONAL PROTECTION sections
before proceeding with clean-up. Use appropriate personal protective equipment during clean-up. Spilled material may
be a slip hazard.
For Dry Spills, collect material in an approved container while minimizing dust generation. Vacuum, as appropriate,
remaining dust on floor. Recycle or dispose of product, as necessary, in accordance with regulations and other
requirements in this section.
Flush small (household) quantities down acceptable sanitary/process sewer. Wipe up small spills with a damp cloth.
Dispose of according to local regulations.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Avoid skin contact and breathing product dust. Store in a
cool, dry place. Keep product dry to maintain free-flowing granules.
Other Precautions: None.
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
This section only applies to the product when used in an industrial setting.
Respiratory Protection (Specify Type): Industrial use may require a NIOSH approved respirator with HEPA filters.
Ventilation: Local Exhaust: Industrial use may require LEV.
Special: None.
Mechanical (General): General dilution ventilation is adequate.
Other: None.
Eye Protection: If a splash of product in solution is likely, chemical goggles may be needed.
Protective Gloves: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Other Protective Equipment: Protective disposable suits may be required under heavy industrial dust conditions.
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SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Specific Gravity (H2O=1): N/A
Boiling Point (掳F): N/A
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): N/A
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (1% solution): ~10-11
Viscosity: N/A Reserve Alkalinity: ~5-7 (to pH 9.5)
Scooped Density: ~663 g/L Solubility in Water: Mostly soluble at 20潞C.
Appearance and Odor: Tide: White powder. Physical State: Solid granules at 20潞C.
Product is perfumed.
Tide with Bleach: White powder with blue speckles.
Product is perfumed.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known.
Conditions to Avoid: Open flame.
Materials to Avoid: None known.
Hazardous Decomposition Products: None known.
Other Recommendations: None.
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): 2.8 - 7.1 g/kg
ED50 approx. 15-119 mg/kg
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations. This product contains an anionic surfactant that has an aquatic
96 hr LC50 of 0.92 ppm (Pimephales promelas, OECD 203 test). This is the lowest L/EC50 amongst fish, Daphina and
algae. This surfactant is rapidly biodegradable under aerobic and anaerobic conditions (protocols: OECD 301-B and
ECETOC 1988, respectively). The levels of biodegradation in these standard test conditions are >70%. Its removal in
municipal sewage treatment is expected to be >99% based on standard laboratory test methods. Environmental risk
assessment confirms comfortable safety margins because of its high removal and fast biodegradability kinetics.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Dry product from consumer may be landfilled. Industrial dry
product may be landfilled if permitted by local regulations or may be incinerated if landfill disposal is not allowed.
Consumer may discard empty container in trash, or recycle where faciliites exist. Industrial producer may discard
empty, individual containers in trash. Multiple empty and/or damaged containers should be compacted and landfilled,
in accordance with all applicable regulations, or incinerated.
Consumer produced household solutions may be disposed of to sewer. Industrial waste water containing product may
be sewered if in compliance with all federal, and state/provincial regulations and local ordinances.
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SECTION XIV - TRANSPORT INFORMATION
The finished product is non-hazardous under DOT.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All intentionally-present components are listed on the US TSCA Inventory.
This product is not subject to warning labeling under California Proposition 65.
No components are affected by Significant New Use Rules (SNURs) under TSCA 搂5.
All ingredients are CEPA approved for import to Canada by Procter & Gamble.
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations.
Sodium carbonate (497-19-8) is listed on the Canadian WHMIS Ingredient Disclosure List (IDL) as item number 1431,
with a threshold of 1%.
SECTION XVI - OTHER INFORMATION
**N/A. - Not Applicable **N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when
used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in
connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable
and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific material designated
herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble
assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from
misuse of the controlled product.
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